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3 protocols using 1 octadecene 1 ode

1

Synthesis of CsPbBr3 Perovskite Nanocrystals

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Lead(II) bromide (PbBr2, 98%, Sigma-Aldrich, Madrid, Spain), cesium carbonate (Cs2CO3, 99.9%, metals basis, Alfa Aesar, Karlsruhe, Germany), oleylamine (OAm) (technical grade, 70%, Sigma-Aldrich), oleic acid (OA) (technical grade, 90%, Sigma-Aldrich), 1-octadecene (1-ODE) (95%, Sigma-Aldrich), ethyl acetate (Sigma-Aldrich), n-hexane (99%, spectrophotometric grade, Sigma-Aldrich), (poly(3,4-ethylenedioxythiophene) (PEDOT:PSS), and isopropanol (99%, technical grade, Sigma-Aldrich), were used for the synthesis of CsPbBr3 PNCs and fabrication of layers. The ligand exchange was performed using 3-mercaptopropionic acid (99%, MPA, Sigma-Aldrich). All chemicals were used without further purification.
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2

Synthesis of Semiconductor Nanocrystals

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Polyacrylonitrile (PAN, Mw = 150 000) was purchased from Sigma Aldrich (USA). N,N-Dimethylformamide (DMF) was purchased from Sigma Aldrich (USA). CdO (99.9%), oleic acid (OA, 90%), 1-octadecene (1-ODE, 90%), trioctylphosphine (TOP, 97%), and Se powder (99.99%) were purchased from Sigma Aldrich. PbO (99.99%), bis(trimethylsilyl)sulfide ((TMS)2S, synthesis grade), InCl3 (98%), ZnCl2 (97%), oleylamine (70%), tris(dimethylamino)phosphine (P(DMA)3, 97%), 1-dodecanethiol (DDT, 98%), CuI (99.999%), indium acetate (99.99%), zinc acetate (99.99%), sulfur (99.998%), zinc diethyldithiocarbamate (Zn DDTC, 97%), cadmium acetate (99.995%), ZnO (99.999%), sodium sulfide nonahydrate (98+%), and sodium sulfite (≥98%) were purchased from Sigma Aldrich.
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3

Methylammonium Lead Iodide Perovskite Synthesis

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All materials were reagent
grade and were used as received. Lead iodide (PbI2, >98%,
from TCI), cesium carbonate(Cs2CO3, >99%,
from
Sigma Aldrich), guanidinium acetate salt (GAOAc, >99%, from Sigma
Aldrich), oleic acid (OA, technical grade 90%), oleylamine (OLA, technical
grade 98% from Sigma Aldrich), 1-octadecene (1-ODE, technical grade
90% from Sigma Aldrich), hexane (reagent grade 97%), methyl acetate
(MeOAc, anhydrous 99.5% from Sigma Aldrich), 2-propanol (99.7% from
Carlo Erba), ethanol (96%) and acetone (99.25%) (from PanReac), hydrochloric
acid (HCl 37%), zinc powder (99.995%), PEDOT:PSS (Clevios 4083from
Heraeus), Al, lithium fluoride (LiF, from Lumtec), PO-T2T (from Lumtec),
and poly-TPD (from Lumtec) were used. EPOXY encapsulation (from Lumtec)
and indium tin oxide (ITO)-coated glass substrates (Pilkington TEC15,
∼15 Ω sq–1) were also used.
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