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2 protocols using tin powders

1

Synthesis and Characterization of High-Purity Perovskite Materials

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Tin iodide (SnI2, 99.999%) was purchased from Alfa Aesar. DMSO (99.8%), N,N‐dimethylformamide (DMF, 99.8%), tin fluoride (SnF2, 99%), TAH (98%), chlorobenzene (CB anhydrous, 99.8%), and tin powders (<150 µm, 99.5%) were purchased from Sigma–Aldrich. Methylammonium iodide (MAI), FAI, and lead iodide (PbI2) were purchased from GreatCell Solar. Fullerene (C60) and bathocuproine (BCP) were obtained from Xi'an Polymer Light Technology Co. Ltd., China. PEDOT:PSS aqueous solution (Al 4083) was acquired from Heraeus Clevios. All the chemical reagents were used as received without any further purification.
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2

Perovskite Solar Cell Fabrication

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All materials were used as received without further purification. The organic halide salts (FAI, MAI and phenylethylammonium iodide (PEAI) with purity of >99%) were purchased from GreatCell Solar Materials. PEDOT-PSS aqueous solution (Al 4083) was purchased from Heraeus Clevios. PbI2 (99.99%, trace metals basis) and PbBr2 (99.99%, trace metals basis) were purchased from TCI. SnI2 (99.999%, trace metals basis) was purchased from Alfa Aesar. SnF2 (99%), tin powders (<150 μm, 99.5%), CsI (99.999%), DMF (99.8% anhydrous), DMSO (99.9% anhydrous), formamidine sulfinic acid (FSA, ≥98%), chlorobenzene (99.8% anhydrous) were purchased from Sigma-Aldrich. The C60 was purchased from Nano-C. N4,N4 ′di(naphthalen-1-yl)-N4,N4 ′ -bis(4-vinylphenyl) biphenyl-4,4 ′ -diamine (VNPB, >95%) was purchased from Lumtec.
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