For the in situ growth of ZIF-8, the raw chemicals zinc nitrate hexahydrate (Zn(NO3)2·6H2O), sodium hydroxide (NaOH) and 2-methylimidazole (2-mim) with purity over 99.0% were purchased from Sigma-Aldrich. For the electrospinning (ES), polyacrylonitrile (PAN) with an average molecular weight of 150 000 was chosen as polymer with a purity of 99.0%. The PAN was purchased from Parchem fine & specialty Co., Ltd N,N-Dimethylformamide (DMF) with purity of 99.0% was purchased from Sigma-Aldrich. Besides, the solvent of methanol and ethanol with purity of 99.9% were purchased from Sigma-Aldrich. The deionized water (D.I.W) was produced in the laboratory by an ultrapure system with a resistivity of 18.0 mΩ cm−1. All chemicals used in this work have not been further treated or purified. High purity gases of CO2 (99.99 mol%), CH4 (99.99 mol%), He (99.99 mol%) and N2 (99.99 mol%) (Foshan Huate Gas Co., Ltd, China) were used for gas adsorption experiments.
2 methylimidazole 2 mim
Manufactured by Merck Group
Sourced in United States, Cameroon
2-methylimidazole (2-MIM) is a heterocyclic organic compound with the molecular formula C4H6N2. It is a white crystalline solid used as a chemical intermediate in various industrial and pharmaceutical applications.
Automatically generated - may contain errors
Lab products found in correlation
Methanol, by Merck Group (4 mentions)
Zinc nitrate hexahydrate zn no3 2 6h2o, by Merck Group (4 mentions)
Zinc nitrate hexahydrate, by Merck Group (3 mentions)
Sodium hydroxide (naoh), by Merck Group (1 mentions)
N n dimethylformamide (dmf), by Merck Group (1 mentions)
Zinc nitrate hexahydrate zn no3 6h2o, by Merck Group (1 mentions)
Pebax mh 1657, by Arkema (1 mentions)
Udel p 3500 lcd, by Solvay (1 mentions)
Dimethyl sulfoxide (dmso), by Sinopharm (1 mentions)
Collagen 1, by Santa Cruz Biotechnology (1 mentions)
Live dead baclight, by Thermo Fisher Scientific (1 mentions)
α sma, by Santa Cruz Biotechnology (1 mentions)
Palladium acetylacetonate, by Sinopharm (1 mentions)
Rosiglitazone, by Solarbio (1 mentions)
Cell counting kit 8 cck 8, by Biosharp (1 mentions)
Sodium bromide, by Sinopharm (1 mentions)
Tgf β1, by Proteintech (1 mentions)
N n dimethylacetamide, by Sinopharm (1 mentions)
Polyvinylpyrrolidone, by Sinopharm (1 mentions)
Lysosensor blue dnd 167, by Thermo Fisher Scientific (1 mentions)
13 protocols using 2 methylimidazole 2 mim
1
ZIF-8 Synthesis and Characterization
2
Fabrication of ZIF-8 MOF Thin Films
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Zinc nitrate hexahydrate (Zn(NO3)·6H2O, 98%, Sigma-Aldrich, St. Louis, MO, USA) and 2-methylimidazole (2-MIM, 99.0%, Sigma-Aldrich) were used as the metal and ligand sources. Glass substrate (Duran, 18 mm × 18 mm) was used for ZIF-8 growth. All the chemicals and materials were used as purchased without further purification.
3
Synthesis and Characterization of 2-MIM/Zn MOF
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All chemicals utilized in this study were commercially purchased from suppliers and employed without further purification. 2-Methylimidazole (2-MIM, 99%), zinc nitrate hexahydrate (Zn(NO3)2·6H2O, 99%), and methanol (MeOH, 99.99%) were purchased from Sigma Aldrich, South Korea. Prior to employing it as the current collector substrate, nickel foam (NF, 1.6 mm thickness) obtained from ALANTUM, South Korea, was carefully cleaned with HCl, ethanol, acetone, and deionized (DI) water.
