Log In Sign up
The largest database of trusted experimental protocols

Acetone d6

Manufactured by Deutero
Visit Supplier
Sourced in Germany

Acetone-d6 is a deuterated organic solvent used as a reference compound in nuclear magnetic resonance (NMR) spectroscopy. It is a stable isotope of acetone, with all six hydrogen atoms replaced by deuterium. Acetone-d6 is a colorless, volatile liquid that is widely used in various analytical applications, particularly in the characterization of organic compounds.

Automatically generated - may contain errors

Lab products found in correlation

N n dimethylacetamide dmac, by Thermo Fisher Scientific (2 mentions) N n dimethylformamide d7, by Deutero (2 mentions) Sarcophine standard, by AG Scientific (1 mentions) Sea salt, by Merck Group (1 mentions) Kanamycin, by Carl Roth (1 mentions) 4 hydroxybenzoic acid, by Thermo Fisher Scientific (1 mentions) Diaion hp 20, by Merck Group (1 mentions) Naringenin, by Merck Group (1 mentions) Restriction enzyme, by New England Biolabs (1 mentions) Dimanganese decacarbonyl, by Merck Group (1 mentions) Carbon dioxide, by Air Liquide (1 mentions) Styrene, by Merck Group (1 mentions) Di tert butyl peroxide, by Merck Group (1 mentions) Irgacure 651, by Merck Group (1 mentions) Bis trifluoromethane sulfonimide lithium salt, by Merck Group (1 mentions) Dichloromethane, by Thermo Fisher Scientific (1 mentions) Hydrochloric acid (hcl), by Honeywell (1 mentions) Ethyl acetate, by Thermo Fisher Scientific (1 mentions) Acetonitrile, by Thermo Fisher Scientific (1 mentions) Methanol, by Thermo Fisher Scientific (1 mentions)

7 protocols using acetone d6

1

Metabolite Quantification with HMDS

Check if the same lab product or an alternative is used in the 5 most similar protocols
Hexamethyldisiloxane (HMDS) and acetone-D6 (99.80% D, 99% purity) were purchased from Deutero GmbH (Kastellaun, Germany). HMDS (0.94 mM as a final concentration) was added for both chemical shift adjustment and absolute metabolite quantification. Sarcophine standard was purchased from AG Scientific, San Diego, CA (St. Louis, MO, USA). All other chemicals and standards were available from Sigma Aldrich (St. Louis, MO, USA).
Farag M.A., Fekry M.I., Al-Hammady M.A., Khalil M.N., El-Seedi H.R., Meyer A., Porzel A., Westphal H, & Wessjohann L.A. (2017). Cytotoxic Effects of Sarcophyton sp. Soft Corals—Is There a Correlation to Their NMR Fingerprints?. Marine Drugs, 15(7), 211.
+ Open protocol
+ Expand
2

Isolation and Synthesis of Natural Compounds

Check if the same lab product or an alternative is used in the 5 most similar protocols
Sea salts and (±)-naringenin were purchased from Sigma-Aldrich (Steinheim, Germany). 4-hydroxybenzoic acid and 1,6-dihydroxynaphthalene were obtained from Acros Organics (New Jersey, USA). 1-hydroxyphenazine was from TCI (Zwijndrecht, Belgium), kanamycin was from Roth (Karlsruhe, Germany), and chloramphenicol was from Genaxxon BioScience (Biberach, Germany). Diaion HP-20 was received from Supelco (Bellefonte, USA) and PCA from InFarmatik (Hungary). Acetone-d6 was purchased from Deutero (Kastellaun, Germany). Reference samples of JBIR-46 and -47 were isolated as described previously [14] (link). Flaviolin was isolated as described by Gross et al. [46] (link) and DMAPP, geranyl diphosphate, and farnesyl diphosphate were synthesized as described previously [47] . Restriction enzymes were bought from New England Biolabs (Frankfurt am Main, Germany).
Zeyhle P., Bauer J.S., Kalinowski J., Shin-ya K., Gross H, & Heide L. (2014). Genome-Based Discovery of a Novel Membrane-Bound 1,6-Dihydroxyphenazine Prenyltransferase from a Marine Actinomycete. PLoS ONE, 9(6), e99122.
+ Open protocol
+ Expand
3

