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3 protocols using poly 9 vinylcarbazole pvk

1

Synthesis of Quantum Dot Materials

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All reagents were used without any further
purification. Cadmium oxide (>99%), trioctylphosphine (TOP, 97%),
trioctylphosphine oxide (TOPO, 99%), selenium (99.98%), sulfur (99%),
tetradecylphosphonic acid (TDPA, >97%), n-hexylphosphonic
acid (HPA, >99%), poly(9,9-dioctylfluorene-alt-N-(4-s-butylphenyl)-diphenylamine)
(TFB,
average molecular weight, ∼120,000 g/mol), and poly(9-vinylcarbazole)
(PVK) were purchased from Sigma-Aldrich. Patterned ITO-glass substrates
(sheet resistance, 20 Ω/sq) were purchased from Xinxiang Ltd.
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2

Synthesis of Perovskite Nanocrystals

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Cadmium acetate dihydrate ((CdAc2·2H2O), 99.99%), lead acetate trihydrate ((PbAc2·3H2O), 99.99%), cesium carbonate (Cs2CO3, reagent Plus, 99%), benzoyl bromide (C6H5COBr, 97%), ethyl acetate (98.8%), toluene (anhydrous,
99.5%), phenethylammonium bromide (≥98%), didodecyldimethylammonium
bromide (DDABr), octadecene (ODE, technical grade, 90%), dimethyl sulfoxide-d6 (DMSO, 99 atom % D) toluene-d8 (99 atom % D), and oleic acid (OA,
90%) were purchased from Sigma-Aldrich. Indium tin oxide (ITO)-patterned
substrates, polystyrene sulfonate (PEDOT:PSS, AL 4083), poly(N,N9-bis(4-butylphenyl)-N,N9-bis(phenyl)-benzidine) (poly-TPD), and 2,2′,2″-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi) were purchased from Ossila Ltd.
Poly(9-vinylcarbazole) (PVK) and LiF were purchased from Sigma-Aldrich.
Didodecylamine (97%) was purchased from TCI. oleic acid was dried
at 120 °C for an hour and stored in a nitrogen-filled glove box.
All other chemicals were used without further purification.
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3

Synthesis and Characterization of Liquid Crystal Compounds

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The compounds A12G, AN12 4-(octyloxy)benzoate-4-(6-hydroxy)benzaldehyde [42 (link)] and C1-NH2 [22 (link)] and C2-NH2 [23 (link)] were obtained as described in previous works. QYPDLC-102 nematic LC polymer was purchased from Canaanchem. Polymeric Matrixes: PS (molecular weight: 18,700 Da, Qingdao, China) and poly(9-vinylcarbazole) (PVK) (molecular weight: 1100 Da) were commercially available supplied by Sigma Aldrich (St. Louis, MO, USA).
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