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2 protocols using anhydrous magnesium sulfate

1

Polysulfone Membrane Functionalization with CNTs

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Polysulfone membrane sheet, PS (PS-20), (Sepro, California, CA, USA). Merck supplied 1,3-phenylenediamine (C6H8N2, 99.5%) and 1,3,5-benzenetricarbonyl trichloride (C9H3Cl3O3, 98%) (Kenilworth, New Jersey, NJ, USA). Short multiwalled carbon nanotubes (MWCNTs) with a purity of 95% and average diameter of 3–10 nm was provided by Grafen Chemical Industries (Ankara, Turkey). MWCNTs COOH and MWCNTs-NH2) are thin multiwalled carbon nanotubes that have been functionalized. MWCNT samples with a purity of 95% were obtained from Nanocyl (Sambreville, Belgium). Hexane (C6H14, 99%) was purchased from Oxford Laboratory (Mumbai, India). Sodium chloride (NaCl, 99%) was purchased from Sigma-Aldrich Chemicals (Hamburg, Germany), while anhydrous magnesium sulfate (MgSO4, 98%) and extra pure anhydrous sodium carbonate (Na2CO3, 99.5%) were obtained from Scharlau (Barcelona, Spain). Absolute ethanol (96%) was purchased from Ajax Finechem Pty, Ltd. (South Wales, Australia). Milli-Q® water (18.2) was used to make both solutions and dilutions in this study.
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2

Pesticide Residue Analysis Protocol

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Pesticide reference standards including malathion, diazinon, profenofos, chlorpyrifos, chlorpyrifos-methyl, omethoate, dimethoate, cypermethrin, deltamethrin, fenpropathrin, permethrin, tetramethrin, cyfluthrin, fenvlarate, lamdacyhalothrin , lindane, heptachlor, aldrin, heptachlor epoxide, mixture endosulfan, dieldrin, endrin, o,P-DDT, carbaryl, carbofuran, bendiocarb, atrazine, imidacloprid, thiomethoxam and pendimethalin were purchased from Sigma Aldrich GmbH (Augsburg, Germany), Supelco and Bayer Crop Science , with certified purity ranging from 95% to 99%. Acetonitrile, acetone, sodium chloride, toluene, acetic acid and anhydrous magnesium sulfate were obtained from Scharlau (Barcelona, Spain). QuEChERS Finisterre micro centrifuge tube containing two or more of primary secondary amine (PSA), anhydrous magnesium sulfate (MgSO4) and graphed carbon black (GCB) with details of TR-Q2035 (150mg MgSO4, 25mg PSA, 2.5mg GCB) and TR-Q2015 (150mg MgSO4, 25mg PSA) were obtained from Teknokroma (Barcelona, Spain). Piperonyl Butoxide (PPB) with certified purity 95% used as internal standard was obtained from Sigma Aldrich GmbH.
All the organic solvents used were high performance liquid chromatography (HPLC) grade.
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