Bis(triphenylphosphine)palladium(ii ) dichloride, triphenylphosphine, copper(i ) iodide, 1-bromo-4-tert-butylbenzene, 1,4-dibromobenzene, sodium hydride, iodomethane, 2-methyl-3-butyn-2-ol, tetrahydrofuran (THF), triethylamine, N,N-dimethylformamide (DMF), chloroform (CHCl3), methanol (MeOH), trifluoroacetic acid (TFA), dimethyl sulfoxide (DMSO) (Fujifilm Wako Pure Chemical (Wako)), chlorotrimethylsilane (Tokyo Chemical Industry), n-butyllithium (Kanto Chemical), tantalum(v ) chloride, and phenylacetylene (Sigma-Aldrich) were used without additional purification. n-Bu4Sn (cocatalyst for polymerization, Wako) and toluene (solvent for polymerization, Wako) were distilled over CaH2 (Wako) prior to use. 1-(p-Trimethylsilyl)phenyl-1-propyne (SPP),21 (link) 4-(tert-butyl)diphenylacetylene (BDPA),10 (link) and 4-(trimethylsilyl)diphenylacetylene (SDPA)11 (link) were prepared according to the literature.
N butyllithium
Manufactured by Kanto Chemical
N-butyllithium is a colorless, flammable, pyrophoric organometallic compound. It is a strong base used as a reagent in organic synthesis for the preparation of other organolithium compounds.
Automatically generated - may contain errors
Lab products found in correlation
Dimethyl sulfoxide (dmso), by Fujifilm (1 mentions)
Chloroform, by Fujifilm (1 mentions)
Trifluoroacetic acid, by Fujifilm (1 mentions)
Phenylacetylene, by Merck Group (1 mentions)
N bu4sn, by Fujifilm (1 mentions)
Silica gel 60 f254, by Merck Group (1 mentions)
Aluminum oxide 60 f 254, by Merck Group (1 mentions)
2 protocols using n butyllithium
1
Synthesis of Functionalized Alkyne Monomers
2
Synthesis and Characterization of Copper(II) Complexes
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
The reactions were monitored by
TLC using Merck “Aluminum oxide 60 F254 neutral,
aluminum sheets” and Merck “Silica gel 60 F254, aluminum sheets”. Column chromatography was carried out
with the use of Al2O3 (Alumina activated 300,
Nacalai Tesque). The reagents used without additional purification
included 2-bromo-3-formylpyridine (96%, Sigma-Aldrich), 5-bromonicotinaldehyde
(97%, Sigma-Aldrich), 6-bromo-3-formylpyridine (95%, Sigma-Aldrich),
3-bromo-2-methylpyridine (97%, Sigma-Aldrich), 3-bromo-5-methylpyridine
(97%, Sigma-Aldrich), 5-bromo-2-methylpyridine (99%, Sigma-Aldrich), n-butyllithium (1.6 M in n-hexane, Kanto
Chemical Co., INC), ethyl formate (FUJIFILM Wako Pure Chemical Corporation),
and PbO2 (FUJIFILM Wako Pure Chemical Corporation). Cu(hfac)2,33 (link) 2,3-bis(hydroxyamino)-2,3-dimethylbutane,34 (link) and 2-methylnicotin aldehyde, 5-methylnicotin
aldehyde, and 6-methylnicotin aldehyde35 were synthesized by standard procedures. C, H, and N elemental analyses
were carried out on a 2400 CHNS/O Series II System (100V) analyzer.
Thermogravimetric and differential thermal analysis (TG-DTA) for polycrystalline
samples [Cu(hfac)2L5-Me ]2, [Cu(hfac)2L5-Br ]2, and [Cu(hfac)2L6-Me ]2 was performed using SII EXSTAR TGA operating
under dry nitrogen with heating from 300 to 500 K at a rate of 5 K/min.
TLC using Merck “Aluminum oxide 60 F254 neutral,
aluminum sheets” and Merck “Silica gel 60 F254, aluminum sheets”. Column chromatography was carried out
with the use of Al2O3 (Alumina activated 300,
Nacalai Tesque). The reagents used without additional purification
included 2-bromo-3-formylpyridine (96%, Sigma-Aldrich), 5-bromonicotinaldehyde
(97%, Sigma-Aldrich), 6-bromo-3-formylpyridine (95%, Sigma-Aldrich),
3-bromo-2-methylpyridine (97%, Sigma-Aldrich), 3-bromo-5-methylpyridine
(97%, Sigma-Aldrich), 5-bromo-2-methylpyridine (99%, Sigma-Aldrich), n-butyllithium (1.6 M in n-hexane, Kanto
Chemical Co., INC), ethyl formate (FUJIFILM Wako Pure Chemical Corporation),
and PbO2 (FUJIFILM Wako Pure Chemical Corporation). Cu(hfac)2,33 (link) 2,3-bis(hydroxyamino)-2,3-dimethylbutane,34 (link) and 2-methylnicotin aldehyde, 5-methylnicotin
aldehyde, and 6-methylnicotin aldehyde35 were synthesized by standard procedures. C, H, and N elemental analyses
were carried out on a 2400 CHNS/O Series II System (100V) analyzer.
Thermogravimetric and differential thermal analysis (TG-DTA) for polycrystalline
samples [Cu(hfac)2L
under dry nitrogen with heating from 300 to 500 K at a rate of 5 K/min.
About PubCompare
Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.
We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.
However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.
Ready to get started?
Sign up for free.
Registration takes 20 seconds.
Available from any computer
No download required
Revolutionizing how scientists
search and build protocols!