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6 protocols using tris trimethylsilyl phosphine

1

Synthesis of Colloidal Nanoparticles

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Indium acetate (99.99%), zinc acetate (99,9%), myristic acid (>99%), tris (trimethylsilyl)phosphine (95%, (TMS)3P), 1-octadecene (90%, ODE), trioctylphosphine (97%, TOP), sulfur (99.99%), selenium (99.99%), dimethylformamide (DMF), poly (methyl methacrylate) (PMMA, MW ~350,000 GPC), aluminum isopropoxide (Al (IPA)3 98%), toluene, methanol, chloroform, acetone, hexane, D-penicillamine, tetramethylammonium hydroxide (TMAOH), phosphate-buffered saline solution (1xPBS), and tris (2-carboxyethyl) phosphine hydrochloride solution 0.5 M (TCEP) were purchased from Sigma-Aldrich. Zinc stearate (90%, ZnSt2) was acquired from Riedel de Haën. Oleic acid (70%) came from Fisher Chemicals. All chemicals were used as received without any further purification, unless stated otherwise.
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2

Synthesis of Colloidal Nanocrystals

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Indium chloride (InCl3) (99.99%, trace metals basis), hexadecylamine (HDA‐98%), zinc undecylenate (98%), 1‐octadecene (ODE‐technical grade, 90%), stearic acid (SA) (98%), tris(trimethylsilyl)phosphine (P(TMS)3) (95%), sulfur (99.98%, trace metals basis), zinc stearate (Zn(St)2‐technical grade), and trioctylphosphine (TOP‐97%) were used from Sigma–Aldrich.
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3

Synthesis of Colloidal Nanocrystals

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Indium(III) acetate (In(OAc)3,
99.99%), zinc(II) acetate (Zn(OAc)2, 99.99%), palmitic
acid (PA, C15H31COOH, 99.99%, stored at
−20 °C), gallium(III) chloride (beads, Sigma-Aldrich,
99.99%), tris(trimethylsilyl)-phosphine (P(TMS)3, 95%), 1-octadecene (ODE, 95%), oleic acid (Sigma-Aldrich,
99.99%), ammonium sulfide solution ((NH4)2S,
20% in H2O), 1-octadecene (ODE, 95%), formamide (FA, 99%),
dimethylformamide (DMF, 99%), Zn stearate (technical grade),
sulfur powder (99.98% trace metals basis), and trioctylphosphine
(TOP, 90% technical grade) were purchased from Sigma-Aldrich. Selenium
powder (99.98% trace metals basis) was purchased by Chem Pure. All
the chemicals were used without further purification.
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4

Synthesis of Colloidal Semiconductor Nanocrystals

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Methyl acetate (anhydrous, 99.5%), toluene (anhydrous, 99.8%),
1-octadecene (ODE, technical grade, 90%), tris(trimethylsilyl)phosphine
(PTMS, 95%), trioctylphosphine (TOP, 97%), selenium (99.99%), palmitic
acid (HPA, >99%), indium acetate (In(Ac)3, 99.99% trace
metal basis), zinc acetate (Zn(Ac)2, 99.99% trace metal
basis), diethylzinc (≥52 wt % Zn basis), and di-n-butylmagnesium (1 M in heptane) were purchased from Sigma-Aldrich.
Ethanol (absolute, SupraSolv for GC-EDC/FID) was purchased from Merck.
Oleylamine (OLA, 80–90% C18, ≥96.0% (primary amine))
was purchased from Acros Organics. n-Hexane (anhydrous)
and sulfur (Puratronic , 99.9995%) were purchased from Alfa Aesar.
The used tris(trimethylsilyl)phosphine, diethylzinc, and di-n-butylmagnesium are spontaneously reactive with air
and moisture and should therefore be handled with care and solely
under inert atmosphere.
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5

Synthesis of Quantum Dots

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Indium chloride (InCl3) (99.99%, trace metals basis), HDA (98%), zinc undecylenate (98%), 1‐octadecene (ODE‐technical grade, 90%), stearic acid (SA) (98%), tris(trimethylsilyl)phosphine (P(TMS)3) (95%), sulfur (99.98%, trace metals basis), zinc stearate (Zn(St)2‐technical grade), and trioctylphosphine (TOP‐97%) were used from Sigma‐Aldrich.
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6

Synthesis of Indium-based Nanomaterials

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Indium acetate (99.99%), myristic acid (>99%), tris(trimethylsilyl)phosphine (95%), 1-dodecanethiol (97%), 1-octadecene (90%), D-penicillamine, tetramethylammonium hydroxide (TMAOH), and tris(2carboxyethyl) phosphine hydrochloride solution 0.5 M (TCEP) were purchased from Sigma-Aldrich. Zinc stearate (90%) was acquired from Riedel de Haen. Indium(III) oxide (99.9997%), indium (III) sulphur (99.995%), indium (III) phosphide (99.99%) and indium (III) phosphate (>98%) were purchased from VWR. Further solvents used within the synthesis were bought from Sigma-Aldrich, Fluka, Acros, and used without further purification.
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