was prepared by mixing the precursors PbI2 (TCI Chemicals),
PbBr2 (TCI Chemicals), CH(NH2)2I
(FAI, GreatCell Solar), CH3NH3Br (MABr, GreatCell
Solar), and CsI (Alfa Aesar) in a 3:1 (vol %) N,N-dimethylformamide (DMF, anhydrous, Sigma-Aldrich):dimethyl
sulfoxide (DMSO, anhydrous, Sigma-Aldrich) ratio with a concentration
of 0.8 M. The precursors were added with the following ratios: Cs0.1(MA0.17FA0.83)0.9Pb0.84(I0.8Br0.2)2.68. The resulting
film thickness of the triple cation perovskite is ca. 220 nm. The
perovskite films were deposited on the glass substrates by a two-step
spin-coating process: In the first step, the perovskite solution was
spin-coated dynamically at 1000 rpm for 10 s. In the second step,
at 6000 rpm, for 20 s, chlorobenzene (anhydrous, Sigma-Aldrich, 100
μL) was dripped onto the sample after 12 s. The films were annealed
at 100 °C for 1 h to complete the crystallization process. The
complete process is performed in a nitrogen-filled glovebox.