Synthesis of Fluorinated Polymer Composites

Check if the same lab product or an alternative is used in the 5 most similar protocols
Vinylidene fluoride (VDF, Dyneon GmbH, Burgkirchen a.d.Alz, Germany, 99.5%), styrene (S, Sigma-Aldrich, Taufkirchen, Germany, 99.5%), methyl methacrylate (MMA, Sigma-Aldrich, Taufkirchen, Germany, 99%), di-tert-butylperoxide (DTBP, Merck, Darmstadt, Germany, 98%), 1-iodoperfluorohexane (ABCR, Karlsruhe, Germany, 99%), 1,4-diiodooctafluorobutane (Dyneon GmbH, Burgkirchen a.d.Alz, Germany), dimanganese decacarbonyl (Sigma-Aldrich, Taufkirchen, Germany, 98%), methanol (95%), hydrochloric acid (37%), N,N-dimethyl acetamide (DMAc, Acros, Geel, Belgium, 99%), ammonium 4,8-dioxa-3H-perfluorononanoate (Dyneon, GmbH, Burgkirchen a.d.Alz, Germany), ammonium peroxydisulfate (Fluka, Honeywell, Hannover, Germany, ≥98.0%), carbon dioxide (Air Liquide, Paris, France, 99.8%), N,N-dimethylformamide-d7 (Deutero GmbH, Kastellaun, Germany, 99.5%), and acetone-d6 (Deutero GmbH, Kastellaun, Germany, 99.8%) were used as received.
Golzari N., Adams J, & Beuermann S. (2017). Inducing β Phase Crystallinity in Block Copolymers of Vinylidene Fluoride with Methyl Methacrylate or Styrene. Polymers, 9(8), 306.
+ Open protocol
+ Expand
4

Synthesis of Polymerizable Ionic Liquids

Check if the same lab product or an alternative is used in the 5 most similar protocols
The polymerizable ionic liquids [C2NMA,22]TFSI, [C4NMA,22]TFSI, [C6NMA,22]TFSI, [C8NMA,22]TFSI, [C2NA,22]TFSI, [C4NA,22]TFSI, [C6NA,22]TFSI and [C8NA,22]TFSI were synthesized as described in our previous publication [10 (link)]. Bis(trifluoromethane)sulfonimide lithium salt (99.95% on metal basis) and the initiator Irgacure651 were purchased from Sigma-Aldrich (Munich, Germany) and Ciba Chemicals (Basel, Switzerland) and used as received. For FT-NMR spectroscopy, polymer samples were dissolved in acetone-d6 (99.80%; Deutero, Germany).
Löwe R., Hanemann T., Zinkevich T, & Hofmann A. (2021). Structure–Property Relationship of Polymerized Ionic Liquids for Solid-State Electrolyte Membranes. Polymers, 13(5), 792.
+ Open protocol
+ Expand
5

Comprehensive Analytical Reagent Protocol

Check if the same lab product or an alternative is used in the 5 most similar protocols
Water (deionized, Nanopure ® , Werner, Leverkusen, Germany), acetic acid, HPLC quality (Mallinckrodt Baker B. V., Deventer, Holland), acetonitrile, HPLC quality (Fisher Scientific, Loughborough, UK), methanol, HPLC quality (Fisher Scientific), dichloromethane (Fisher Scientific), n-butanol, p.a. (Fisher Scientific), ethyl acetate, p.a. (Fisher Scientific), (+)-catechin hydrate, ≥98% (Sigma, Steinheim, Germany), (-)-epicatechin, p.a. (Sigma), p-anisaldehyde, 98% (Sigma), hydrochloric acid, 37% (Riedel-de-Haën, Seelze, Germany), ethanol, p.a. (Riedel-de-Haën), sulfuric acid, 98% (Riedel-de-Haën), sodium hydrogen carbonate, p.a. (Merck, Darmstadt, Germany), tert-butylmethlyether (distilled, industrial quality), methanol (distilled, industrial quality), n-hexane (distilled, industrial quality), and acetone-d 6 (Deutero GmbH, Kastellaun, Germany) were used.
Esatbeyoglu T., Wray V, & Winterhalter P. (2015). Isolation of dimeric, trimeric, tetrameric and pentameric procyanidins from unroasted cocoa beans (Theobroma cacao L.) using countercurrent chromatography. Food chemistry, 179.
+ Open protocol
+ Expand
6

