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2 protocols using potassium titanium oxide oxalate dihydrate

1

Synthesis and Characterization of Dye-Sensitized Solar Cells

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Ti (or W, Ni, etc.) wires (99.9%, with the diameter of 0.50 mm) were purchased from China New Metal Materials Technology Co., Ltd. Boric acid (H2BO3, 99.5%), ethanol (99.7%), acetone (99.5%), potassium titanium oxide oxalate dihydrate (C4K2O9Ti·2H2O, 98.5%), and diethylene glycol (DEG) were purchased from Sinopharm Chemical Reagent Co. Ltd. Ruthenium 535-bisTBA (N719) was purchased from Solaronix. Guanidinium thiocyanate (GuSCN, 99.0%) was from Amresco. Ammonium hexafluorotitanate (IV) ((NH4)2TiF6, 98%), lithium iodide (LiI, 99.999%), iodine (I2, 99.99%), 1-methyl-3- propylimidazolium iodide (PMII, 98%), 4-tert-butylpyridine (TBP, 96%) and tert-butyl alcohol (99.5%) were obtained from Aladdin. Acetonitrile (99.8%) and valeronitrile (99%) were from Alfa Aesar. All solvents and chemicals were reagent grade and were used as received without further purification.
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2

Photocatalytic Nanocomposite Synthesis

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Potassium titanium oxide oxalate dihydrate (K2TiO(C2O4)2·2H2O, ≥98% Ti basis), hydrogen hexachloroplatinate(IV) hexahydrate (H2PtCl6·6H2O, 99.9%), sodium borohydrate (NaBH4, 98%), sodium hypophosphite monohydrate (NaH2PO2·H2O, 99%), diethylene glycol (99%), and urea (H2NCONH2, 99%) were commercially available from Sinopharm Chemical Reagent Co., Ltd. Hexadecyltrimethylammonium bromide (CTAB, >99%), L-ascorbic acid (L-AA, >99%), sodium citrate tribasic dihydrate (99%), and citric acid (99.5%) were purchased from Sigma-Aldrich. All reagents were used without any further purification. Ultrapure water (18.2 MΩ) produced with a Milli-Q purification system was used in the synthesis and photocatalytic measurements.
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