4
Synthesis of ZnO Nanostructures
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Zinc nitrate hexahydrate, 2-methylimidazole (2-MIM), sodium formate of reagent grade, methanol and 1-octanol of analysis grade were purchased from Sigma-Aldrich. Deionized water produced with a Merck Millipore system was used. The α-Al2O3 disks (30 mm in diameter and 1 mm in thickness) were purchased from Fraunhofer IKTS.
5
Polysulfone-Based Membrane Fabrication
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Pellets of polysulfone
(Udel P-3500 LCD) were purchased from Solvay Advanced Polymers. Poly[1-(trimethylsilyl)prop-1-yne]
(PTMSP) was purchased from Fluorochem, United Kingdom. Polyether-block-amide, Pebax MH 1657 (comprising 60 wt % poly(ethylene
oxide) (PEO) and 40 wt % aliphatic polyamide (PA6)) in the form of
pellets was kindly provided by Arkema, France. 2-Aminoterephthalic
acid (BDC-NH2) and anhydrous zirconium tetrachloride (ZrCl4) were purchased from Acros Chemicals. Zirconyl chloride octahydrate
(ZrOCl2·8H2O) was purchased from Alfa Aesar.
Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and 2-methylimidazole (2-mIm) were purchased from Sigma-Aldrich.
4-Methyl-5-imidazole-carboxyaldehyde was purchased from Acros Chemicals.
The solvents methanol (MeOH), 1-butanol (1-ButOH), N-methyl-2-pyrrolidone (NMP), and absolute ethanol (EtOH) were purchased
from Análisis Vinicos, Panreac, and Gilca, Spain. All gases
used for the separation tests were of research grade (greater than
99.995% purity) and supplied by Abelló Linde S.A., Spain. All
gases, polymers, reactants, and solvents were used as received.
(Udel P-3500 LCD) were purchased from Solvay Advanced Polymers. Poly[1-(trimethylsilyl)prop-1-yne]
(PTMSP) was purchased from Fluorochem, United Kingdom. Polyether-block-amide, Pebax MH 1657 (comprising 60 wt % poly(ethylene
oxide) (PEO) and 40 wt % aliphatic polyamide (PA6)) in the form of
pellets was kindly provided by Arkema, France. 2-Aminoterephthalic
acid (BDC-NH2) and anhydrous zirconium tetrachloride (ZrCl4) were purchased from Acros Chemicals. Zirconyl chloride octahydrate
(ZrOCl2·8H2O) was purchased from Alfa Aesar.
Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and 2-methylimidazole (2-mIm) were purchased from Sigma-Aldrich.
4-Methyl-5-imidazole-carboxyaldehyde was purchased from Acros Chemicals.
The solvents methanol (MeOH), 1-butanol (1-ButOH), N-methyl-2-pyrrolidone (NMP), and absolute ethanol (EtOH) were purchased
from Análisis Vinicos, Panreac, and Gilca, Spain. All gases
used for the separation tests were of research grade (greater than
99.995% purity) and supplied by Abelló Linde S.A., Spain. All
gases, polymers, reactants, and solvents were used as received.
6
PHBV-Based Scaffold Fabrication and Cell Culture
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4.1 Materials. Palladium acetylacetonate, Polyvinylpyrrolidone (PVP), Sodium bromide (NaBr), Dimethyl sulfoxide (DMSO) and N, N- dimethylacetamide (DMA) were purchased from Sinopharm Group Chemical reagent Co., Ltd. (Shanghai, China). Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and 2-methylimidazole (2-mim) were purchased from Sigma-Aldrich (USA). Rosiglitazone was manufactured by Solarbio (Beijing, China). Polyhydroxybutyrate valerate (PHBV) was provided by Hunan University (Changsha, China). Trichloromethane (TCM) and dimethylformamide (DMF) were purchased from Aladdin (Shanghai, China). Cell Counting Kit-8 (CCK-8) were purchased from Biosharp (Hefei, Anhui, China). TGF-β1 were purchased from Proteintech Group, Inc (USA). PCR primers were designed and synthesized by Sangon Biotech (Shanghai, China). Bacteriological petri dishes were purchased from Jiangsu province. LIVE/DEADBacLight were produced by Invitrogen (USA). α-SMA, CTGF and Collagen-I antibodies were purchased from Santa Cruz Biotechnology, Inc. (USA). Hematoxylin-Eosin (HE) Staining Kit and Masson Staining Kit were purchased from Wuhan Servicebio Technology Co., Ltd (Wuhan, Hubei, China). Other conventional consumables for cell culture were purchased from Sigma-Aldrich (USA).
