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2 protocols using poly vinyl alcohol pva 10 000

1

Synthesis of Nanoparticle Catalysts

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The chemicals chromium (III) nitrate (99%, Sigma-Aldrich, St. Louis, MO, USA), NaOH (≥98%, Sigma-Aldrich, USA), silver nitrate (≥99%, Sigma-Aldrich, MO, USA), Palladium (II) nitrate solution (99.9%, Sigma-Aldrich, USA), Ni(NO3)2 6H2O (99.99%, Sigma-Aldrich, USA), Sodium Borohydride (Fisher scientific, Waltham, MA, USA), Poly (vinyl alcohol) (PVA, 10,000, 80%, Sigma-Aldrich, MO, USA), and Nitrobenzene (≥99%, Sigma-Aldrich, USA). Deionized water was employed in all synthesis and this was supported by the Milli-Q direct 8 treatment system (Millipore, Molsheim, France). All chemicals were utilized as they were obtained, unless noted otherwise.
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2

Synthesis of Transition Metal Nanoparticles

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Cobalt (II) nitrate hexahydrate (98%), chromium (III) nitrate (99%), sodium hydroxide (≥98%), copper (II) nitrate (≥99.9%), palladium (II) nitrate solution (99.9%), polyvinyl alcohol (PVA) (10,000, 80%), benzyl alcohol (≥99%), benzyl benzoate (≥99%), benzene (99.8%), benzaldehyde (≥99%), toluene (≥99.7%), benzoic acid (≥99.9%), and nitrobenzene (≥99%) were obtained from Sigma-Aldrich, St. Louis, CO, USA. Sodium borohydride and acetone were bought from Fisher Scientific, Hanover Park, IL, USA.
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