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2 protocols using co no3 2 hexahydrate

1

Synthesis of Metal Nanoparticles

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HAuCl4 ∙ 3H2O (99.99% (metals basis)), L-cysteine hydrochloride (98%), D-cysteine hydrochloride (98%), L-glutathione (98%+), D-methionine (99%), L-methionine (98 + %), L-cystine dihydrochloride (98%), D-cystine (98%), Cu(NO3)2 trihydrate (98%), Fe(NO3)3 nonahydrate (98%), Co(NO3)2 hexahydrate (99%), Ni(NO3)2 hexahydrate (98%), and KOH (99 + %) were purchased from Alfa Aesar. AgNO3 (>99.9%), HCl (37%), and H2SO4 (75%) were purchased from Roth. Hexadecyl-trimethylammonium bromide (CTAB, >99%), ascorbic acid (AA, >99%), and acetic acid (80%), were purchased from Acros Organics. Hexadecyltrimetryammonium chloride (CTAC, >98.0%), 1-decanol (>98%), L-penicillamine (99%), D-penicillamine (99%), Cd(NO)3 tetrahydrate (99%), Pb(NO3)2 (99%), and ammonium hydroxide (28%–30%) were purchased from Sigma-Aldrich. Milli Q water was used in all experiments. All reagents were used as received without further purification.
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2

Synthesis and Deposition of Co-Bi Catalyst

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The Co-Bi powder was obtained through a modified precipitation
technique.60 (link),61 (link) In a beaker, 291 mg of Co(NO3)2 hexahydrate (Alfa Aesar, >98%) was dissolved
in DIW by sonication. To initiate the precipitation, 5 mL of 0.5 M
NaBH4 aqueous solution was poured in the beaker with fast
stirring. NaBH4 reacted quickly with gas evolution. The
solution was kept stirring for 40 min, and then the precipitate was
rinsed and centrifuged several times with DIW and then ethanol to
remove residues of the reaction solution. Eventually, the powder was
dried from ethanol in a desiccator at 35 °C.
Co-Bi was deposited as catalysts onto the BiVO4 photoanode
surface by drop casting an ethanol dispersion of the powder (0.5 mg/mL)
obtained by 15 min sonication. The catalyst loading was varied by
changing the dropped volume (10, 25, and 50 μL/cm2). After application of the dispersion with a micropipette, ethanol
was evaporated in the desiccator.
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