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Hydrogen hexachloroplatinate 4 hexahydrate

Manufactured by Merck Group
Sourced in United States

Hydrogen hexachloroplatinate (IV) hexahydrate is a chemical compound used as a laboratory reagent. It is a yellow-orange crystalline solid that is soluble in water and certain organic solvents. The compound's core function is to serve as a source of platinum ions for various chemical reactions and applications in the laboratory setting.

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6 protocols using hydrogen hexachloroplatinate 4 hexahydrate

1

Surface Functionalization of Stainless Steel

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Foils (100 mm × 100 mm) of 316 SS and 316L polished SS (Goodfellow, Pittsburgh, PA, USA) were cut into 10 mm × 10 mm coupons and a 0.8 mm hole was drilled in one corner. 316L SS 20-gauge wire was obtained from Beadlon (Valley Township, PA, USA). Oligo(ethylene glycol) methacrylate (OEGMA), Cu(I)Br, 2,2′-bipyridyl, ethyl 2-bromoisobutyrate, dopamine hydrochloride, anhydrous pyridine, hydrogen hexachloroplatinate (IV) hexahydrate, anhydrous dimethylformamide (DMF), 10-undecen-1-ol, dimethylchlorosilane, 1-ethyl-3-(3-N,N-dimethylaminopropyl)carbodiimide hydrochloride, 2-bromoisobutyryl bromide and N-hydroxysuccinimide (NHS) were purchased from Sigma-Aldrich (Milwaukee, WI, USA). Succinic anhydride was purchased from Alfa Aesar (Wardhill, MA, USA). For the polymerization of OEGMA, DI H2O and methanol (MeOH) (VWR, Atlanta, GA, USA) were degassed by bubbling a stream of argon through the solvents for 3 h. Peptide ligands (RGD (GRGDSPC) or RDG (GRDGSPC) or RGD-FITC (GRGDSPK conjugated to fluorescein isothiocyanate(FITC))) were custom synthesized by GenScript (Piscataway, NJ, USA)
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2

Synthesis of Platinum and Palladium Nanoparticles

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Hydrogen hexachloroplatinate (IV) hexahydrate (H2PtCl6 ∙ 6H2O), palladium (II) chloride (PdCl2) and gallic acid (C6H2(OH)3CO2H) were obtained from Sigma-Aldrich (Saint Louis, MO, USA). All reagents were used without any additional purification or modification steps.
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3

Synthesis and Characterization of Dye-Sensitized Solar Cells

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Reagent grade 1,2-dihydroxybenzene (catechol, 99+%), iodine (I2) >99.8 purity, guanidinium thiocyanate (GuSCN >97%), 1-methylimidazole (>97%), polyethylene glycol (PEG-300), lithium iodide (LiI, 99.9%), 4-tert-butylpyridine (tBP, 96%), acetonitrile (ACN, 99.8%), valeronitrile (VLN, 99.5%), and hydrogen hexachloroplatinate (IV) hexahydrate (H2PtCl6∙H2 O,≥37.5%) were all purchased from Sigma-Aldrich. Fluorine-doped tin oxide (F-SnO2,14 Ω/sq.) glass, 1-iodopropane (>98%, TCI), cis-Bis(isothiocyanato) (2,2′-bipyridyl-4,4′-dicarboxylato) (4,4′-di-nonyl-2′-bipyridyl) ruthenium (II) (Z907, Organica), potassium iodide (KI, 99.5%, D.S.P), toluene (>99.5%, Daejung), and titanium (IV) oxide paste (20 nm, Head Solar, Korea) were purchased from different suppliers. All chemicals were used as purchased.
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4

Synthesis of Metal-Oxide Nanoparticles

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Tin(iv) chloride pentahydrate (SnCl4·5H2O, >95.0%), niobium(v) ethoxide (Nb(OEt)5, >99.9%), ruthenium(iii) acetylacetonate (Ru(acac)3, no purity statement), ruthenium(iii) chloride hydrate (RuCl3·nH2O, >85.0% as anhydrous), palladium(ii) acetate (Pd(OAc)2, >97.0%), formic acid, acetonitrile, ethyl acetate, methanol, N,N-dimethylformamide (DMF) and tetrahydrofuran (THF) were purchased from the FUJIFILM Wako Pure Chemical Corporation. Dibutyltin diacetate (nBu2Sn(OAc)2, >98.0%), triethyl phosphate (PO(OEt)3, >99.0%), triisopropoxyvanadium(v) oxide (VO(OiPr)3, >97.0%) and triethylene glycol were purchased from the Tokyo Chemical Industry Co., Ltd. Rhodium(iii) acetylacetonate (Rh(acac)3, >97%) and hydrogen hexachloroplatinate(iv) hexahydrate (H2PtCl6·6H2O, >98.5%) was purchased from Sigma-Aldrich. All chemicals were used as received without further purification. S-2000 (commercial SnO2) was purchased from the Mitsubishi Materials Electronic Chemicals Co., Ltd.
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5

Synthesis of Platinum Nanoparticles

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The N-phenyl-p-phenylenediamine (Tokyo Kasei Kogyo Co., Tokyo, Japan), hydrogen hexachloroplatinate (IV) hexahydrate (H2PtCl6·6H2O, Aldrich, St. Louis, MO, USA), ethylene glycol (EG, J.T. Baker®, Center Valley, PA, USA), and Vulcan XC72 (Cabot Corporation, Boston, MA, USA.) were used without further purification.
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6

Synthesis and Functionalization of Silica Nanoparticles

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Tetraethyl orthosilicate (TEOS, 98%, Aldrich, St. Louis MO), 3-aminopropyl ethoxysilane (APTES, 99%, Aldrich), ethanol (EtOH, 99%, Aldrich), cyclohexane (99%, Aldrich), n-hexanol (99%, Aldrich), polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether (Triton X-100, 99%, Aldrich), 3-(trihydroxysilyl)propyl methylphosphonate (THPMP, 42%, Aldrich) and benzyl alcohol (BzOH, Aldrich) were used as received. Milli-Q ® grade water (Millipore, Billerica MA) and ammonium hydroxide (NH4OH, 25-28% solution in water, Aldrich) were used for the hydrolysis of silicate precursors. Fluorescein 6isothiocyanate (FITC, 99%, Aldrich) was used without previous purification. Gold (III) chloride trihydrate (HAuCl4•3H2O, ≥ 49.0% Au basis, Aldrich), hydrogen hexachloroplatinate (IV) hexahydrate (H2PtCl6•6H2O, ≥ 37.5% Pt basis, Aldrich) and silver nitrate (AgNO3, Aldrich) were used as metal sources, along with sodium borohydride (NaBH4, Aldrich) as reducing reagent.
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