Silver(i ) nitrate was purchased from Lachema (Czech Republic), dimethyl sulfoxide (DMSO), palladium(ii ) acetate (Pd(OAc)2) and 3-bromopyridine from Sigma-Aldrich Chemie, 2-bromopyridine, diisopropyl phosphite and N,N-diisopropylethylamine from Fluka, 1,1′-bis(diphenylphosphino)ferrocene (dppf) from Alfa Aesar, bromotrimethylsilane from Acros, dichloromethane, methanol and acetonitrile from VWR Chemicals.
3 bromopyridine
Manufactured by Merck Group
3-bromopyridine is a chemical compound used in various laboratory applications. It is a derivative of pyridine with a bromine substituent at the 3-position. 3-bromopyridine is commonly used as a versatile building block in organic synthesis and pharmaceutical research.
Automatically generated - may contain errors
Lab products found in correlation
Triphenylphosphine, by Merck Group (2 mentions)
Furan, by Merck Group (2 mentions)
Grubbs second generation catalyst, by Merck Group (2 mentions)
Pentane, by Merck Group (2 mentions)
Dicyclopentadiene, by Merck Group (2 mentions)
Dichloromethane, by Avantor (1 mentions)
Bromotrimethylsilane, by Thermo Fisher Scientific (1 mentions)
Acetonitrile, by Avantor (1 mentions)
Methanol, by Avantor (1 mentions)
Dimethyl sulfoxide (dmso), by Merck Group (1 mentions)
Diisopropyl azodicarboxylate, by Merck Group (1 mentions)
Dichloromethane, by Thermo Fisher Scientific (1 mentions)
Thionyl chloride, by Merck Group (1 mentions)
N phenylmaleimide, by Merck Group (1 mentions)
Methanol, by Merck Group (1 mentions)
Acetonitrile, by Merck Group (1 mentions)
Ethyl acetate, by Merck Group (1 mentions)
Dimethylformamide, by Merck Group (1 mentions)
Tetrahydrofuran, by Merck Group (1 mentions)
Isopropyl alcohol, by Merck Group (1 mentions)
4 protocols using 3 bromopyridine
1
Synthesis of N-Substituted Pyridines
2
Synthesis of Functionalized Norbornene Derivatives
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
Example 1
Materials: The following materials were purchased and used as received.
Dimethyl 5-norbornene-2,3-dicarboxylate (C3) was purchased from Alfa Aesar,
Dichloromethane (DCM) was stored over activated Alumina and purged with Argon before use, Isopropyl alcohol (IPA), dicyclopentadiene (DCPD), 1H,1H,2H-Perflouro-1-octene (PF6), 1H,1H,2H-Perflouro-1-dodecene (PF10), toluene, thionyl chloride, ethylacetate, dimethylformamide (DMF), Maleimide, furan, diisopropylazodicarboxylate (DIAD), triphenylphosphine (Ph3P), 1-haxadecanol, tetrahydrofuran (THF), ethyl acetate, N-phenylMaleimide, acetonitrile, methanol, Grubbs second generation catalyst, 3-bromopyridine, and pentane were obtained from Sigma-Aldrich Co. and used without further treatment. Dichloropentane, also obtained from Sigma-Aldrich Co., was treated with basic alumina before use. Cyclooctadiene (COD) was purified by vacuum distillation from boron trifluoride and used fresh.
3
Synthesis of Ruthenium Catalysts and Ionic Liquids
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
Chromium-coated tungsten
rods were purchased from R.D. Mathis, gold shot (99.99%) was acquired
from J&J Materials, and silicon (100) wafers were obtained from
WRS Materials. A Millipore Elix filtration system was used to produce
deionized water (≥10.0 MΩ).
The following chemicals
were purchased from Sigma-Aldrich and used without further modification:
3-bromopyridine, 4-mercapto-1-butanol (95%), dicyclopentadiene (98%),
Grubbs catalyst second generation [(H2IMes)(PCy3)(Cl)2Ru = CHph], and trans-3,6-endomethylene-1,2,3,6-tetrahydrophthaloyl
chloride (NBDAC). The following chemicals were purchased from Fisher
Scientific and used without further modification: allyl bromide (99%),
1,2-dichloroethane (DCE), 1,2-dimethylimidazole (98%, dMIm), ethanol
(200 Proof), methylene chloride (DCM), potassium bis(fluorosulfonyl)imide
(KFSI), potassium hexafluorophosphate (KPF6), and potassium
perchlorate (KClO4).