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7
Cellular Uptake and Cytotoxicity of AFt-2MIM Nanoparticles
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AFt from equine spleen (0.2 μm filtered), 2-methylimidazole (2-MIM), zinc nitrate hexahydrate, thiazolyl blue tetrazolium bromide (MTT), and GOx were purchased from Sigma-Aldrich. DOX was obtained from Tokyo Chemical Industry Company. MDA-MB-231 and MCF-10A cells were obtained from Chinese National Collection of Authenticated Cell Cultures. MX-1 cells were kindly sponsored by Professor Yuqing Chen. LysoSensor Blue DND-167 was obtained from Thermo Fisher Scientific Incorporated. TfR1 (CD71) mouse monoclonal antibody and CoraLite488-conjugated goat anti-mouse lgG(H + L) were purchased from Proteintech Incorporated. Goat anti-Mouse lgG H&L (Alexa FluorR 555) preadsorbed was purchased from Abcam. Blocking buffer, antibody dilution buffer for immunofluorescence, antifade mounting medium with DAPI, and PBS were purchased from Beyotime Biotechnology Incorporated. Fetal bovine serum (FBS), Dulbecco’s modified eagle medium (DMEM), RPMI 1640 medium, penicillin/streptomycin, and 0.25 % trypsin-EDTA solution were purchased from Gibco. BCA protein assay kit was purchased from CoWin Biotech Co., ltd. Amicon Ultra 3 K filters were purchased from Merck Millipore Company. All the chemicals were of analytical grade and used without further purification.
8
Fabrication of Zinc-based Electrode Material
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The zinc nitrate hexahydrate (Zn(NO3)2·6H2O), 2-methylimidazole (2-MIM), carbon black, polyvinyl dene fluoride (PVDF), N-methylene propylene (NMP), methanol (MeOH) and ethanol (EtOH) were bought from Sigma-Aldrich, South Korea. All the chemicals were purchased from the suppliers directly. The nickel plate (Ni) as a current collector and nickel foam (NF, 1.6 mm thickness) as a substrate for the working electrode, obtained from ALANTUM, South Korea, were carefully cleaned with ethanol, acetone, and deionized (DI) water.
9
Synthesis of Cobalt Vanadate Catalysts
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All chemicals were used as received. 2-methylimidazole (2-MIM, 99%, Sigma Aldrich), cobalt nitrate hexahydrate (Co(NO3)2·6H2O, 98%, Baker Analyzed Reagent), and sodium orthovanadate (Na3VO4, ≥90%, Sigma Aldrich), and potassium hydroxide (KOH, ≥85%, Honeywell Fluka).
10
SPEEK Ionomer Synthesis and Characterization
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Granulated SPEEK (FUMION E ionomers) with an ion-exchange capacity (IEC) of 1.75 mmol/g were acquired from Fumatech GmbH (St. Ingbert, Germany). N,N-Dimethylacetamide (DMAc) 99.8% solvent, methanol, 2-methylimidazole (2-MIm, 99%), zinc chloride (ZnCl2, ≥97%), cobalt chloride (CoCl2, ≥99.8%) and sodium formate (HCO2Na, ≥99%) were purchased from Sigma-Aldrich (Sigma-Aldrich Química SL, Madrid, Spain).
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