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3 protocols using veratrole

1

Heterogeneous Catalysis Precursor Synthesis

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Nickel(ii) nitrate hexahydrate (Ni(NO3)2·6H2O) (>98.5% purity), ammonium molybdate tetrahydrate ((NH4)6Mo7O24·4H2O) (81.0–83.0% purity MoO3 basis), Brij 30, ammonium sulphide solution (20.0% in H2O), tetraethyl orthosilicate (TEOS) (98.0% purity), sucrose (99.5% purity), sulphuric acid (99.9% purity), dodecane (99.0% purity), guaiacol (99.0% purity), catechol (99.0% purity), anisole (99.7% purity), cyclohexanol (99.0% purity), cyclohexane (99.5% purity), cyclohexene (analytical grade), veratrole (99.0% purity), cresol (99.0% purity), pluronic P-123, activated carbon (norit SX ultra) were all purchased from Sigma-Aldrich.
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2

Standards Purchase for Compound Analysis

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Standards of 2-methylanisole, 2-methylphenol, 3-methoxycatechol, anisole, caffeic acid, catechol, 3,4-dihydroxybenzaldehyde, ferulic acid, guaethol, guaiacol, phenol, protocatechuic acid, pyrogallol, syringol, vanillic acid, vanillin, and veratrole were purchased from Sigma Aldrich (Sigma Aldrich, St Louis, MO).
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3

Deuterium-labeled Compounds Synthesis

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Deuterium-labeled 1,2-dihydroxybenzene-d6 (98% atom deuterium) and 2-hydroxybenzoic acid-d6 (98.8% atom deuterium) were from CDN isotopes (Pointe-Claire, QC, Canada). S-[Methyl-14C] adenosyl-L-methionine (2.146 GBq) was from PerkinElmer. Catechol, guaiacol, salicylic acid, 1,2-dihdroxybenzoic acid, and veratrole were obtained from Sigma-Aldrich (Oakville, ON, Canada). All other materials were obtained from Sigma-Aldrich or Fisher Scientific.
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