Formamidinium chloride

Manufactured by Merck Group

Formamidinium chloride is a chemical compound used in various laboratory applications. It is a white crystalline solid that is soluble in water and alcohol. Formamidinium chloride serves as a precursor in the synthesis of other chemical compounds and is utilized in research and development processes. However, a detailed description of its core function while maintaining an unbiased and factual approach is not available.

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Formamidinium (2 citations)

3 protocols using formamidinium chloride

Perovskite Solar Cell Fabrication

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FAI and Methylammonium iodide (MAI) were purchased from GreatCell Solar and used without further purification. PbI₂ (99.99%) was purchased from Tokyo Chemical Industry. 2-Mercaptoethanol (2-ME), DMSO, CsI (99.999%), guanidinium iodide (>99%), formamidinium chloride, phenylethylammonium chloride, zinc chloride, CBH, 2-propanol (IPA; anhydrous, 99.5%), toluene, PTAA (number average molecular weight 7000 to 10,000), and BCP (>96%) were purchased from Sigma-Aldrich. C₆₀ (>99.55%) was purchased from Nano-C. Formamidinium hypophosphite was synthesized via a method that was based on, and modified from, a previously published method.

Wang M., Fei C., Uddin M.A, & Huang J. (2022). Influence of voids on the thermal and light stability of perovskite solar cells. Science Advances, 8(38), eabo5977.

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Synthesis and Characterization of Perovskite Materials

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Lead bromide (PbBr

_{2}, \geq

98%), dimethylformamide (DMF, 99.8%), formamidinium chloride (98% Purity), octylamine (99%), Bis[2-(methacryloyloxy)ethyl] phosphate (BMEP), and poly(methyl methacrylate) (PMMA, average Mw 350,000) were purchased from Sigma Aldrich. Toluene (≥99.8%) and oleic acid (<70%) were purchased from Fisher Scientific. Formamidinium bromide (>99.5%) was purchased from Osilla (Sheffield, UK). Lead chloride (PbCl

_{2}

, 99%) was purchased from Acros Organics. EJ-290 Plastic Scintillator Casting Resin was purchased from Eljen Technology (Sweetwater, TX, USA).

Braddock I.H., Al Sid Cheikh M., Ghosh J., Mulholland R.E., O’Neill J.G., Stolojan V., Crean C., Sweeney S.J, & Sellin P.J. (2022). Formamidinium Lead Halide Perovskite Nanocomposite Scintillators. Nanomaterials, 12(13), 2141.

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Perovskite Precursor Compounds Synthesis

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The
following materials were used: methylammonium
iodide (Sigma, 98%), formamidinium iodide (Sigma, 98%), formamidinium
bromide (Sigma, 98%), formamidinium chloride (Sigma, 97%), CsI (Fischer,
99.9%), CsBr (Fischer, 99.9%), CsCl (Acros, 99.99%), SnI₂ (Sigma, 99.999%), SnBr₂ (Sigma), SnCl₂ (Sigma,
98%), SnI₄ (Sigma, 99.999%), and SnBr₄ (Sigma,
99%).

Kubicki D.J., Prochowicz D., Salager E., Rakhmatullin A., Grey C.P., Emsley L, & Stranks S.D. (2020). Local Structure and Dynamics in Methylammonium, Formamidinium, and Cesium Tin(II) Mixed-Halide Perovskites from 119Sn Solid-State NMR. Journal of the American Chemical Society, 142(17), 7813-7826.

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