Zirconium oxychloride

Manufactured by Merck Group

Sourced in India, United States

Zirconium oxychloride is a chemical compound used as a laboratory reagent. It is a white, crystalline solid with the chemical formula ZrOCl2. The compound is soluble in water and is commonly used in various analytical and research applications.

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Close spelling variants of this product

Zirconium oxychloride octahydrate Zirconium oxychloride hydrate Zirconium(IV) oxychloride octahydrate

7 protocols using zirconium oxychloride

Fumaric Acid Metal-Organic Framework Synthesis

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Fumaric acid (

C_{4} H_{4} O_{4}

, purity ≥ 99.0%), Zirconium oxychloride octahydrate (ZrO

{Cl}_{2}

·8

H_{2}

O, purity ≥ 99.5%), Formic acid (HCOOH, purity ≥ 98.0%), N,N’-dimethylformamide (DMF, HPLC grade), Ethanol (purity ≥ 99.0%), MEthanol (HPLC grade), and Sulfuric acid (purity: 95–97%) all from Sigma-Aldrich Co, and Deionized water. It is noteworthy that all the materials were used without any additional treatment.

Aghajani Hashjin M., Zarshad S., Motejadded Emrooz H.B, & Sadeghzadeh S. (2023). Enhanced atmospheric water harvesting efficiency through green-synthesized MOF-801: a comparative study with solvothermal synthesis. Scientific Reports, 13, 16983.

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Graphite-based Nanomaterial Synthesis and Evaluation

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Graphite powder (100 mesh,
99.9% pure), potassium permanganate (KMnO₄, >99%), sulfuric
acid (H₂SO₄, 98%), hydrogen chloride (HCl, 36%),
hydrogen peroxide (H₂O₂, 30%), and zirconium
oxychloride (ZrOCl₂·8H₂O, >99%) were
obtained
from Sigma Aldrich Bangalore, India. Sodium nitrate (NaNO₃, AR grade, Qualigens, India), Dulbecco’s modified Eagle’s
medium (DMEM, HI Media), fetal bovine serum (FBS, HI Media), α-minimum
essential medium (α-MEM, Gibco/Life Technologies), 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium
bromide (MTT, HI Media), 1% pen/strep (HI Media), human umbilical
cord blood-derived mesenchymal stem cells (hMSCs) (PromoCell, Germany),
human colon (HCT116) and lung (A549) carcinoma cell lines (National
Sciences for Cell Sciences, NCCS, Pune, India, American Type Culture
Collection, ATCC), Drug Cisplat (cisplatin injection I.P. 50 mg/50
mL, Zydus Oncosciences), and double-distilled water were used throughout
the experiment.

Kanth Kadiyala N., Mandal B.K., Kumar Reddy L.V., Barnes C.H., De Los Santos Valladares L, & Sen D. (2023). Efficient One-Pot Solvothermal Synthesis and Characterization of Zirconia Nanoparticle-Decorated Reduced Graphene Oxide Nanocomposites: Evaluation of Their Enhanced Anticancer Activity toward Human Cancer Cell Lines. ACS Omega, 8(2), 2406-2420.

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Antimicrobial Nanomaterial Synthesis and Evaluation

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Ferric nitrate nonahydrate (Fe(NO₃)₃·9H₂O), zinc nitrate (Zn(NO₃)₂·6H₂O), aluminum nitrate nonahydrate (Al(NO₃)₃·9H₂O), cobalt nitrate hexahydrate (Co(NO₃)₂·6H₂O), nickel nitrate hexahydrate (Ni(NO₃)₂·6H₂O), zirconium oxychloride (ZrOCl₂·8H₂O), and sodium hydroxide were purchased from Sigma-Aldrich. All solutions and experiments were prepared and conducted by suspending the nanomaterials using deionized water (DW) and sonication with the Ultrasonic Processor at 220 V/50 Hz (Model FS/000100/T). Different media types were used in this study according to the microorganism type, such as Muller Hinton broth and Muller Hinton agar for bacterial growth, while Sabarouds Dextrose Agar (SDA) and Sabarouds Dextrose Broth (SDB) were used for fungus growth using a typical or standard antifungal treatment (cyclohexamide-growing fungi and doxycycline-standard for both Gram-positive and Gram-negative bacteria).

Mahmoud R., Eldin Z.E., Khalifa A., Ahmed Anwar A.A., GadelHak Y., Othman S.I., Allam A.A., Essam D., Abo El-Ela F.I., Aleem Abdel Aziz S.A, & Zaher A. (2024). Antifungal and antibacterial investigation of quinary Zr Al Fe Co Ni layered double hydroxide and its Al Fe Co Ni quaternary and Fe Co Ni tertiary roots. RSC Advances, 14(21), 14815-14834.

