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7 protocols using bis 2 ethylhexyl adipate

1

Synthesis of Luminescent Nanomaterials

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Oleic acid, bis(2-ethylhexyl) adipate, ytterbium acetate, erbium acetate, and sodium acetate were purchased from Sigma Aldrich (Burlington, MA, USA); yttrium trifluoroacetate from GFS Chemicals (Columbus, OH, USA); sodium trifluoroacetate and di-n-butyl phthalate from Alfa Aesar (Ward Hill, MA, USA); ethyl alcohol from Koptec (King of Prussia, PA, USA); isopropanol from VWR Chemicals (Mississauga, ON, Canada).
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2

Characterization of Phthalate Esters

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Di-(2-ethylhexyl) phthalate (DEHP; 99.7%), bis-2-ethylhexyl adipate (DEHA; 99%), and triphenyl phosphate (TPP) were purchased from Sigma-Aldrich. Benzyl butyl phthalate (BBP; 98%), was purchased from Supelco, and phthalate esters mixture (1 mL of 500 µg/mL each in methanol), containing dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP), BBP, DEHA, and DEHP, was purchased from Sigma-Aldrich, Supelco. Tetrahydrofuran (THF), ethanol, and hexane were purchased from Sigma-Aldrich (MO, USA).
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3

Microneedle Patch for Electrochemical Sensing

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Hydrogen
ionophore I (tridodecylamine)
of selectophore grade, carbonate ionophore VII (N,N-dioctyl-3α,12α-bis(4-trifluoroacetylbenzoyloxy)-5β-cholan-24-amide)
of selectophore grade, poly(vinyl chloride) (PVC), polyurethane (PU)
(Reference 81367, selectophore grade), bis(2-ethylhexyl)sebacate (DOS,
>97%), sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (NaTFPB),
tridodecylmethylammonium chloride (TDMACl), bis(2-ethylhexyl) adipate
(DEHA), and tetrahydrofuran (THF, >99.9%) were purchased from Sigma-Aldrich
(Sweden). Carbon/graphite ink (C2030519P4) and silver/silver chloride
(Ag/AgCl) 50/50 paste (C2131007D3) were obtained from Sunchemical.17 ,18 Silicon rubber (Ecoflex 00–50 platinum cure) and stainless-steel
microneedles (MN) (Dermaroller local supplier, Sweden) were employed
for the fabrication of the MN patch. Other chemicals and materials
are provided in the Supporting Information.
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4

Solvent-based PHB Polymer Extraction

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All chemicals used in this study were of analytical grade. PHB pellets (Average MW: 550,000 g/mol) were obtained from Goodfellow Cambridge Ltd. (Huntingdon, UK). Chloroform and ethanol were obtained from Fisher Scientific (Hampton, NH, USA). Bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) sebacate, lauric acid, triacetin, tributyl citrate, tributyl 2-acetylcitrate, l-Linalool, and geraniol were obtained from Sigma-Aldrich (St. Louis, MO, USA).
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5

Tenax TA Preparation and Phthalate Analysis

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Tenax TA (refined), particle size 60-80 mesh, was obtained from Supelco (Bellefonte, USA) and cleaned up prior to use. All the Tenax used in this work came from the same batch.
Diisobutyl phthalate (CAS no. 84-69-5), Diisobutyl phthalate-3,4,5,6-d 4 (CAS no. 358730-88-8; analytical standard), diisononyl phthalate (CAS no. 28553-12-0; ester content ≥ 99%, mixture of C 9 isomers), 2,6-di-tert-butyl-4-methyl-phenol (CAS no. 128-37-0), bis(2ethylhexyl) adipate (CAS no. 103-23-1) and benzophenone (CAS no. 119-61-9; purified by sublimation), all of 99% or higher purity, were purchased from Sigma-Aldrich (Steinheim, Germany). Acetone (CAS no. 67-64-1; for liquid chromatography Lichrosolv®) and n-hexane (CAS no. 110-54-3; for liquid chromatography Lichrosolv®) were obtained from Merck KGaA (Darmstadt, Germany).
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6

Analytical Standards for Environmental Analysis

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Benzophenone (CAS no. 119-61-9; purified by sublimation), 2,6-di-tert-butyl-4-methyl-phenol (CAS no. 128-37-0), diisobutyl phthalate (CAS no. 84-69-5), diisobutyl phthalate-3,4,5,6-d4 (CAS no. 358730-88-8; analytical standard), bis(2-ethylhexyl) adipate (CAS no. 103-23-1) and diisononyl phthalate (CAS no. 28553-12-0; ester content ≥ 99%, mixture of C9 isomers), all of 99% or higher purity, were purchased from Sigma-Aldrich (Steinheim, Germany). n-Hexane (CAS no. 110-54-3; for liquid chromatography Lichrosolv®) was obtained from Merck KGaA (Darmstadt, Germany).
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7

Analytical Standards Preparation and Tenax Cleanup

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Benzophenone (CAS no. 119-61-9; purified by sublimation), 2,6-di-tert-butyl-4-methyl-phenol (CAS no. 128-37-0), diisobutyl phthalate (CAS no. 84-69-5), diisobutyl phthalate-3,4,5,6-d4 (CAS no. 358730-88-8; analytical standard), bis(2-ethylhexyl) adipate (CAS no. 103-23-1) and diisononyl phthalate (CAS no. 28553-12-0; ester content ≥ 99%, mixture of C9 isomers), all of 99% or higher purity, were purchased from Sigma-Aldrich (Steinheim, Germany).
Acetone (CAS no. 67-64-1) and n-hexane (CAS no. 110-54-3) for liquid chromatography Lichrosolv® were from Merck KGaA (Darmstadt, Germany).
Tenax TA (refined), particle size 60-80 mesh, was purchased from Supelco (Bellefonte, USA) and cleaned up prior to its use by Soxhlet extraction. Tenax TAken from only one batch was used.
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