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16 protocols using indium 3 acetate

1

Synthesis of Multimetal Nanoparticles

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Polyvinylpyrrolidone (PVP, (C6H9NO)n, AMW ~55,000), indium(III) acetate (InC6H9O6, 99.99%), and bismuth(III) nitrate pentahydrate (Bi(NO3)3·5H2O, ≥99.99%) were purchased from Sigma-Aldrich. Sodium selenite (Na2SeO3, ≥98%), copper (II) nitrate trihydrate (Cu(NO3)2·3H2O, 99%), silver nitrate (AgNO3, ≥99.9%), ethylene glycol (EG, HOCH2CH2OH, 99%), lead (II) acetate trihydrate (PbC4H6O4·3H2O), tin(II) chloride anhydrous (SnCl2, 98%), and potassium hydroxide (KOH, ≥98%) were acquired from Fisher. Analytical grade ethanol and acetone were obtained from various sources.
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2

Synthesis of Colloidal Metal-Chalcogenide Nanocrystals

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Copper(i) iodide (CuI, 99.99%), indium(iii) acetate (In(OAc)3, 99.99%), zinc(ii) acetate (Zn(OAc)2, 99.99%), 1-dodecanethiol (99.9%), 1-octadecylamine (97%), 1-octadecene (90%), and γ-(mercaptopropyl)trimethoxysilane (95%) were purchased from Sigma-Aldrich Corp. (USA) and used without further purification.
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3

Synthesis of Colloidal Quantum Dots

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Indium(III) chloride (InCl3, 99.9%), indium (III) acetate (In(OAc)3, 99.99%), silver nitrate (AgNO3, 99%), zinc(II) acetate dihydrate (Zn(OAc)2*2H2O, 99%), zinc stearate (technical grade), sodium sulfide (Na2S × 9H2O, 98%), NH4OH (aqueous 5.0 M solution), thioglycolic acid (TGA), 1-dodecanethiol (DDT, 98%), 1-octadecene (ODE, 90%), oleic acid (OA, 99%), acetone (>99%), and methanol (99.93%) were purchased from Sigma Aldrich and used without purification. All the aqueous solutions were prepared using Milli-Q water (Millipore) as a solvent.
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4

Synthesis of Colloidal Nanocrystals

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All the reagents were used without further purification. Cesium acetate (CsOAc, 99.99%), silver acetate (AgOAc, 99%), sodium acetate (NaOAc, 99.99%), indium(iii) acetate (In(OAc)3, 99.99%), bismuth(iii) acetate (Bi(OAc)3, 99.99%), chlorotrimethylsilane (TMSCl, 98%), oleic acid (OA, 90%), and 1-octadecane (ODE, 95%) were purchased from Sigma-Aldrich. Oleylamine (OAm, 80–90%) was purchased from Kanto Kagaku. Toluene (99.5%), hexane (96%), and ethyl acetate (99.5%) were purchased from Wako Chemicals.
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5

Synthesis of Colloidal Quantum Dots

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Indium (III) acetate (99.999%), palmitic acid (98%, PA), zinc stearate (10% Zn basis), 1‐octadecene (90%, ODE), oleic acid (90%, OA), selenium powder (99.99%), sulfur powder (99.998%), PVP, Tetramethylammonium hydroxide (≥97%, TMAH), anhydrous zinc acetate (99.99%), and dimethyl sulfoxide (≥99.9%, DMSO) were purchased from Sigma‐Aldrich. Tris(trimethylsilyl)‐phosphine (98%, (TMS)3P) and trioctylphosphine (97%, TOP) were purchased from Strem Chemicals. Poly[(9,9‐dioctylfluorenyl‐2,7‐diyl)‐alt‐(4,4′‐(N‐(4‐butylphenyl) (TFB) was purchased from Xi'an Polymer Light Technology Corp. Acetone (extra dry, >99%), ethanol (extra dry, >99%), ethyl acetate (extra dry, >99%), and octane (extra dry, >99%) were purchased from Acros. All chemicals were used without further purification.
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6

