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3 protocols using triethylene glycol

1

Synthesis of Graphene-Based Materials

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Graphite flakes, sodium chloride (NaCl, ≥99.0%), sulfuric acid (H2SO4, 98%), sodium nitrate (NaNO3, ≥99%), potassium permanganate (KMnO4, ≥99%), hydrogen peroxide (H2O2, 30% in water), concentrated aqueous solution hydrochloric acid (HCl, 37 wt.%), copper(II) nitrate hydrate (Cu(NO3)2·3H2O, ≥99%), chloroplatinic acid hexahydrate (H2PtCl6·6H2O, 99.9%), palladium chloride (PdCl2, 99%), ethylene glycol (EG, 99%), and triethylene glycol (TEG, 99%) were purchased from Sinopharm Chemical Reagent Co., Ltd. (Beijing, China). All chemicals were used as received without further purification. Deionized (DI) water was used in this experiment to prepare the solutions.
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2

Transition Metal Catalyzed Organic Reactions

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Cobalt acetylacetonate
(Co(acac)2, 98%), rhodium(II) trifluoroacetate dimer (Rh2(COOCF3)4, GR), sodium trifluoroacetate
(NaCOOCF3, >98%), sodium borohydride (NaBH4,
>96%), o-nitrophenol (o-NP, >99%), m-nitrotoluene (m-NP, 98%), p-nitrophenol (p-NP, >98%), o-chloronitrobenzene
(o-CNB, 99%), and m-chloronitrobenzene
(m-CNB, 98%) were purchased from Aladdin. Poly(vinylpyrrolidone)
(PVP-K30, GR), triethylene glycol (TREG, AR), ethylene glycol (EG,
AR), absolute ethyl alcohol (AR), and acetone (AR) were purchased
from Sinopharm Chemical Reagent Co., Ltd. Aluminum oxide powders calcined
at 500 °C for 3 h were purchased from Qingdao Haiyang Chemical
Co., Ltd. All of the reagents were used as received without further
purification.
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3

Synthesis of Metal Nanoparticles

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TEOS, HAuCl4, and Fe(acac)3 were purchased from Energy Chemical; Dopamine purchased from Alfa Aesar; ammonia solution (25–28 %), ethanol, sodium citrate, polyvinylpyrrolidone (PVP), ethylene glycol (EG), diethylene glycol (DEG), triethylene glycol, AgNO3, and NaCl were purchased from Sinopharm Chemical Reagent Co. (Shanghai, China). All the reagents were used without further purification. Deionized water was used throughout the experiments.
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