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2 protocols using bis difluoroboryl diphenylglyoximato cobalt 2 phcobf

1

Synthesis of Functional Polymer Monomers

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All materials were used as supplied unless stated otherwise. All monomeric species used in this study, ethylene glycol dicyclopentenyl ether acrylate (EGDPEA), benzyl acrylate (BA), benzyl methacrylate (BMA, 96%), diethylene glycol ethyl ether methacrylate (DEGMA, 95%), 3,3,5-trimethyl cyclohexyl methacrylate (TMCHMA, 98%) and isobornyl methacrylate (IBMA), were purchased from Sigma Aldrich. Bis[(difluoroboryl) diphenylglyoximato]cobalt(II) (PhCoBF, DuPont) was used as supplied without further purification. 2,2’-Azobis(4-methoxy-2,4-dimethylvaleronitrile) (V70, 98%, Sigma Aldrich) was purified by recrystallization with methanol. Dichloromethane (DCM) was molecularly distilled then dried with molecular sieves.
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2

Synthesis and Characterization of Methacrylate Polymers

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Methyl methacrylate (MMA, 99%), ethyl methacrylate (EMA, 99%), butyl methacrylate (BMA, 99%), lauryl methacrylate (LMA, 96%), stearyl methacrylate (SMA, 89.5%), methyl acrylate (MA, 99%), iron(II) bromide (FeBr2, 98%), 2,2-azobis(isobutyronitrile) (AIBN, 98%), glyoxal solution (40 wt% in H2O), 2,6-diisopropylaniline (97%), 2,4,6-trimethylaniline (98%), and shark squalene were purchased from Sigma-Aldrich (Gillingham, UK). Cobalt(II) bromide (CoBr2, 98%) and dimethyl glyoxime (DMG, 99%) were purchased from Acros Organics (Verona, Italy). Diphenyl glyoxime (DPG, 99%) was purchased from Alfa Aesar (Heysham, UK). Bis[(difluoroboryl) diphenylglyoximato]cobalt(II) (PhCoBF) was supplied by DuPont (Wilmington, DE, USA). Technical-grade toluene, propan-2-ol, and diethyl ether were obtained from campus departmental stores. Amaranth squalene was purchased from Wilshire Technologies (Princeton, NJ, USA). Napa Valley Naturals (Stonewall Kitchen, York, ME, USA) grapeseed oil was purchased from a local grocery store. 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) was obtained from Lipoid (Ludwigshafen, Germany). Poloxamer 188 and glycerol were obtained from Spectrum Chemical (New Brunswick, NJ, USA). Buffer components were obtained from J.T.Baker (Phillipsburg, NJ, USA) or Fluka (Charlotte, NC, USA). All materials were used as supplied without further purification.
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