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2 protocols using lead 2 acetate trihydrate

1

Synthesis of Semiconductor Nanocrystals

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Cadmium oxide (CdO, 99.5%), trioctylphosphine
oxide (99%), trioctylphosphine (TOP, 97%), selenium powder (Se, 99.99%),
and lead(II) acetate trihydrate (Pb(CH3CO2)2·3H2O, 99.999%) were purchased from Strem
Chemicals. Octadecylphosphonic acid (99%) was purchased from Polycarbon
Industries. Copper(II) acetylacetonate (Cu(acac)2, 97%),
hexadecylamine (98%), tetrakis(acetonitrile)copper(I) hexafluorophosphate
(99.99%), octadecene (technical grade, 90%), 1-dodecanethiol (≥98%),
oleylamine (70%), tetrachloroethylene (≥99%), anhydrous chloroform,
methanol, toluene, and tetrahydrofuran were purchased from Sigma-Aldrich.
All chemicals were used without any further purification.
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2

Synthesis of Metal-Based Photocatalysts

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Cadmium (II) chloride (CdCl2, 99+%), copper (II) acetate (Cu(ac)2, 99%), copper (II) chloride (CuCl2, 98%), copper (II) nitrate trihydrate (Cu(NO3)2·3H2O, 99.5%), copper (II) sulfate (CuSO4, 98%), and lead (II) acetate trihydrate (Pb(ac)2·3H2O, 99.999%) were purchased from Strem Chemicals (Newburyport, MA, USA). Hydrazine monohydrate (98%), hydrogen peroxide (H2O2, 30% wt.), methylene blue (MB), and rhodamine 6G (Rh6G, 95%) were purchased from Sigma-Aldrich (St. Louis, MI, USA). Sodium hypochlorite (11–14% wt. available chlorine, assay result (iodometric titration) of 11.8% wt.) and rhodamine B (RhB) were purchased from Alfa Aesar (Heysham, Lancashire, UK). Hydrochloric acid (HCl, 32% wt.) was purchased from Bio-Lab (Jerusalem, Israel). All reagents were used as received without further purification. Deionized (DI) water was purified using a Millipore Direct-Q system (18.2 MΩ cm resistivity).
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