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5 protocols using sodium sulfate

1

Synthesis of MnO2-based Supercapacitor Electrode

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Analytical-grade chemicals were used as received, without any further purification. Nickel foam (98% purity, Fluka, Tokyo, Japan), graphene oxide sheet (99% purity, Goal Bio, Hsichu, Taiwan), multiwalled carbon nanotube (MWCNT) (98% purity, Showa, Tokyo, Japan), sodium sulfate (≥98% purity, Honeywell, Hannover, Germany), safranin (99% purity, Alfa Aesar, Karlsruhe, Germany), potassium permanganate (98% purity, Showa, Tokyo, Japan), and manganese sulfate (98% purity, Showa, Tokyo, Japan) were used for the preparation of the MnO2-based/NF electrode. sodium sulfate (≥98% purity, Honeywell, Hannover, Germany) was used as the electrolyte.
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2

Analytical Reagents Identification

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Acetic acid and sodium azide was from Merck & Co. (Darmstadt, Germany). Potassium bromide and sodium sulfate was from Riedel-de haën (Seelze, Germany). Sodium acetate, phenolphthalein, potassium chromate, silver nitrate, and sodium hydroxide were from Sigma-Aldrich Corp. (St. Louis, MO, USA).
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3

Synthesis of Metal Sulfate Compounds

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All chemicals utilized in this work were of analytical grade and were used as received, with no prior purification. All solutions were prepared with double-distilled water. Nickel sulfate hexahydrate (NiSO4·6H2O), formic acid (HCOOH, FA), disodium hydrogen phosphate (Na2HPO4), hydrochloric acid (HCl), sodium hydroxide pellets (NaOH) and sulfuric acid (H2SO4) were purchased from Sigma-Aldrich, whereas iron(ii) sulfate heptahydrate (FeSO4·7H2O) and sodium sulfate (Na2SO4) were purchased from Riedel-de Haën and Merck, respectively.
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4

Activated Carbon Electrode Preparation

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Analytical-grade chemicals were used as received, without any further purification. Coconut shell (from Ping-Tong, Taiwan), potassium hydroxide (98% purity, Showa, Tokyo, Japan), HCl (Showa, Tokyo, Japan) and ammonium persulfate (98% purity, Honeywell, Hannover, Germany) were utilized to prepare activated carbon powder. Nickel foam (NF) (98% purity, Fluka, Tokyo, Japan), carbon black and polyvinylidene fluoride (PVDF) (Showa, Tokyo, Japan) was used to prepare AC/NF electrode. Sodium sulfate (≥98% purity, Honeywell, Hannover, Germany) was used as the electrolyte.
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5

Synthesis of Nickel-Manganese Electrocatalyst

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All chemicals used in this work were of analytical grade and were used without further purification. Nickel foam (98% purity, Fluka), manganese acetate tetrahydrate (99.9%), dimethylsulfoxide (99.9%), sodium sulfate (98%), ethanol (99%), acetone (99%), and ammonium acetate (99.9%) were from Sigma Aldrich. sodium sulfate (≥98% purity, Honeywell) was used as the electrolyte.
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