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2 protocols using cobalt chloride

1

Synthesis of Metal Coordination Complexes

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Boric acid (H3BO3, 99.97%), urea (NH2CONH2, 99.3+%), d-(+)-glucose (99%), calcium nitrate tetrahydrate (Ca(NO3)2·4H2O, 99%), magnesium nitrate hexahydrate (Mg(NO3)2·6H2O, 98.0–102.0%), strontium nitrate (Sr(NO3)2, 99.0+%), barium nitrate (Ba(NO3)2, 99.95%), silver nitrate (AgNO3, 99.9+%), nickel(ii) nitrate hexahydrate (Ni(NO3)2·6H2O, 98%), 2,2′-bipyridine (99+%), lanthanum(iii) oxide (La2O3, 99.99%) were purchased from Alfa Aesar. Cobalt nitrate hexahydrate (Co(NO3)2·6H2O, 99%) was purchased from Aladdin and cobalt chloride (CoCl2·6H2O, 99.99%) from MACKLIN.
Other analytical grade solvents including ethanol, acetonitrile and chemicals such as potassium hydroxide, ammonia solution, hydrochloric acid and triethanolamine were supplied by Sinopharm.
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2

Synthesis of Metal-Organic Nanomaterials

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Ethylene glycol (EG), ethanol absolute, ferric chloride (FeCl3·6H2O), cobalt chloride (CoCl2·6H2O), anhydrous sodium acetate (CH3COONa), polyethylene glycol (molecular weight 4000), and ammonia water (25% NH3 H2O) were purchased from Macklin Reagent (Shanghai, China). All other reagents were purchased from Sinopharm Chemical Reagent Co., Ltd (Shanghai, China) and were of analytical grade or better unless otherwise stated. Ultrapure water (Millipore, Milli-Q) was used for reagent water throughout the studies.
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