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Soil Sample Pretreatment for XRF Analysis

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Calcium oxide (96%), perchloric acid (85%), nitric acid (60%), lanthanum oxide (99%), ammonium acetate (97%), sulfanilic acid azochromotrop (SPANDS), and lanthanum alizarin complexone solution were purchased from Daejung Chemicals (Gyunggi, South Korea). Sodium hydroxide (98%), aqueous ammonia (25%), hydrochloric acid (35%), acetic acid (99.5%), and acetone (99.5%) were obtained from OCI Company Ltd.
(Seoul, South Korea). Zirconium oxychloride (35%) and boric acid (99.5%) were obtained from Sigma-Aldrich (Pittsburgh, PA, USA), and nitrophenol (99%) was purchased from Alfa Aesar (Heysham, UK). Sodium acetate trihydrate (98.5%) was obtained from Samchun (Gyunggi, South Korea), and Total Ionic Strength Adjustment Buffer (TISAB) III and ion control solutions were obtained from Fisher Scientific (Pittsburgh, PA, USA). The chemicals were used as received without further purification, and all solutions used in the experiment were prepared with deionized water produced using Nex Power 1000 (Human, Seoul, South Korea). The liquid-binder aqueous additive for the pretreatment of soil samples for XRF analysis was purchased from Chemplex Industries Inc. (Palm City, FL, USA).

Oh S.Y., Kim H, & Yoon H.O. (2024). Fluorine contamination, mobility, and risks in soils at a phosphate-gypsum waste landfill: a new analytical method and comparison with previous methods. Environmental geochemistry and health, 46(5).

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PVA-Propolis Composite Preparation and Characterization

Cited 1 time

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The polyvinyl alcohol polymer matrix used in this research was obtained from Sigma-Aldrich Chemical Company (Darmstadt, Germany). The series of samples using different PVA molecular weights Mowiol 20–98 (Mw = ~125 kDa, degree of hydrolysis 98.0–98.8) and polyvinyl alcohol 18–88 (Mw = ~130 kDa, degree of hydrolysis 86.7–88.7) were performed; the melting point was 200 °C and the density was 1.269 g/cm³. The total flavonoids content was determined according to [23 (link)], using zirconium oxychloride (98%, Mw = 322.25, Sigma-Aldrich) and methanol (99.9%, Mw = 32.04%, Sigma-Aldrich). The ethyl alcohol (96.4–96.6%, Mw = 46.07, SIA Kalsnavas Elevators, Jaunkalsnava, Latvia) used to prepare the laboratory-made propolis extracts. The extract from Riga Pharmaceutic Factory (Riga, Latvia) contains 70% ethyl alcohol extract. Various types of propolis and its extracts were used (Table 7). The stages of the solution-mixing process are designated as marked (Figure 3). Laboratory distilled water (conductivity 1 µS/cm) was used to prepare PVA solutions and propolis extracts.

Zelca Z., Kukle S., Janceva S, & Vilcena L. (2022). Propolis Integration Methods into Solutions for Highly Loaded Propolis Fibers by Needleless Electrospinning. Molecules, 27(7), 2311.

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Synthesis of PA6 Polymer Composite

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PA6 (Commercial grade 1030B)
with a melt flow index of 4.6 ± 0.23 g/10 min (at 250 °C
under a 2.16 kg load), a weight average molecular weight of 30 kg/mol,
a density of 1.14 g/cm³, and a melting point of 220 °C,
was obtained from UBE Industries Ltd., Tokyo, Japan. Zirconium oxychloride
(ZrOCl₂·8H₂O), acetonitrile, bPEI, HCCP,
and phosphoric acid (98%) were purchased from Sigma-Aldrich, Johannesburg,
South Africa and used as received without purification.

Malkappa K., Bandyopadhyay J, & Ray S.S. (2020). Design of Poly(cyclotriphosphazene)-Functionalized Zirconium Phosphate Nanoplatelets To Simultaneously Enhance the Dynamic Mechanical and Flame Retardancy Properties of Polyamide 6. ACS Omega, 5(23), 13867-13877.

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Polymer-Guided Silica-Zirconia Nanocomposites

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A poly(ethylene glycol) PEG-400 or a Pluronic® F-127 copolymer of ethylene oxide (E) and propylene oxide (P), were used for the emulsion formation. Reactants, Pluronic® F-127 (E 106 -P 70 -E 106 ), PEG-400 (E 9 ), tetraethoxysilane (TEOS) (Si(OEt) 4 ), calcium chloride (CaCl 2 ,2H 2 O), and zirconium oxychloride (ZrOCl 2 ,8H 2 O) were purchased from Sigma-Aldrich and used as received.

Guyot M., Daurat C., Vuillet-A-Ciles V., Pontille L., Le Porcher B., Chiriac R., Toche F., Chassagneux F., Toury B, & Bois L. (2021). Foam Silica Films Synthesized by Calcium Chloride-Assisted Emulsification. Langmuir : the ACS journal of surfaces and colloids, 37(15).

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