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5 protocols using dysprosium 3 chloride hexahydrate

1

Dysprosium-Carboxylate Coordination Polymer Synthesis

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All chemicals were of reagent grade and were used as commercially obtained without any further purification. N,N-dimethylformamide anhydrous (HCON(CH3)2, ≥99.8%), dysprosium(III) chloride hexahydrate (DyCl6·6H2O, ≥99.99%), 5-aminoisophthalic acid (H2NC6H3-1,3-(CO2H)2, 94%), methanol (CH3OH, 99.8%), ethanol (C2H5OH, 99.8%), dimethyl sulfoxide anhydrous (C2H6OS, ≥99.9%), and acetic acid (CH3COOH, 99–100%) were purchased from Sigma Aldrich (Darmstadt, Germany). All the aqueous solutions were prepared with ultrapure water (0.22 μS/cm, 25 °C, MilliQ©, Millipore, Burlington, CA, USA).
Cellulose filter paper (Ref. 1240, sheet 203 × 254 mm, base weight 85 g/m2; thickness 200 µm; retention 14–18 µm) was obtained from Filter-Lab (Barcelona, Spain).
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2

Synthesis of Luminescent Nanoparticles

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Nanoparticles zinc oxide (<100 nm particles size), Erbium (III) chloride hexahydrate, Europium (III) chloride hexahydrate, Terbium (III) chloride, Dysprosium (III) chloride hexahydrate, Europium (III) chloride hexahydrate and Deionized (DI) water were purchased from Sigma Aldrich (Madrid, Spain), and used without any further purification.
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3

Synthesis of Luminescent Coordination Polymers

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Silver
nitrate (AgNO3), calcium chloride dihydrate (CaCl2·2H2O), sodium nitrate (NaNO3), potassium
chloride
(KCl), manganese chloride (MnCl2), copper II chloride dihydrate
(CuCl2·2H2O), magnesium chloride anhydrous
(MgCl2), aluminum chloride (AlCl3), iron III
chloride (FeCl3), dysprosium III chloride hexahydrate (DyCl3·6H2O), sodium citrate tribasic tetrahydrate
(HOC(COONa) (CH2COONa)2·4H2O),
hydrogen peroxide (H2O2), terbium III chloride
hexahydrate (TbCl3·6H2O), ytterbium III
chloride hexahydrate (YbCl3·6H2O), holmium
III chloride hexahydrate (HoCl3 ·6H2O),
lead chloride (PbCl2), sodium carbonate anhydrous (Na2CO3), sodium phosphate (Na3PO4), sodium sulfate (Na2SO4), sodium fluoride
(NaF), sodium acetate (CH3COONa), disodium tartrate, disodium
succinate, disodium malate, CTAB, polyethylene glycol 1500, and dodecanoic
acid were purchased from Sigma-Aldrich Company (South Korea). Fumaric
acid, p-toluene sulfonic acid (PTSA), and 3-(4-hydroxyphenyl)propanoic
acid were purchased from Merck (Germany). All solvents and chemicals
were used as received without purification. DI water filtered to 18
MΩ·cm was used in all experiments.
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4

Synthesis of Metallic Nanostructures

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Gold(III) chloride trihydrate (≥ 99.9%, HAuCl4 · 3H2O), chloroplatinic acid hexahydrate (≥ 37.50% Pt, H2PtCl6 · 6H2O), sodium borohydride (≥ 98.0%, NaBH4), cetyltrimethylammonium bromide (≥ 98%, CTAB), cetyltrimethylammonium chloride solution (25 wt.% in water, CTAC), L-Ascorbic acid (≥ 99%, AA), sodium hydroxide (NaOH) and dysprosium(III) chloride hexahydrate (≥ 99.9%) were purchased from Sigma-Aldrich (Zwijndrecht, the Netherlands). 90% enriched dysprosium-164 oxide powder (164Dy2O3) was obtained from Oak Ridge National Laboratory (sample number 122502, ORNL, Tennessee, USA). Ethylenediaminetetraacetic acid disodium salt dihydrate (Na2EDTA · 2H2O), Diethylenetriamine pentaacetate (DTPA), hydrochloric acid (HCl, 30%, Suprapur®) and nitric acid (HNO3, 69%, Supelco®) was supplied by Merck. All chemicals were used as received without further purification. MiliQ water was obtained from an in-house MiliQ system (Millipore) and used throughout this study.
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5

Synthesis of Rare-Earth Doped Silica Nanoparticles

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The chemicals were used as received and without further purification. Tetraethoxysilane, titanium(iv) isopropoxide, dysprosium(iii) chloride hexahydrate, holmium(iii) chloride hexahydrate, neodymium(iii) chloride hexahydrate, erbium(iii) chloride hexahydrate, and samarium(iii) chloride hexahydrate were purchased from Sigma-Aldrich. Cobalt(ii) chloride hexahydrate was provided by AnalaR. Iron(iii) chloride hexahydrate was from Fluka. Curcumin (98% purity) and propylene oxide were purchased from Acros Organics. Methanol, hydrochloric acid (37%), and ammonium hydroxide were from Riedel-de-Haen, Panreac and Fischer Scientific, respectively. Double deionized water was prepared in our laboratory.
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