Synthesis of Colloidal Quantum Dots

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Oleylamine (OAm, technical grade, 70%), 1-octadecene (ODE, 90%), sulfur (S, 99.999%), and hexanes (99%) were purchased from Fisher Scientific. Tris(trimethylsilyl) phosphine ((TMS)3P, 98%) was purchased from Strem Chemical, Inc. Chloroform was purchased from J.T.Baker. Indium (III) acetate (In(Ac)3, 99.99%), oleic acid (OA, 90%), n-trioctylphosphine (TOP, 97%), selenium pellets (Se, 99.99%), zinc acetate (Zn(Ac)2, 99.0%), indium (III) acetylacetonate (In(Acac)3, 99.99%), trioctylphosphine oxide (TOPO, 99%), myristic acid (HMy, 99%), ethanol (99.8%), dioctylamine (97%), and InP/ZnS QDs (λem=670 nm) in toluene were purchased from Sigma-Aldrich. ODE was heated to 120 °C under vacuum for several hours with multiple argon backfill and evacuation cycles to ensure complete removal of air and water and stored in an argon glovebox prior to use. CdSe/ZnS QDs were purchased from NNCrystal US Corporation. All other chemicals were used directly without further purification. Quartz cuvettes were purchased from Starna Cells Inc. All air-sensitive materials were stored and handled in an argon glovebox.
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7

Synthesis of Inorganic Nanoparticles and Dyes

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1-Dodecanthiol (DDT, 98%) was obtained from Acros Organics; Zinc stearate (65%), Zinc oxide (99%) and Indium (III) acetate (In(Ac)3, 98%), Silver (I) nitrate (AgNO3, ≥99.5%), Oleic acid (OA, 90%), 1-Octadecene (ODE, 90%), Oleylamine (OlAm, 70%), 2-Ethylhexanoic acid (99%), Thiourea (99%), Triethyleneglycol dimethylether (98%), L-cysteine hydrochloride monohydrate (98%), Potassium hydroxide (KOH, 90%) were purchased from Sigma Aldrich (Saint Petersburg, Russian Federation). Organic cyanine dyes: 3,3′-diethylthiacarbocyanine iodide (Cy3) (95%) and 3,3′-diethylthiadicarbocyanine iodide (Cy5) (98%) were purchased from Sigma-Aldrich. Solvents: Isopropanol (99.8%), acetone (99.75%), and chloroform (99.9%) were obtained from Vekton (Saint Petersburg, Russian Federation). All chemicals were used without further purification. Ultrapure water (Milli-Q) was used throughout the experiments.
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8

Synthesis of Colloidal Nanocrystals

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Indium(III) acetate (In(OAc)3,
99.99%), zinc(II) acetate (Zn(OAc)2, 99.99%), palmitic
acid (PA, C15H31COOH, 99.99%, stored at
−20 °C), gallium(III) chloride (beads, Sigma-Aldrich,
99.99%), tris(trimethylsilyl)-phosphine (P(TMS)3, 95%), 1-octadecene (ODE, 95%), oleic acid (Sigma-Aldrich,
99.99%), ammonium sulfide solution ((NH4)2S,
20% in H2O), 1-octadecene (ODE, 95%), formamide (FA, 99%),
dimethylformamide (DMF, 99%), Zn stearate (technical grade),
sulfur powder (99.98% trace metals basis), and trioctylphosphine
(TOP, 90% technical grade) were purchased from Sigma-Aldrich. Selenium
powder (99.98% trace metals basis) was purchased by Chem Pure. All
the chemicals were used without further purification.
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9

Synthesis of Colloidal Semiconductor Nanocrystals

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Indium (III) acetate [In(Ac)3, ≥99.99%], myristic acid (MA, ≥99%), zinc (II) stearate [Zn(St)2, >99%], tri-η-octyl phosphine (TOP, ≥97%), 1-octadecene (ODE, technical grade), selenium powder (Se, ≥99.99%), sulfur powder (S, ≥99.98%), acetic acid solution (HAc, ≥99%), and Zirconium acetate solution in dilute acetic acid [Zr(Ac)4, Zr: 15.0–17.0% gravimetric] were purchased from Sigma-Aldrich. Tris(trimethylsilyl) phosphine ((TMS)3P, >98%, 10 wt.% in hexane) were purchased from Strem Chemicals. Toluene (anhydrous, ≥99.8%), acetone (anhydrous, ≥99.8%), and ethanol (anhydrous, ≥99.8%) were purchased from General-reagent.
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10

Synthesis of Colloidal Nanocrystals

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Copper(i) chloride (CuCl, anhydrous, beads, ≥99.99% trace metals basis), indium(iii) acetate (In(Ac)3, 99.99% trace metals basis), zinc acetate (Zn(Ac)2, 99.99% trace metals basis), tellurium powder (Te, 200 mesh, 99.99%), 1-octadecene (ODE, technical grade, 90%), 1-dodecanethiol (DDT, ≥98%), oleylamine (OLA, technical grade, 70%) and tetrabutylammonium hexafluorophosphate (TBAPF6, 98%) were purchased from Sigma-Aldrich. The chemicals were used as such without further purification.
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