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4 protocols using samarium iii acetate hydrate

1

Synthesis and Characterization of Lipid Compounds

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Myristic acid (Fluka Chemistry, 98%), palmitic acid (Riedel-de HaënTM, 98%), stearic acid (Sigma-Aldrich, 98.5%), oleic acid (Sigma-Aldrich, 99%), linoleic acid (Sigma-Aldrich, 99%), O-(1H-6-chlorobenzotriazole-1-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate (HCTU, Novabiochem), Nile red (Carl Roth), pyrene (Alfa Aesar, 98%), samarium(iii) acetate hydrate (Sigma-Aldrich, 99.9%), sodium thiosulfate (Sigma-Aldrich, 99%), N,N-diisopropylethylamine (DIPEA, Sigma-Aldrich, 99.5%), N,N-dimethylformamide (DMF, VWR chemicals, 99.9%), tetrahydrofuran (Acros organics, 99.6%), diethyl ether (VWR international, 100%), acetone (VWR international, 99%), acetonitrile (VWR international, 99.95%), formic acid (Thermo Fisher Scientific, 99%), methanol (VWR international, 100%), hydrogen peroxide (Acros organics, 35 wt% solution in water), toluene (VWR international, 100%), trifluoroacetic acid (Sigma-Aldrich, 99%), acetic acid (Sigma-Aldrich, 99.8%), phosphate buffer saline 10× (PBS 10×, Euromedex) were used without further purification. Ultrapure water (18 MΩ cm) was obtained by passing in-house deionized water through a Millipore Milli-Q Biocel A10 purification unit. Bacto Tryptone (Sigma), yeast extract (Sigma), ampicillin (Sigma) and isopropyl β-d-thiogalactopyranoside (IPTG, VWR chemicals) were used for cell culture.
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2

Rare-earth metal complexes synthesis

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Yttrium(III) acetate hydrate 99.9%, yttrium(III)
trifluoroacetate 99%, yttrium(III) nitrate hexahydrate 99.8%, yttrium(III)
chloride hexahydrate 99.99%, samarium(III) acetate hydrate 99.9%,
europium(III) acetate hydrate 99.9%, lutetium(III) acetate hydrate
99.9%, citric acid 99%, maleic acid ≥99%, citraconic acid 98%,
tetramethylammonium hydroxide 25% v/v in water, tetrabutylammonium
fluoride hydrate 98%, and ammonium fluoride >99.99% were purchased
from Sigma-Aldrich. Ethanol 96% from Panreac, acetone 99.5% from Scharlau,
and deuterium oxide 99.90% D were purchased from euriso-top. All reagents
were used as received without further purification.
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3

Synthesis of Cadmium-based Nanocrystals

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The chemicals and solvents used throughout the experiments were of analytical grade and used directly without any further purification. Cadmium oxide (CdO, 99.99%, powder), sulfur (S, 99.98%), samarium(iii) acetate hydrate (Sm(CH3COO)3·H2O, 99.9%), oleic acid (OA, 90%), Tri-n-octylphosphine (TOP, 97%), 1-octadecene (ODE, 90%), toluene (99.8%) and isopropanol (99.7%) were purchased from Sigma-Aldrich.
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4

Synthesis of Samarium(III) Acetate Nanoparticles

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Samarium(III) acetate hydrate [Sm(OAc)3.xH2O, 99.9%], oleic acid (OA, tech, 90%), oleylamine (OAm, tech, 70%) were purchased from Sigma-Aldrich. All chemicals were used without any further purification.
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