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3 protocols using ytterbium oxide

1

Synthesis of NaYF4:Yb3+/Er3+ Phosphor

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Erbium oxide (Er2O3, 99.99%, Sigma-Aldrich), ytterbium oxide (Yb2O3, 99.99%, Sigma-Aldrich), yttrium oxide (Y2O3, 99.9%, Alfa Aesar), ethanol (99.9%, Analytical CS Reagent), sodium hydroxide (NaOH, 99.99% Sigma-Aldrich), 1-octadecene (ODE, 90% technical grade, Sigma-Aldrich), DI water (H2O, CDH Pvt. Ltd.), ammonium fluoride (NH4F, 95%, Fisher Scientific), oleic acid (OA, 65–88%, Merck), chloroform (CHCl3, 99% Sisco Research Laboratories Pvt. Ltd), and hydrochloric acid (HCl, 37% Sigma-Aldrich), methanol (99%, Ranken Chemicals) were used at raw materials for synthesizing NaYF4:Yb3+/Er3+ phosphor without any further purification.
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2

Synthesis and Characterization of Rare-Earth Nanomaterials

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Ammonium fluoride
(NH4F), yttrium oxide (Y2O3, 99.99%),
erbium oxide (Er2O3, 99.99%), ytterbium oxide
(Yb2O3, 99.99%), TCS, certificated reference
material (CRM), BPA, DCP, PCP, potassium permanganate (KMnO4), and phosphate buffer saline (PBS, pH = 7.4) were purchased from
Sigma-Aldrich. PAA (Mw = 2000) was obtained
from Acros Organics. Concentrated hydrochloric acid (HCl) and ethylene
glycol (EG) were obtained from Alfa Aesar. Sodium chloride (NaCl)
and CP were purchased from Oriental Chemical Industries and Junsei
Chemical Company, respectively. A stock solution of TCS (0.345 mM)
was prepared in 5 mL of acetone solution (acetone/water = 5:95, v/v).
All other reagents were of analytical grade and used as received without
any further purification.
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3

Synthesis of Lanthanide Nanocrystals

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The lanthanide raw materials including erbium(III) acetate hydrate (99.9%), yttrium(III) acetate hydrate (99.9%), ytterbium(III) acetate hydrate (99.99%), holmium(III) acetate hydrate (99.9%), yttrium oxide (99.9%), ytterbium oxide (99.9%), yttrium(III) oxide (99.9%), ytterbium(III) oxide (99.9%) together with oleic acid (90%), 1-octadecene (90%), sodium hydroxide (NaOH; >98%), ammonium fluoride (NH4F; >98%), and trifluoroacetic acid (CF3COOH; >99%) were purchased from Sigma-Aldrich. The sodium trifluoroacetate (CF3COONa; >98%) were purchased from Alfa. All of these materials were used as received unless otherwise noted.
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