Hyperpolarization of Vinyl Acetate Derivatives

Check if the same lab product or an alternative is used in the 5 most similar protocols

Samples for PHIP−SAH and −HOT: 10 μl of TVOA (synthesized according to a protocol described below) or vinyl acetate (CAS 108‐05‐4, Merck) was dissolved in 600 μL of acetone‐d6 or chloroform‐d (Deutero GmbH) yielding a 100 mmol/L concentration. For PHIP experiments the catalyst [1,4‐Bis(diphenylphosphino)butane(1,5‐cyclooctadiene)rhodium(I) tetrafluoroborate] [1] (CAS: 79255‐71‐3, Strem Chemicals) was added to reach a concentration of 5 mmol/L. chloroform‐d and acetone‐d6 were dried by pouring it through a 3 cm column (ID=5 mm) of basic aluminium oxide powder and magnesium sulfate respectively directly before preparation of the samples. Both powders were dried overnight at 120°. Note, that even after drying, the residual HDO concentration was determined to approx. 1 mM. These samples were flushed by pH2 to produce hyperpolarization in the following stage.
Samples for reference NMR spectra: NMR spectra of the following compounds dissolved in chloroform‐d or acetone‐d6 were measured at concentrations of 10–100 mM: vinyl acetate (CAS: 108‐05‐4), ethyl‐acetate (CAS: 141‐78‐6), triethyl orthoacetate (CAS: 78‐39‐7), acetaldehyde (CAS: 75‐07‐0), 2‐chloroethanol (CAS: 107‐07‐3), ethyl alcohol (CAS: 64‐17‐5). All compounds were purchased from Merck. These samples and the corresponding spectra were used to assign the products of the TVOA hydrogenation.
Pravdivtsev A.N., Brahms A., Kienitz S., Sönnichsen F.D., Hövener J, & Herges R. (2021). Catalytic Hydrogenation of Trivinyl Orthoacetate: Mechanisms Elucidated by Parahydrogen Induced Polarization. Chemphyschem, 22(4), 370-377.
+ Open protocol
+ Expand
7

Emulsion Polymerization of Vinylidene Fluoride

Check if the same lab product or an alternative is used in the 5 most similar protocols
Vinylidene fluoride (Dyneon, 99.5%), the chain transfer agent 1,4−diiodooctafluorobutane, the emulsifier ammonium 4,8-dioxa-3H-perfluorononanoate (ADONA, Dyneon, Gendorf, Germany), and the initiator ammonium peroxydisulfate (APS) (≥98.0%, Fluka) were used as received. Ultrapure and deionized water (electric conductivity: 0.055 µS∙cm−1) served as continuous phase for the emulsion polymerization. N,N−dimethyl acetamide (DMAc) (99%, Acros, Nidderau, Germany) containing 0.1% of LiBr (≥99%, Riedel-de-Häen) is used as eluent for size-exclusion chromatography. N,N−dimethylformamide−d7 (99.5%, Deutero GmbH, Kastellaun, Germany) and acetone−d6 (99.8%, Deutero GmbH, Kastellaun, Germany) were used as received.
Brandl F., Drache M, & Beuermann S. (2018). Kinetic Monte Carlo Simulation Based Detailed Understanding of the Transfer Processes in Semi-Batch Iodine Transfer Emulsion Polymerizations of Vinylidene Fluoride. Polymers, 10(9), 1008.
+ Open protocol
+ Expand

About PubCompare

Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.

We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.

However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.

Ready to get started?

Sign up for free.
Registration takes 20 seconds.
Available from any computer
No download required

Sign up now

Revolutionizing how scientists
search and build protocols!