Benzyl acrylate

Manufactured by Merck Group

Benzyl acrylate is a chemical compound used as a raw material in various industrial applications. It is a colorless liquid with a characteristic odor. Benzyl acrylate is commonly used in the production of polymers, resins, and other specialty chemicals.

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Lab products found in correlation

Isobornyl methacrylate, by Merck Group (1 mentions) Bis difluoroboryl diphenylglyoximato cobalt 2 phcobf, by DuPont (1 mentions) 2 2 azobis 4 methoxy 2 4 dimethylvaleronitrile v70, by Merck Group (1 mentions) Benzyl methacrylate, by Merck Group (1 mentions) Pentaerythritol triacrylate, by Merck Group (1 mentions) Tetrahydrofuran thf, by Thermo Fisher Scientific (1 mentions) 2 ethylhexylamine, by Merck Group (1 mentions) N butylamine, by Merck Group (1 mentions) N hexane, by Thermo Fisher Scientific (1 mentions) 2 ethylhexyl acrylate, by Merck Group (1 mentions) Trimethylolpropane triacrylate, by Merck Group (1 mentions) Dibutylamine, by Merck Group (1 mentions) N octylamine, by Merck Group (1 mentions)

2 protocols using benzyl acrylate

Synthesis of Functional Polymer Monomers

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All materials were used as supplied unless stated otherwise. All monomeric species used in this study, ethylene glycol dicyclopentenyl ether acrylate (EGDPEA), benzyl acrylate (BA), benzyl methacrylate (BMA, 96%), diethylene glycol ethyl ether methacrylate (DEGMA, 95%), 3,3,5-trimethyl cyclohexyl methacrylate (TMCHMA, 98%) and isobornyl methacrylate (IBMA), were purchased from Sigma Aldrich. Bis[(difluoroboryl) diphenylglyoximato]cobalt(II) (PhCoBF, DuPont) was used as supplied without further purification. 2,2’-Azobis(4-methoxy-2,4-dimethylvaleronitrile) (V70, 98%, Sigma Aldrich) was purified by recrystallization with methanol. Dichloromethane (DCM) was molecularly distilled then dried with molecular sieves.

Adlington K., Nguyen N.T., Eaves E., Yang J., Chang C.Y., Li J., Gower A.L., Stimpson A., Anderson D.G., Langer R., Davies M.C., Hook A.L., Williams P., Alexander M.R, & Irvine D.J. (2016). Application of Targeted Molecular and Material Property Optimization to Bacterial Attachment-Resistant (Meth)acrylate Polymers. Biomacromolecules, 17(9), 2830-2838.

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Synthesis of Acrylate and Amine Monomers

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Material Benzylalcohol (≥99%), benzylacrylate (≥99%, contains hydroquinone monomethyl ether (MEHQ) as inhibitor), bisphenol A glycerolate (1 glycerol/phenol) diacrylate (contains 250-500ppm MEHQ as inhibitor), n-butylamine (≥99%), dibutylamine (≥99%), N,Ndiisopropylethylamine (DIPEA, ≥99%) 2-ethylhexylacrylate (98%, contains MEHQ as inhibitor), 2-ethylhexylamine (98%), N-methylbutylamine (≥98%), pentaerythritol triacrylate (PTA, technical grade, contains 600ppm MEHQ as inhibitor), trimethylolpropane triacrylate (TMPTA, technical grade, contains 300-400ppm MEHQ as inhibitor), n-octylamine (99%), were purchased from Sigma-Aldrich. Tetrahydrofuran (THF), and n-hexane were purchased from Acros Organics.
4,4′-methylenebis(cyclohexylamine) (MBCA, >98%) was purchased from TCI. Jeffamine D2000 was kindly provided by Huntsman, and Priamine 1074 was kindly provided by Croda. All reagents were used without further purification unless stated otherwise.

Taplan C., Guerre M, & Du Prez F.E. (2021). Covalent Adaptable Networks Using β-Amino Esters as Thermally Reversible Building Blocks. Journal of the American Chemical Society, 143(24).

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