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2 hydroxy 2 methylpropiophenone hmpph

Manufactured by Merck Group

2-hydroxy-2-methylpropiophenone (HMPPh) is a chemical compound used in various laboratory applications. It functions as an initiator for photopolymerization reactions. HMPPh exhibits the property of UV light absorption, which is a key characteristic for its use in these reactions.

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2 protocols using 2 hydroxy 2 methylpropiophenone hmpph

1

Hydroxypropyl Cellulose Polymer Modification

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Hydroxypropyl cellulose (HPC) was purchased from Tokyo Chemical Industry Co., Ltd. (TCI) and the molecular parameters are as follows: number- and weight-average molecular weights, 9.9 × 104 and 1.5 × 104 respectively; degree of substitution, DS = 1.4 and MS = 3.9,28 (link) where DS and MS denote an average number of substituted hydroxyl group and that of introduced hydroxypropyl group, respectively. Methyl acrylate (MA), methyl methacrylate (MMA), ethyl acrylate (EA), ethyl methacrylate (EMA), isopropyl methacrylate (iPMA), and 4-acryloylmorpholine (ACMO) were obtained from TCI and used after passing through a column packed with activated alumina (Wako Pure Chemical Industries, Ltd. (Wako)). Dehydrated pyridine (Wako), propionic anhydride (TCI), 4-dimethylaminopyridine (DMAP) (Wako), 2-hydroxy-2-methylpropiophenone (HMPPh) (Sigma Aldrich Co. LCC.) were used without further purification.
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2

Cellulose-Based Hydrogel Synthesis

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Cotton-derived fibrous cellulose was obtained by cutting and milling of Whatman filter paper No. 5 (GE Healthcare Life Sciences Corp.). Sulfuric acid (Nacalai Tesque, Inc.) and polyethylene glycol (PEG; molecular weight = ~20,000, Wako Pure Chemical Ind., Ltd.) were used as received. Monomers, HEMA (Wako Pure Chemical Ind., Ltd.) and AA (Nacalai Tesque, Inc.), were purified by vacuum distillation before use. A photopolymerization initiator, 2-hydroxy-2-methylpropiophenone (HMPPh; Sigma-Aldrich), and a cross-linking agent, ethylene dimethacrylate (EDM; Tokyo Kasei Kogyo Co., Ltd.), were used without further purification.
Calcium chloride dihydrate (CaCl 2 •2H 2 O) and ammonium carbonate ((NH 4 ) 2 CO 3 ) were purchased from Nacalai Tesque, Inc. and used as ion sources for mineralization. A low-molecular-weight PAA (L-PAA; average degree of polymerization (DP) = 25, Sigma-Aldrich) was used as a precipitation inhibitor in the salt solution of ion server [25, 37] . Other conventional chemicals were purchased from Wako Pure Chemical Ind., Ltd. or Nacalai Tesque, Inc. and used as received.
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