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Ksg 15

Manufactured by Shin-Etsu Chemical

The KSG-15 is a laboratory equipment product offered by Shin-Etsu Chemical. It is designed for the precise measurement and monitoring of various parameters. The core function of the KSG-15 is to provide accurate and reliable data for laboratory research and analysis purposes.

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14 protocols using ksg 15

1

Roll-on Antiperspirant Formulation

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Example 24

(Component)Weight (%)
1.Cross-linked, polyether-modified silicone (Note 1)20.0
2.Cross-linked dimethylpolysiloxane (Note 2)15.0
3.Dimethylpolysiloxane, 6 mm2/sec at 25 degrees C.10.0
4.Decamethylcyclopentasiloxane30.0
5.Aluminum zirconium tetrachlorohydrate20.0
6.Treated powder 94.9
7.Perfume0.1
(Note 1)
Cross-linked, polyether-modified silicone: KSG-210, ex Shin-Etsu Chemical Co. Ltd.
(Note 2)
Cross-linked dimethylpolysiloxane: KSG-15, ex Shin-Etsu Chemical Co. Ltd.
Preparation Method
A: Components 1 to 4 were mixed uniformly.
B: Components 5 to 7 were added to the mixture obtained in the step A and dispersed uniformly.

The roll-on type antiperspirant obtained had refreshing feeling, and had no stickiness or oiliness. The makeup did not change with time or in temperature change, and, the usability and the stability were excellent.

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2

Formulation and Characterization of O/W Emollient Cream

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Example 12

(Ingredients)Mass (%)
1.Crosslink type dimethylpolysiloxane (*1)7.0
2.Crosslink type dimethylpolysiloxane (*2)30.0
3.Acryl silicone resin (*3)3.0
4.Decamethylcyclopentasiloxane8.0
5.1,3-Butylene glycol4.0
6.Branched type polygrycerin modified silicone (*4)0.6
7.Silicone compound (17)0.3
8.Copolymer of acrylamide/Na acryloyldimethyl-0.6
taurate (*5)
9.Copolymer of ammonium acryloyldimethyl-0.7
taurate/VP (*6)
10.Sodium chloride0.1
11.Purified water45.7
Sum: 100.0
(*1) KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(*2) KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(*3) KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(*4) KF-6104 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(*5) Simugel 600 (manufactured by SEPPIC)
(*6) Aristoflex AVC (manufactured by CLARIANT)
(Production Method)
A: Ingredients 1 to 4 were mixed uniformly.
B: Ingredients 5 to 11 were mixed uniformly.
C: The mixture obtained in A was gradually added to the mixture obtained in B with stirring and mixed with each other to give O/W emollient cream.

The O/W emollient cream thus obtained showed smoothness with no greasiness, had a light spreading property, and maintained an effect to protect skin.

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3

Emulsified Silicone-Based Skin Cream

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Example 11

TABLE 5
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 45.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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4

Formulation of Silicone-Based Emollient Cream

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Example 12

(Component)Mass (%)
1. Crosslinked dimethylpolysiloxane (note 1)7.0
2. Crosslinked dimethylpolysiloxane (note 2)30.0
3. Acrylic silicone resin (note 3)3.0
4. Decamethylcyclopentasiloxane8.0
5. 1,3-butylene glycol4.0
6. Branched polyglycerin-modified silicone (note 4)0.6
7. Silicone compound (IV)0.3
8. (Acrylamide/sodium acryloyldimethyltaurate) copolymer0.6
(note 5)
9. Dimethyl taurine ammonium acrylate/VP copolymer0.7
(note 6)
11. Sodium chloride0.1
12. Purified water45.7
Sum total100.0
(note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-15
(note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-16
(note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: KP-545
(note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6104
(note 5) Manufactured by Seppic, Inc.: SIMULGEL 600
(note 6) Manufactured by Clariant, Ltd.: ARISTOFLEX AVC
(Preparation of Cosmetic)
A: Components 1 to 4 were homogeneously mixed.
B: Components 5 to 11 were homogeneously mixed.
C: Under stirring, the A was gradually added to the B to emulsify, and an O/W emollient cream was obtained.

The O/W emollient cream obtained like this had refreshing feeling without greasiness, light spread, and a lasting skin protecting effect.