Grubbs third generation catalyst
([(H2IMes) (3-Br-py)2(Cl)2Ru = CHPh])
was synthesized as described by
Love et al.30 (link) 3-[(bicyclo[2.2.1]hept-5-en-2-yl)methyl]-1,2-dimethylimidazol-3-ium
hexafluorophosphate ([N1-dMIm][PF6]) was synthesized
as described by Njoroge et al.2 (link)
rods were purchased from R.D. Mathis, gold shot (99.99%) was acquired
from J&J Materials, and silicon (100) wafers were obtained from
WRS Materials. A Millipore Elix filtration system was used to produce
deionized water (≥10.0 MΩ).
The following chemicals
were purchased from Sigma-Aldrich and used without further modification:
3-bromopyridine, 4-mercapto-1-butanol (95%), dicyclopentadiene (98%),
Grubbs catalyst second generation [(H2IMes)(PCy3)(Cl)2Ru = CHph], and trans-3,6-endomethylene-1,2,3,6-tetrahydrophthaloyl
chloride (NBDAC). The following chemicals were purchased from Fisher
Scientific and used without further modification: allyl bromide (99%),
1,2-dichloroethane (DCE), 1,2-dimethylimidazole (98%, dMIm), ethanol
(200 Proof), methylene chloride (DCM), potassium bis(fluorosulfonyl)imide
(KFSI), potassium hexafluorophosphate (KPF6), and potassium
perchlorate (KClO4).
Grubbs third generation catalyst
([(H2IMes) (3-Br-py)2(Cl)2Ru = CHPh])
was synthesized as described by
Love et al.30 (link) 3-[(bicyclo[2.2.1]hept-5-en-2-yl)methyl]-1,2-dimethylimidazol-3-ium
hexafluorophosphate ([N1-dMIm][PF6]) was synthesized
as described by Njoroge et al.2 (link)
4
Organometallic Heterocycle Synthesis
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
Furan, maleic anhydride, 3-bromopropylamine hydrobromide, 1-bromohexane, 3-aminomethyl pyridine, triphenylphosphine, cysteamine, hydrogen tetrachloroaurate(III), sodium borohydride, ethylvinyl ether, 3-bromopyridine, acetic anhydride, petroleum ether, diethyl ether,
N,N-dimethylformamide (DMF),
N,N-dimethylacetamide (DMAc), dichloromethane (DCM), chloroform, pentane, dimethyl sulfoxide (DMSO) were purchased from Sigma Aldrich and used as received. Ethyl acetate and hexane were distilled by conventional techniques. Grubbs second generation catalyst was purchased from Sigma Aldrich. Grubbs third generation catalyst [(H2-Imes)(3-Br-py)2-(Cl)2Ru=CHPh] was freshly prepared according to the previously reported procedure [38]. Phosphate buffered saline (PBS) was obtained from Sigma Aldrich in tablet form. Mueller–Hinton broth (MHB) and Mueller–Hinton agar (MHA) media (both from Dıfco, BD Diagnostic Systems, United States) were used for microbiological tests.
Staphylococcus aureusATCC 25923 strain and
Escherichia coliATCC 25922 strain were acquired from the department of Molecular Biology and Genetics Department (Yildiz Technical University, Turkey) and used as representative of Gram-positive and Gram-negative bacteria, respectively (ATCC is the registered trademark of American Type Culture Collection).
N,N-dimethylformamide (DMF),
N,N-dimethylacetamide (DMAc), dichloromethane (DCM), chloroform, pentane, dimethyl sulfoxide (DMSO) were purchased from Sigma Aldrich and used as received. Ethyl acetate and hexane were distilled by conventional techniques. Grubbs second generation catalyst was purchased from Sigma Aldrich. Grubbs third generation catalyst [(H2-Imes)(3-Br-py)2-(Cl)2Ru=CHPh] was freshly prepared according to the previously reported procedure [38]. Phosphate buffered saline (PBS) was obtained from Sigma Aldrich in tablet form. Mueller–Hinton broth (MHB) and Mueller–Hinton agar (MHA) media (both from Dıfco, BD Diagnostic Systems, United States) were used for microbiological tests.
Staphylococcus aureusATCC 25923 strain and
Escherichia coliATCC 25922 strain were acquired from the department of Molecular Biology and Genetics Department (Yildiz Technical University, Turkey) and used as representative of Gram-positive and Gram-negative bacteria, respectively (ATCC is the registered trademark of American Type Culture Collection).
About PubCompare
Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.
We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.
However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.
Ready to get started?
Sign up for free.
Registration takes 20 seconds.
Available from any computer
No download required
Revolutionizing how scientists
search and build protocols!