Ltq orbitrap with apci probe

All reagents and solvents were used as received (Sigma‐Aldrich, Fluka, Acros Organics, Fisher Scientific Co LLC) if not stated otherwise. Melting and decomposition points were measured with a TA Instruments Q20 DSC using heating rates of 5 °C ⋅ min⁻¹. ¹H and ¹³C NMR spectra were measured with a Bruker AV‐III‐800 (5 mm QCI Z‐gradient cryoprobe). All chemical shifts are quoted in ppm relative to TMS (¹H, ¹³C). Infrared spectra were measured with a PerkinElmer Spectrum Two FT‐IR spectrometer. Transmittance values are described as “strong” (s), “medium” (m) and “weak” (w). Low resolution mass spectra were measured with an Agilent 1260 Infinity II Quaternary LC instrument. High resolution mass spectra were measured with a Thermo Fisher Scientific LTQ Orbitrap with APCI probe. Sensitivity data were determined using a BAM friction tester (Reichel & Partner Gmbh) and BAM Drophammer (OZM research).
Caution! The described compounds 1–3 are energetic materials with sensitivity to various stimuli. While we encountered no issues in the handling of these materials, proper protective measures (face shield, ear protection, body armor, Kevlar gloves, and earthened equipment) should be used at all times.

All reagents and solvents were used as received (Sigma-Aldrich, Fluka, Acros Organics, Fisher Scientific Co LLC) if not stated otherwise. Melting and decomposition points were measured with a TA Instruments Q20 DSC using heating rates of 5 °C min⁻¹. ¹H and ¹³C NMR spectra were measured with a Bruker AV-III-800 (5 mm QCI Z-gradient cryoprobe). All chemical shifts are quoted in ppm relative to TMS (¹H, ¹³C). Infrared spectra were measured with a PerkinElmer Spectrum Two FT-IR spectrometer. Transmittance values are described as “strong” (s), “medium” (m) and “weak” (w). Low resolution mass spectra were measured with an Agilent 1260 Infinity II Quaternary LC instrument. Elemental analysis data was collected using a vario EL cube. High resolution mass spectra were measured with a Thermo Fisher Scientific LTQ Orbitrap with APCI probe. Sensitivity data were determined using a BAM friction tester (Reichel & Partner Gmbh) and BAM Drophammer (OZM research).
Caution! The described compounds are energetic materials with sensitivity to various stimuli. While we encountered no issues in the handling of these materials, proper protective measures (face shield, ear protection, body armor, Kevlar gloves, and earthened equipment) should be used at all times.