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Ch nh2 2i fai

Manufactured by Greatcell Solar

CH(NH2)2I(FAI) is a chemical compound used in laboratory equipment. It serves as a core component in various research and analytical processes. The detailed function and intended use of this product are not available at this time.

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2 protocols using ch nh2 2i fai

1

Fabrication of Perovskite Solar Cells

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The perovskite solution
was prepared by mixing the precursors PbI2 (TCI Chemicals),
PbBr2 (TCI Chemicals), CH(NH2)2I
(FAI, GreatCell Solar), CH3NH3Br (MABr, GreatCell
Solar), and CsI (Alfa Aesar) in a 3:1 (vol %) N,N-dimethylformamide (DMF, anhydrous, Sigma-Aldrich):dimethyl
sulfoxide (DMSO, anhydrous, Sigma-Aldrich) ratio with a concentration
of 0.8 M. The precursors were added with the following ratios: Cs0.1(MA0.17FA0.83)0.9Pb0.84(I0.8Br0.2)2.68. The resulting
film thickness of the triple cation perovskite is ca. 220 nm. The
perovskite films were deposited on the glass substrates by a two-step
spin-coating process: In the first step, the perovskite solution was
spin-coated dynamically at 1000 rpm for 10 s. In the second step,
at 6000 rpm, for 20 s, chlorobenzene (anhydrous, Sigma-Aldrich, 100
μL) was dripped onto the sample after 12 s. The films were annealed
at 100 °C for 1 h to complete the crystallization process. The
complete process is performed in a nitrogen-filled glovebox.
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2

Deuteration of Formamidinium Iodide

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CH(NH2)2I (FAI, Greatcell Solar Materials Pty Ltd.) was dissolved in excessive D oxide (Sigma-Aldrich, 99.9 atom %) at a molar ratio of 1:40 under stirring, followed by heating the solution to 90°C for 2 h under argon (Ar). The liquid was then evaporated at 70°C under a flow of Ar to dry off. This process was repeated three times to ensure complete substitution of ammonium H by D to yield the high purity of D–FAI. Finally, the white solid was collected and moved to the vacuum oven at 60°C overnight for further drying. In principle, most of the D2O can be recollected by reflux for future scaled-up synthesis.
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