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2 protocols using tin 2 chloride dihydrate

1

Perovskite Solar Cell Fabrication

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Titanium tetraisoproxide (TTIP, >97.0%), N,N-dimethylformamide (DMF, dehydrated, >99.5%), dimethyl sulfoxide (DMSO, dehydrated, 99.0%), 2-Propanol (IPA, dehydrated, >99.7%), and acetonitrile (dehydrated, >99.5%) were purchased from Kanto Chemical Co., Inc. (Portland, OR, USA). Spiro-MeOTAD, chlorobenzene (CB, anhydrous, 99.8%), Terpineol (anhydrous), and 4-tert-butylpyridine (TBP, 98%) were obtained from Sigma-Aldrich, Co. (St, Louis, MI, USA). Methylamine hydrobromide (MABr, >98.0%), Cesium iodide (CsI, >99.0%), Formamidine hydroiodide (FAI, 99.99%), Lead(II) iodide (PbI2, 99.99%), Lithium bis(trifluoromethanesulfonly)imide (Li-TFSI, >98.0%), and Formamidine hydrobromide (FABr, 99.99%) were purchased from Tokyo Chemical Industry Co., Ltd. (Tokyo, Japan). Polyethylene glycol 400 (PEG400) and Tin(II) chloride dihydrate (SnCl2·2H2O, >97.0%) were from FUJIFILM Wako Pure Chemical Corporation, Richmond, VA, USA. All chemicals were used as purchased.
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2

Optimized Silver Mirror Synthesis

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All reagents used in the present study were of analytical reagent grade unless otherwise specified. Milli-Q water (Millipore Reagent Water System, Bedford, MA, USA) was used in all of the experiments. Dilute nitric acid, sulfuric acid, ethanol, potassium hydroxide, glucose and sodium chloride were obtained from Kanto Chemical Co. (Tokyo, Japan). Hydrogen peroxide, a silver nitrate solution, an ammonia solution, saccharin, tin(II) chloride dihydrate and hydrochloric acid were purchased from Fujifilm Wako Pure Chemical (Tokyo, Japan). The silver powder was obtained from Nilaco (Tokyo, Japan). Tollens' reagent used for the silver-mirror reaction was prepared using a silver nitrate solution, an ammonia solution and potassium hydroxide. The silver plating solution was prepared by diluting solution 4 times with a 137 ppm saccharin solution.
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