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Pss na

Manufactured by Merck Group

PSS-Na is a laboratory reagent used for ion exchange chromatography. It is a sodium salt of polystyrene sulfonate, a polymer with sulfonate functional groups. PSS-Na is a common stationary phase material in ion exchange columns, facilitating the separation and purification of ionic compounds.

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4 protocols using pss na

1

Fabrication of Quasi-2D Perovskite Solar Cells

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CsI, PbI2, LiF, CsCl, dimethyl sulfoxide (DMSO), chlorobenzene, and poly (sodium 4-styrenesulfonate) [PSS-Na; average Mw (weight-average molecular weight) ~70,000] were purchased from Sigma-Aldrich. 3TPYMB, PhBAI, 2-NMAI, and PVK (average Mw > 100,000) were purchased from Xi’an Polymer Technology Corp. TFB and 2-[2-[2-(2-aminoethoxy)ethoxy]ethoxy]ethanamine (ODEA) were purchased from 1-Material and Aladdin, respectively. The m-PEDOT:PSS solution was a mixture of normal PEDOT:PSS (AI 4083) aqueous solution with PSS-Na aqueous solution (100 mg/ml) by a volume ratio of 3:1, as well as with CsCl (15 mg/ml). The BC powder was dissolved in DMSO solvent with a concentration of 10 mg/ml; to introduce passivators, CsAc or CsFa (5 mg/ml) was separately added in the BC solution. The quasi-2D perovskite (2-NMA0.4PhBA0.6)2CsPb2I7 precursor was prepared by dissolving PhBAI, 2-NMAI, CsI, and PbI2 in a molar ratio of 0.6:0.4:0.75:1 in DMSO under continuous stirring overnight at 40°C while keeping the Pb2+ concentration at 0.2 M. Meanwhile, ODEA was added into DMSO with a concentration of 20 μl/ml, and the solution was added in perovskite precursor with a concentration of 50 μl/ml.
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2

Fabrication of PET-based Organic Electronics

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The polyethylene terephtalate (PET) substrate Polifoil Bias is purchased from Policrom Screen. Ag 5000, DuPont Silver Ink is used for printed interconnects. Carbon ink 7102 printing paste from DuPont is used for the electrode contacts. Insulating ink (5018, DuPont) is used for electrode isolation. PQ-10, PSSNa, and BBL were purchased from Sigma-Aldrich and used as received. The P(g42T-T) and BBL inks are fabricated through a solvent exchange method. P(g42T-T) (30 mg) dissolved in chloroform (15 mL) is added dropwise to isopropanol (75 mL) under high speed stirring (1500 rpm) to obtain bright blue nanoparticles of P(g42T-T). BBL (30 mg) dissolved in methanesulfonic acid (15 mL) is added dropwise to isopropanol (75 mL) under high-speed stirring (1500 rpm) to obtain dark purple BBL nanoparticles. The P(g42T-T) and BBL nanoparticles are respectively collected by centrifugation (5000 rpm, 30 min) and washed in IPA six times until neutral. The neutral P(g42T-T) and BBL nanoparticles are re-dispersed in IPA to obtain dispersion inks (about 0.006 mg/mL for P(g42T-T) and 0.1 mg/mL for BBL)34 ,46 (link).
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3

Pt-Ir Alloy and PEDOT:PSS Coatings

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(1) Pt-Ir alloy with nanoscale surface textures: Electrochemical deposition of Pt-Ir used a mixed plating bath of ammonium hexachloroplatinate and hexachloroirridate. The details of the plating solution and deposition processes appear elsewhere.[22 ] Immersing bare electrode surfaces in the plating bath followed by application of a controlled electrochemical potential (Gamry Reference 600 in a 3-electrode system) caused chemical reduction of metal ions in solution to metal alloys on the electrode surfaces. The deposition conditions define the morphology and composition of the resulting coatings. (2) PEDOT:PSS coatings: 0.2g of EDOT (Sigma-Aldrich) added to 200 mL deionized water, stirred overnight for complete dissolution, followed by 0.4 g of PSSNa (Sigma-Aldrich) yielded the solution for electro-polymerization. A potentiostat (Gamry Reference 600) controlled the electro-polymerization processes in a 3-electrode configuration. Immersing the selected electrodes on the 3D-MIM into the solution and applying a constant voltage (1.1 V to Ag/AgCl reference electrode) for 10 minutes, formed the desired coating, as evidence by a change in the color of the electrode surface from gold to dark blue/black. For values above a certain level, the thicknesses of the coatings has little effect on the electrochemical impedance.
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4

Fabrication of Perovskite Solar Cells

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The modified PEDOT:PSS (m-PEDOT:PSS) solution is a mix of normal PEDOT:PSS (AI 4083) aqueous solution and 100 mg ml−1 PSS-Na (Sigma Aldrich) aqueous solution by a volume ratio of 6:5. TOPO, PbBr2, dimethyl sulfoxide (DMSO) and chlorobenzene (CB) were purchased from Sigma Aldrich. 2,2’,2”-(1,3,5-Benzinetriyl)- tris(1-phenyl-1-H-benzimidazole) (TPBi) and formamidinium bromide (FABr) and methylammonium chloride (MACl) were purchased from Xi’an Polymer Light Technology Corp. Phenylethylammonium bromide (PEABr) was purchased from Dyesol (now Greatcell Solar).
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