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2 protocols using anhydrous methylacetate

1

Colloidal Quantum Dot Synthesis

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Cesium
carbonate (Cs2CO3, 99.9%), 1-octadecene (ODE,
90%), oleic acid (OA, 90%), lead bromide
(PbBr2, 99.999%), oleylamine (OLAM, 70%), tin(II) bromide
(SnBr2), cadmium bromide tetrahydrate (CdBr2·4H2O, 98%), zinc bromide (ZnBr2, 99.999%),
anhydrous toluene (99.8%), anhydrous hexane (95%), and anhydrous methyl
acetate (99.5%) were obtained from Sigma-Aldrich. OLAM and OA were
degassed at 120 °C for 1 h prior to use. All others chemicals
were used as received.
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2

Synthesis of Semiconductor Nanocrystals

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cadmium oxide (99.99%), oleic acid (technical grade, 90%), and n-hexadecane (99%) were purchased from Sigma Aldrich and used as received. Indium acetate (99.99%), diethyl zinc (≥52 wt % Zn basis), cadmium acetate (99.995%), cadmium acetylacetonate (≥99.9%), lead oxide (>99.9%), oleic acid (≥99%), anhydrous hexanes (>99%), anhydrous methyl acetate (99.5%), and toluene-d8 (99.6%) were purchased from Sigma-Aldrich and stored in an argon glovebox. Anhydrous tetrahydrofuran (≥99.9%, Sigma-Aldrich) was distilled from a solvent still immediately prior to being stored in an argon glovebox. Indium (99.9999%), zinc (99.9999%), cadmium (99.999%), Indium phosphide (99.9999%), zinc sulfide (99.995%), and cadmium sulfide (99.999%) were purchased from Alfa Aesar and used as received. Lead sulfide (99.995%) and hydrochloric acid (37%, ACS Reagent) were purchased from Fisher Scientific and used as received. Argon (99.999%), and hydrogen (5% in argon) were purchased from Airgas and used as received. Zinc acetate (99.98%, Alfa Aesar), tris(trimethylsilyl)phosphine (98%, Strem Chemicals), bis(trimethylsilyl)sulfide (98%, Beantown Chemical), bis(trimethylsilyl)amine (98%, Acros Organics), and anhydrous acetone (99.5%, Fisher Scientific) were stored in an argon glovebox and used as received.
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