Emim tfsi

For the synthesis of the zinc‐based ZIF‐62 crystal, zinc nitrate hexahydrate (≥99%), imidazole (99.5%), and benzimidazole (98%) were acquired from Sigma‐Aldrich and dimethylformamide (DMF) (99.9%) was purchased from VWR chemicals. For the synthesis of polymer electrolyte films, PEO (M_w = 6 × 10⁵), EMIM‐TFSI, and LiTFSI (≥99%) were obtained from Sigma‐Aldrich, while acetonitrile (≥99.99%) was obtained from VWR chemicals. For the NMR analyses, 35% deuterium chloride (DCl) in D₂O/DMSO‐d6 was obtained from VWR chemicals. All the chemicals were used as purchased without further purification.

Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS), acetone and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ([EMIM][TFSI]) are purchased from Sigma-Aldrich.

After a single Langmuir–Schaefer deposition the MoS₂ networks had a film thickness of ~15 nm. Interdigitated electrodes (Ti/Au, 5 nm/95 nm) were then deposited (FC-2000 Temescal Evaporator) through a shadow mask (L_Ch = 50 µm, W_Ch = 19.4 mm) onto the sample. The ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM-TFSI, 98 %, HPLC, Sigma Aldrich) was utilised to regulate ion injection into the semiconducting channel. The ionic liquid was first heated under vacuum at 100 °C for 6 h to degas any absorbed water. Subsequently, a small amount of EMIM-TFSI was carefully pipetted onto the transistor, ensuring the gate and channel were adequately covered. To remove any remaining water, the devices were left in a Janis probe station under vacuum conditions overnight, lasting 12 h. After this step, the devices were returned to atmospheric pressure in preparation for measurements. For electrical characterisation, a Keithley 2612 A dual-channel source measuring unit was used. The transfer characteristics were undertaken within a gate voltage window of −3 to 3 V, employing a scan rate of 50 mV s⁻¹. Additionally, V_DS was set to 1 V for all the devices during the measurements.

PBTTT (poly(2,5-bis(3-alkylthiophene-2-yl)thieno(3,2-b)thiophene); M_w = 44 kDa, PDI
= 1.47), IDTBT-C16 (poly(indaceno(1,2-b:5,6-b′)dithiophene-co-2,1,3-benzothiadiazole); (M_w = 92 kDa, PDI 2.3), and DPP-BTz (poly((2,5-bis(2-octadecyl)-2,3,5,6-tetrahydro-3,6-diketopyrrolo(3,4-c)pyrrole-1,4-diyl)-alt-(2-octylnonyl)-2,1,3-benzotriazole); M_w = 63 kDa, PDI = 3.2) were synthesized as described
previously.^{47 (link),58 (link),59 (link)} P3HT (poly(3-hexylthiophene-2,5-diyl); 99.0% RR, M_w = 44 kDa, PDI 2.1) was purchased from TCI. Ion-exchange
salts Li-PFSI (>98%), Li-HFSI (>98%), and Na-BArF (>98%,
<7% water)
were purchased from TCI; Li-TFSI (>99%, <1% water), Na-TFSI
(>97%),
BMP-TFSI (>98.5%, <0.04% water), EMIM-TFSI (>98%, <0.1%
water),
TBA-TFSI (>99%), DMPI-TFSM (>97%, <0.5% water), TBA-OTf (>99%),
and TBA PF6 (>99%) were purchased from Sigma-Aldrich. FeCl₃ (anhydrous, >99.99% trace metals basis) was purchased
from Sigma-Aldrich.
All polymer and dopant solutions were prepared using anhydrous solvents
(Romil Hi-Dry, <20 ppm water). Triethylamine (>99.5%) and 4,4′-difluorobenzophenone
(TraceCERT certified reference material) for QNMR dedoping experiments
were obtained from Sigma-Aldrich. All materials were used as received
with the exception of Na BArF, which was dried following the procedure
given by Yakelis et al.^{66 (link)}