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5

Formulating a Cosmetic Cream with Silicone Components

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Example 12

TABLE 6
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 55.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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6

Water-in-Oil Cream Formulation

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Example 5

Water-in-Oil Cream

    • A: Ingredients (1) to (4) were uniformly mixed.
    • B: Ingredients (5) to (10) were uniformly mixed
    • C: Component B was added to Component A and emulsification carried out, giving a water-in-oil emulsion.

(1)Crosslinked polyglycerol-modified silicone 6)4%
(2)Crosslinked dimethylpolysiloxane 7)1
(3)Silicone-branched polyglycerin-modified3
silicone 3)
(4)Dimethylpolysiloxane (6 cs)13
(5)1,3-Butylene glycol8
(6)Ethanol5
(7)Phenoxyethanol0.3
(8)Sodium citratesuitable amount
(9)Sodium chloridesuitable amount
(10) Purified waterbalance
Total100.0

6) KSG-710 (Shin-Etsu Chemical Co., Ltd)

7) KSG-15 (Shin-Etsu Chemical Co., Ltd)

This cream had a moisturizing feel and also had a good feel on use. When the silicone-branched polyglycerin-modified silicone of the invention is substituted with a conventional substance, the cream that uses the conventional substance, as with the results shown in Table 1, becomes a cream that clearly feels sticky.

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7

Cosmetic Cream Formulation and Evaluation

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Example 10

TABLE 4
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 35.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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8

Silicone-based Cosmetic Cream Formulation

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Example 13

TABLE 7
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 65.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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9

Sun-Cut Cream Formulation and Evaluation

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Example 8

(Component)Mass (%)
1. Crosslinked glycerin-modified silicone (note 1)2.0
2. Crosslinked dimethylpolysiloxane (note 2)3.0
3. Siloxane compound (V)1.5
4. Acryl silicone resin (note 3)4.5
5. Decamethylcyclopentasiloxane5.8
6. Dimethyldistearylammonium hectrite1.2
7. Titanium dioxide dispersio(note 4)20.0
8. Zinc oxide dispersion (note 5)15.0
9. 1,3-butylene glycol5.0
10. Sodium citrate0.2
11. Sodium chloride0.5
12. Purified waterBalance
Sum total100.0
(note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-810
(note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-15
(note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: KP-549
(note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: SPD-T6
(note 5) Manufactured by Shin-Etsu Chemical Co., Ltd.: SPD-Z6
(Preparation of Cosmetic)
A: Components 1 to 8 were homogeneously mixed.
B: Components 9 to 12 were mixed.
C: The B was added to the A to emulsify, and a sun-cut cream was obtained.

The sun-cut cream obtained like this had no stickiness, light spread, no greasiness, and excellent cosmetic durability.

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10

Formulation of Emulsion-Type Antiperspirant

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Example 26

  • Step A: Components 10 to 14 were mixed.
  • Step B: Component 15 was dissolved in component 16.
  • Step C: The mixture obtained in step B was gradually added to the mixture obtained in step Awhile stirring to be emulsified to obtain an emulsion type antiperspirant.

TABLE 14
Example(%)
Roll-on Emulsification
typetype
Component4243
1. Crosslinked polyether-modified silicone 10.0
composition (note 46)
2. Dimethyl polysiloxane (viscosity 6 mm2/s)10.0
3. Crosslinked silicone composition (note 47)14.3
4. Decamethylcyclopentasiloxane30.0
5. Copolymer (A) of Example (4)10.5
6. Organically modified bentonite0.2
7. Aluminum zirconium tetrachlorohydrate20.0
8. Silicone treated zinc oxide5.0
9. PerfumeProper
amount
10. Hexamethyldisiloxane20.0
11. Isododecane10.0
12. Copolymer (A) of Example (6)2.0
13. Oleyl polyether modified silicone 1.0
(note 48)
14. POE monooleate (20 mol) sorbitan0.5
15. Glycine salt of aluminum zirconium 20.0
tetrachloride hydrate
16. Purified waterThe rest
(Note 46)
KSG-210 manufactured by Shin-Etsu Chemical Co., Ltd.
(Note 47)
KSG-15 manufactured by Shin-Etsu Chemical Co., Ltd.
(Note 48)
KF-6026 manufactured by Shin-Etsu Chemical Co., Ltd.

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