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21 protocols using tetrabutyl titanate

1

Synthesis of Cobalt Ferrite Nanocomposites

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All the chemical reagents used in the preparation of materials are of analytical grade. Barium acetate, calcium acetate, tetrabutyl titanate, ethylene glycol, and glacial acetic acid were purchased from Sinopharm Group Chemical Reagent Co., Ltd. CoFe2O4 material with an average nanoparticles diameter of ∼40 nm was purchased from Beijing Dk Nano Technology Co., LTD. PVP was purchased from Zhangjiakou Kerma Fine Chemicals Co., Ltd.
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2

Synthesis and Characterization of Biodegradable Polymers

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Dimethyl terephthalate (DMT), dimethyl succinate (DMS), 1,4-butanediol (BD), chloroform and dichloromethane (DCM), sodium hydroxide (NaOH) and hydrochloric acid (HCl) were commercially supplied by Shanghai Lingfeng Chemical Reagent Co. Ltd. Serinol was supplied by Shanghai Yijing industrial Co. Ltd. Sodium chloride (NaCl) was supplied by Sinopharm Chemical Reagent Co. Ltd. Tetrabutyl titanate (TBT), ditertbutyl dicarbonate ((Boc)2O), sulfamic acid, methylene blue (MB), 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide hydrochloride (EDC), hexafluoroisopropanol (HFIP) and N-hydroxysuccinimide (NHS) were supplied by Aladdin Chemical Regents Co. Ltd. Carboxymethyl-β-cyclodextrin (CM-β-CD) was supplied by Zhiyuan Bio-Technology Co. Ltd (Shandong, China). All chemicals were of analytical grade and used as received without further purification.
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3

Synthesis of Titanium Oxide Nanomaterials

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Chemicals: Tetrabutyl titanate (TBT, 98%), tin chloride (SnCl 2 •2H 2 O, A. R.), sodium dodecylbenzenesulfonate (SDBS, A. R.) and oxalic acid (H 2 C 2 O 4 •2H 2 O, A. R.) were purchased from the Sinopharm Chemical Reagent Company (Shanghai, China). All of the chemicals cited above were used as received without further purification. Deionized (DI) water from a Millipore-Q purification system (Milli-pore, USA) with a resistivity of 18.2 MΩ cm was used in this work.
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4

Synthesis of Dye-Sensitized Photocatalysts

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Perylene-3,4,9,10-tetracarboxylic dianhydride, glycine, imidazole, tetracycline (TC), methylene blue (MB), and methyl orange (MO) were purchased from Aladdin. Triethylamine, hydrochloric acid, copper nitrate trihydrate, tetrabutyl titanate, glacial acetic acid, sodium hydroxide and N,N-dimethylformamide (DMF) were purchased from Sinopharm Chemical Reagent Co. All reagents were analytically pure and could be used without further purification.
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5

Synthesis of Cadmium Sulfide Nanostructures

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Cadmium chloride (CdCl2·2.5H2O, AR) and absolute ethanol were purchased from Beijing Chemical Works (China). Ethylene glycol (EG, HOCH2CH2OH, AR) and tetrabutyl titanate (TBT, 98%) were purchased from Sinopharm Chemical Reagent Co. Ltd. Acetic acid (CH3COOH, AR) was purchased from Tianjin Deen Chemical Reagent Co. Ltd. Silver nitrate (AgNO3, AR) and thioacetamide (TAA) were purchased from Aladdin. RhB (AR) was purchased from Tianjin Kemiou Chemical Reagent Co., Ltd.
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6

Synthesis of Polybutylene Terephthalate Copolymers

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Dimethyl terephthalate (DMT), 1,4-butanediol (BDO), catalysts tetrabutyl titanate (TBT) and magnesium acetate (MgAc2) were purchased from Sinopharm Chemical Reagent Co. Ltd. (Shanghai, China). CHDM was purchased from Aladdin Reagent Co. Ltd. (Shanghai, China); it was the mixture of 69% trans and 31% cis, and PTMG with an average molar weight of 1000 g mol−1 was supplied by BASF (Shanghai, China). The antioxidants (Irganox 1010 and Irgafos 168) were supplied by Ciba (Basel, Switzerland). All of these chemical materials were dried under vacuum at 80 °C for 24 h to a constant mass before use.
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7

Titanium-based Composite Synthesis

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Tetrabutyltitanate
(CP), anhydrous ethanol (AR), Triton X-100 (CP), glacial acetic acid
(AR), polyethylene glycol 600 (AR), Li2CO3 (AR),
methyl orange (MO, AR), and HCl (AR) were purchased from Sinopharm
Chemical Reagent Co., Ltd. (China). Doubly distilled water was used
throughout this study.
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8

Activated Carbon Fiber Synthesis

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Activated carbon ber (ACF) was purchased from Nantong Senyou Carbon Fiber Co., Ltd. Concentrated nitric acid (HNO 3 , 68%), zinc nitrate (Zn(NO 3 ) 2 , AR), zinc acetate (Zn(CH 3 COO) 2 , AR), zinc chloride (ZnCl 2 , AR), anhydrous ethanol (C 2 H 6 O, AR), acetic acid (CH 3 COOH), tetrabutyl titanate (C 6 H 36 O 4 Ti, TBOT, AR) and carbon disul de (CS 2 , AR) were supplied by Sinopharm Chemical Reagent Co., Ltd.
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9

Sol-Gel Synthesis of Silica-Titania Coatings

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Tetrabutyltitanate (TBOT), tetraethylorthosilicate (TEOS, 98%), ammonium hydroxide (NH4OH, 8–28%), hydrochloric acid (HCl, 8%), acetic acid (HAC, 98%), absolute ethanol (EtOH, 99.5%), nitric acid (HNO3, 68%), and 3-glycidyloxypropyltrimethoxysilane (KH-560, 97%) were purchased from Sinopharm (Beijing, China). Polyacrylic acid (PAA, M.W. ~ 3000 g/mol) was purchased from Wokai (Shanghai, China). All materials were of analytical grade. Deionized (DI) water with a resistivity of 18 MΩ·cm was used in all experiments. PV glass substrates with a thickness of 3.2 mm and a patterned rear side were purchased from Xinyi Co., Ltd. (Wuhu, China).
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10

Synthesis of Photocatalytic Nanocomposite Materials

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The tetrabutyl titanate (Ti(OC4H9)4), nitric acid (HNO3), ammonium vanadate (NH4VO3), cobalt nitrate (Co(NO3)2), acetylacetone, acetone, and absolute ethanol were purchased from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). P25 photocatalyst were purchased from Evonik Degussa, Essen, Germany. All reagents were of analytical grade and used without further purification. Deionized (DI) water and hydrolytic inhibitor (a mixture of acetylacetone, acetone, and absolute ethanol) were prepared by our group.
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