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Nanomer pgv

Manufactured by Merck Group
Sourced in United States

Nanomer® PGV is a specialty nanomaterial product offered by Merck Group. It is a modified natural montmorillonite clay with a nanoscale particle size. The core function of Nanomer® PGV is to serve as a performance-enhancing additive in various applications, leveraging its unique physical and chemical properties.

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4 protocols using nanomer pgv

1

Gelatin-Based Composite Hydrogels

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The materials used for this study were: gelatin (Berthelet, Laval, QC, Canada), glycerol (GLY) (analytical grade, Sigma-Aldrich, Saint Louis, MO, USA), hydrophilic bentonite (Nanomer® PGV, Sigma-Aldrich, Saint Louis, MO, USA), lignocellulosic microfiber from Agave angustifolia Haw, obtained from the method developed by Hernández et al. [14 (link)], potassium hydroxide, hydrochloric acid and silica gel (Hycel, Jalisco, Mexico), sodium bromide and sodium chloride (Fermont, Monterrey, Mexico). Distilled water (DW) was used in all formulations.
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2

Thermal Degradation of Nanoclay Samples

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Nanoclay samples (i.e., unmodified, bentonite (Nanomer PGV) and surface-modified clays: Nanomer I.31PS (0.5–5 wt % aminopropyltriethoxysilane and 15–35 wt % octadecylamine), I.34TCN (25–30 wt % methyl dihydroxylethyl hydrogenated tallow ammonium), and I.44P (35–45 wt % dimethyl dialkyl amine); Supplementary Figure 1a) were purchased from Sigma-Aldrich. Thermal degradation by incineration of such nanoclays was performed at 900 °C using a TGA701 Thermogravimetric Analyzer (LECO). Briefly, samples were heated at 6 °C/min from 25 to 105 °C in nitrogen to measure the moisture content and at 43 °C/min from 105 to 950 °C to determine the high volatile content. Next, samples were evaluated for ash content at 15 °C/min in O atmosphere and between 550 and 900 °C. Resultant ash was collected and used as a model for thermally degraded byproduct formation (referred to hereafter as PGV900, I31900, I34900, and I44900).23 (link),24 (link)
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3

Decontamination of Radioactive Surfaces

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Poly(vinyl alcohol) (PVA, average Mw ≈ 85,000–124,000 Da, 87–89% hydrolyzed, Sigma Aldrich), sodium alginate (Alg, white powder seaweed extract from Special Ingredients Ltd., Glasgow, UK), gelatine (Glt, GELITA® Pharmaceutical Gelatin, Limed Bovine Bone Gelatine, 250 bloom, 8 mesh), iminodisuccinic acid (IDS, BAYPURE® CX 100, Lanxess), hydrophilic bentonite (BT, Nanomer® PGV, Sigma–Aldrich), glycerol (Gly, purity ≥99.5%, Sigma–Aldrich), were used as received. Radionuclides solutions for controlled contamination consisted of radioactive solutions of 90Sr-90Y (β−emitting representative radionuclide) and 241Am (α−emitting representative radionuclide), in 0.1N HNO3, initial activity: 90Sr/Y—1.64 kBq/g and 241Am—600 Bq/g. Surfaces employed for decontamination tests: concrete (C, approximately dimensions 12 mm × 12 mm × 0.8 mm), painted metal (PM, approximately dimensions 20 mm × 10 mm × 0.2 mm), ceramic tiles (CT, approximately dimensions 8 mm × 8 mm × 0.5 mm), linoleum (L, linoleum for flooring purposes, approximately dimensions 10 mm × 10 mm × 0.3 mm) and epoxy resin (P, ProLab® epoxy cover for workbenches, approximately dimensions 20 mm × 10 mm × 0.6 mm). It is important to note that none of the surfaces utilized in the decontamination test had been previously used, yet they had been wiped with alcohol before contamination.
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4

Decontaminating Chemical Warfare Agents

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Poly(vinyl alcohol) (PVA, 86.7–88.7% hydrolysis degree, Mw ≈ 130,000 Da, DP ≈ 2700, Sigma–Aldrich), hydrophilic bentonite (BT, Nanomer® PGV, Sigma–Aldrich, St. Louis, MO, USA), anhydrous glycerol (GLY, Sigma–Aldrich, St. Louis, MO, USA), copper(II) acetate monohydrate (≥98%, Sigma Aldrich, St. Louis, MO, USA), titanium(IV) oxide (nanopowder, <100 nm particle size, 99.5% trace metals basis, Sigma Aldrich, St. Louis, MO, USA), Triton™ X-100 solution (Sigma Aldrich, St. Louis, MO, USA), ascorbic acid (≥99%, Sigma Aldrich, St. Louis, MO, USA), Silver nitrate (≥99.0%, Sigma Aldrich, St. Louis, MO, USA), tri-sodium citrate dihydrate (Sigma Aldrich, St. Louis, MO, USA), and sodium borohydride (≥99.0%, Sigma Aldrich, St. Louis, MO, USA) were used as received. For the chemical decontamination tests, real chemical warfare agents (CWA) were used: bis(2-chloroethyl) sulfide (HD, sulfur mustard, purity: 95%, own synthesis), together with a chemical warfare simulant: dimethyl methylphosphonate (DMMP, as simulant for nerve agents, ≥97%, Sigma Aldrich). All the tests involving the decontamination of the toxic agents utilized in this study were performed at the Research and Innovation Center for CBRN Defense and Ecology in the ‘Chemical Analysis Laboratory’ from Bucharest, the only OPCW-designated laboratory in Romania.
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