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2 protocols using 1 2 dichloroethane dce

1

Rare Earth Chloride Synthesis Protocol

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All chemical reagents were obtained from the commercial institution and used without further purification. The rare earth (RE) chlorides including LuCl3•6H2O (99.9%), GdCl3•6H2O (99.9%), YbCl3•6H2O (99.9%), and ErCl3•6H2O (99.9%) were obtained from QingDa elaborate Chemical Reagent Co. Ltd (Shandong). NaOH, NaF, anhydrous alcohol, toluene, oleic acid (OA), IGEPAL CO-520, dopamine hydrochloride, ammonium hydroxide, 1,2-dichloroethane (DCE), IR-26 dye, cyclohexane, and other reagents were all purchased from Sinopharm Chemical Reagent Co., China.
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2

Macroporous PS-co-DVB Resin Synthesis

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Macroporous PS-co-DVB resin was supplied by Jinkai Resin Chemical Co., Ltd (Jiangsu, China), it had cross-linking degree of 6%, total pore volume (Vtotal) of 0.039 cm3 g−1, average pore size (DP) of 24.3 nm and BET surface area (SBET) of 19.5 m2 g−1. Anhydrous FeCl3, nitric acid, sulfuric acid, hydrochloric acid, acetic anhydride, sodium sulfite, 1,2-dichloroethane (DCE), DCM, aniline (AN) and p-nitroaniline (PNA) were obtained from Sinopharm Chemical Reagent Co., Ltd. SnCl2·6H2O was supplied from Xilong Scientific Co., Ltd (Shantou, China). Methylene blue (MB) was purchased from Macklin Biochemical Co., Ltd (Shanghai, China).
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