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2 protocols using lead thiocyanate

1

Synthesis of Lead Halide Perovskites

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Lead bromide (PbBr2, ≥98%),
lead thiocyanate (Pb(SCN)2, 99.5%), cesium carbonate (Cs2CO3, 99%), oleylamine (OLAM, 70%), oleic acid (OA,
90%), 1-octadecene (ODE, 90%), tetrachloroethylene, toluene (anhydrous,
99.8%), lead(II) acetate trihydrate (≥99.5%), benzoyl bromide
(97%), and dodecane were purchased from Sigma-Aldrich. Cesium acetate
(99%) and ethyl acetate (≥99.5%) were purchased from Fisher
Scientific. All chemicals were used without further purification;
lead compounds were stored inside a nitrogen-filled glovebox.
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2

Synthesis of Lead-Based Perovskite Nanocrystals

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Lead
thiocyanate (Pb(SCN)2, 99.5%),
lead bromide (PbBr2, ≥98%), lead iodide (PbI2, 99%), lead chloride (PbCl2, 98%), oleylamine
(OLAM, 70%), oleic acid (OA, 90%), 1-octadecene (ODE, 90%), NH4SCN (≥97.5%), Zn(CH3COO)2·2H2O (≥99%), Al(NO3)3·9H2O (≥98%), 1-ethyl-3-methylimidazolium iodide (EMII,
97%), methanol (MeOH, anhydrous, 99.8%), ethanol (≥99.5%),
ethyl acetate (99.8%), and toluene (TOL, anhydrous, 99.8%) were purchased
from Sigma-Aldrich. All chemicals were used without further purification
(lead salts were stored under nitrogen).
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