Tris 2 dimethylamino ethyl amine me6tren

Manufactured by Merck Group

Sourced in United States

Tris[2-(dimethylamino)ethyl]amine (Me6TREN) is a chemical compound used as a reagent in laboratory settings. It is a multidentate ligand, capable of coordinating with metal ions. The core function of this product is to serve as a complexing agent in various analytical and experimental procedures.

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Lab products found in correlation

5 protocols using tris 2 dimethylamino ethyl amine me6tren

Synthesis of Siloxane-Containing Polymers

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Methyl methacrylate (MMA, 99%) was obtained
from Thermo Fisher Scientific and purified using a basic alumina column
to remove inhibitor. Tetrahydrofuran (THF), anisole, toluene, acetone,
and isopropanol were purchased from Fisher Scientific and used as
received. Monomethacryloxypropyl-terminated poly(dimethylsiloxane)
(MCR-M17, M_n = 5000 g/mol, DP = 70, Đ = 1.15) was obtained from Gelest and purified using
basic alumina columns to remove inhibitor. Copper(I) bromide (CuBr,
99.999%), tris[2-(dimethylamino)ethyl]amine (Me₆TREN),
and ethylene bis(2-bromoisobutyrate) (2-BiB, 97%) were purchased from
Sigma-Aldrich and used as received.
No unexpected or unusually
high safety hazards were encountered.

Keith A.N., Vatankhah-Varnosfaderani M., Clair C., Fahimipour F., Dashtimoghadam E., Lallam A., Sztucki M., Ivanov D.A., Liang H., Dobrynin A.V, & Sheiko S.S. (2020). Bottlebrush Bridge between Soft Gels and Firm Tissues. ACS Central Science, 6(3), 413-419.

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Synthesis and Characterization of PEO-Br Macroinitiator

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Tris(2-(dimethylamino)ethyl)amine (Me₆TREN, 97%) was obtained from Sigma-Aldrich (St. Louis, MO, USA). Copper bromide (CuBr, 95.0%) was supplied by Kishida Chemical (Osaka, Japan). Ethanol (99.5%), tetrahydrofuran (THF, 99.5%), and cetylpyridinium chloride (90%) were purchased from Fujifilm Wako Pure Chemical (Osaka, Japan). All chemicals were used as received; 2-Methoxyethyl acrylate (MEA, 98.0%) from Fujifilm Wako Pure Chemical (Osaka, Japan) was treated with an inhibitor-remover prepacked column from Sigma-Aldrich (St. Louis, MO, USA) prior to use. PEO (MW = 500,000 g/mol) was purchased from Fujifilm Wako Pure Chemical (Osaka, Japan). PEO-based macroinitiator (PEO-Br) was prepared and purified in accordance with the literature [28 (link)]. Number average molecular weight (M_n(GPC)) and molecular weight distribution (M_w/M_n) estimated from gel-permeation chromatography (GPC) for PEO-Br were 4.64 × 10⁵ g/mol and 1.23, respectively. The degree of polymerization (DP) for PEO-Br was 11,340. Pyrene (97%) from Fujifilm Wako Pure Chemical (Osaka, Japan) was recrystallized from mEthanol. Water was purified using an ion-exchange column system.

Mizoue Y., Onodera E., Haraguchi K, & Yusa S.I. (2022). Association Behavior of Amphiphilic ABA Triblock Copolymer Composed of Poly(2-methoxyethyl acrylate) (A) and Poly(ethylene oxide) (B) in Aqueous Solution. Polymers, 14(9), 1678.

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Synthesis of Copper Polymer Catalysts

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Triethylamine, K₂Cr₂O₇, NaBH₄, methylbenzene, and
ethanol were analytical grade and purchased from Kelong Co., Ltd.
(Chengdu, China). CuCl, CuCl₂, CTS (99%), and 4VP (>98%)
were purchased from Aladdin Industrial Co. (Shanghai, China). Tris(2-dimethylaminoethyl)
amine (Me6TREN, 99%) was purchased from Sigma-Aldrich Chemical Co.
(St. Louis, MO, USA). Other reagents used were analytical grade. All
chemical reagents and solvents are used without further purification.
The deionized water used in the following experiments was purified
using an ultrapure reverse osmosis system (Chengdu Ultrapure Technology
Co. China).

Xiao C, & Lin J. (2020). Efficient Removal of Cr(VI) Ions by a Novel Magnetic 4-Vinyl Pyridine Grafted Ni3Si2O5(OH)4 Multiwalled Nanotube. ACS Omega, 5(36), 23099-23110.

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Synthesis of Polymeric Nanomaterials

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The chemicals used in this study, namely dopamine hydrochloride (DA), methyl trifluoroacetate (MTFA), triethylamine (TEA), p-toluenesulfonic acid (PTSA, Ts-OH), 2,2-dimethoxypropane (DMP), calcium chloride, silica gel, potassium carbonate, tetrahydrofuran (THF), α-bromoisobutyryl bromide (BIBB), dichloromethane (DCM), trifluoroacetic acid (TFA), 2-(dimethylamino) ethyl methacrylate (DMAEMA), 1-bromooctane, acetonitrile (AeCN), copper(I) bromide, tris[2-(dimethylamino)ethyl] amine (Me₆TREN), tris(hydroxymethyl)aminomethane (Trizma base), hydrogen peroxide, and copper(II) sulfate pentahydrate were purchased from different vendors, including Sigma-Aldrich (St Louis, MO, USA), Alfa Aesar (Ward Hill, MA, USA), J.T. Baker (Phillipsburg, NJ, USA), SHOWA (Chuo-ku, Japan), Fluka (Milwaukee, WI, USA), MACRON (Phillipsburg, NJ, USA), and DUKSAN (Gyeonggi, Republic of Korea), at the highest purity available.

Cheng C.H., Zeng X.Z., Chiu W.Y, & Lin J.C. (2024). A Facile Surface Modification Scheme for Medical-Grade Titanium and Polypropylene Using a Novel Mussel-Inspired Biomimetic Polymer with Cationic Quaternary Ammonium Functionalities for Antibacterial Application. Polymers, 16(4), 503.

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Synthesis of Functionalized Silica Nanoparticles

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Chloroauric acid (HAuCl₄·3H₂O, 99.9%), silver nitrate (AgNO₃, AR grade), 4-vinylpyridine (4VP, 98%), tris[2-(dimethylamino)ethyl]amine (Me₆TREN, 99%), copper(i) bromide (CuBr, 98%), 4-nitrophenol (4-NP, 99.5%), Rhodamine B(RhB, 98%) and sodium borohydride (NaBH₄, 98%) were purchased from Sigma-Aldrich. Tetraethyl orthosilicate (TEOS, 98%) and trichloro-[4-(chloromethyl)phenyl]silane (97%) were supplied from Alfa Aesar. Technical-grade ethanol, N,N-dimethylformamide (DMF) and anhydrous tetrahydrofuran (THF) were purchased from WANQING Chemical Glass ware and Instrument Co., Ltd. (Nanjing, China).

Chen X., Zhang L., Xu B., Chen T., Hu L., Yao W., Zhou M, & Xu H. (2021). Hairy silica nanosphere supported metal nanoparticles for reductive degradation of dye pollutants. Nanoscale Advances, 3(10), 2879-2886.

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