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2 protocols using silver nitrate

1

Synthesis of Novel Polymer Electrolytes

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All reagents were purchased from suppliers: (i) Merck (alkylating agents, hexamethylenetetramine, triethylenetetramine, isophorone diamine, lithium bis(trifluoromethylsulfonyl)imide, sodium dicyanamide, ethylene glycol, organic solvents, reagents necessary to perform analyzes), and (ii) abcr GmbH (bisphenol A diglycidyl ether, DGEBA, silver nitrate). The minimum purity for alkylating agents, amines (beyond triethylenetetramine—97%) and compounds used for metathesis is 99%, while all solvents had a minimum HPLC grade. DGEBA was 85% purity.
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2

Synthesis of Colloidal Metal Nanocrystals

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Cadmium oxide (CdO, 99.998%), methanol (anhydrous, 99.9%), and selenium (Se, 99.999%) were purchased from Alfa Aesar. Bis(trimethylsilyl)sulfide (97%), silver nitrate (99.85%), tri-n-butylphosphine (97%), tri-n-octylphosphine oxide (TOPO, 99%) and tri-n-octylphosphine (TOP, 97%) were purchased from ABCR. Toluene (99.9%) and methanol (≥99.5%) were purchased from Carl Roth. Octadecylphosphonic acid (ODPA, ≥99%), hexylphosphonic acid (HPA, ≥99%), and tributyl phosphine (97%) were purchased from PCI Synthesis. Cadmium nitrate tetrahydrate (99%), hydrogen peroxide (H 2 O 2 , 35%), lead acetate trihydrate (>99%), mercaptopropionic acid (MPA, 99%), mercury chloride (99.5%), octadecene (ODE, 90%), potassium hydroxide (KOH, ≥85%), sulfur (S, 99.98%), tetrakis (acetonitrile)copper hexafluorophosphate ([Cu(CH 3 CN) 4 ]PF 6 , 97%) were purchased from Sigma Aldrich. Acetone (dried, 99.9%) was purchased from Merck.
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