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2 protocols using phenylethylammonium chloride

1

Perovskite Solar Cell Fabrication

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FAI and Methylammonium iodide (MAI) were purchased from GreatCell Solar and used without further purification. PbI2 (99.99%) was purchased from Tokyo Chemical Industry. 2-Mercaptoethanol (2-ME), DMSO, CsI (99.999%), guanidinium iodide (>99%), formamidinium chloride, phenylethylammonium chloride, zinc chloride, CBH, 2-propanol (IPA; anhydrous, 99.5%), toluene, PTAA (number average molecular weight 7000 to 10,000), and BCP (>96%) were purchased from Sigma-Aldrich. C60 (>99.55%) was purchased from Nano-C. Formamidinium hypophosphite was synthesized via a method that was based on, and modified from, a previously published method.
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2

Cation-Exchange Resin Synthesis and Perovskite Deposition

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Carboxylic acid cation-exchange resin WAC-gel (WACG-HP, gel type, hydrogen form) and WAC-MP (WACMP, macroporous type, hydrogen form) and sulfonic acid cation-exchange resin SAC-MP (SACMP-H, macroporous type, hydrogen form) were purchased from ResinTech Inc. Sulfonic acid cation-exchange resin SAC-gel (Amberlite® IRC120 H, gel type, hydrogen form), Lead(II) iodide (99%), PTAA (average Mn 7000–10,000), bathocuproine (BCP), dimethylformamide (DMF), dimethyl sulfoxide (DMSO), 2-methoxyethanol (2-ME), 1,2-Dichlorobenzene, toluene, isopropyl alcohol, phenylethyl ammonium chloride, and Pb standard solution (1000 ± 2 ppm) were purchased from Sigma-Aldrich. Lead(II) iodide (99.99%, trace-metal basis) was purchased from TCI America. Formamidinium iodide (FAI) and formamidinium chloride were purchased from GreatCell Solar. C60 was purchased from Nano-C Inc. Copper (Cu) and chromium (Cr) for thermal evaporation were purchased from Kurt J. Lesker company.
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