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2 protocols using guanidinium iodide

1

Perovskite Solar Cell Fabrication

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FAI and Methylammonium iodide (MAI) were purchased from GreatCell Solar and used without further purification. PbI2 (99.99%) was purchased from Tokyo Chemical Industry. 2-Mercaptoethanol (2-ME), DMSO, CsI (99.999%), guanidinium iodide (>99%), formamidinium chloride, phenylethylammonium chloride, zinc chloride, CBH, 2-propanol (IPA; anhydrous, 99.5%), toluene, PTAA (number average molecular weight 7000 to 10,000), and BCP (>96%) were purchased from Sigma-Aldrich. C60 (>99.55%) was purchased from Nano-C. Formamidinium hypophosphite was synthesized via a method that was based on, and modified from, a previously published method.
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2

Perovskite Solar Cell Fabrication

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Cs2CO3 (99.95%, Sigma Aldrich), Oleic Acid (  99%, Sigma Aldrich), Octadecene (Sigma Aldrich), PbI2 (99.99%, Sigma Aldrich), Guanidinium iodide (> 99%, Sigma Aldrich), Oleylamine (Sigma Aldrich), Methyl acetate (MeAc), Hexane (Sigma Aldrich), Tetrahydrofuran (Sigma Aldrich), poly(3,4-ethylenedioxythiophene) polystyrene sulfonate [PEDOT:PSS] (Heraeus), 2,2′,2″-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole [TPBI] (Ossila), lithium fluoride [LiF] (Sigma Aldrich), and Silver [Ag] (Sigma Aldrich). The chemicals were used as received without further purification.
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