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4 protocols using sodium hydroxide beads

1

Selenium-Ascorbic Acid Synthesis

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Sodium selenite (Na2SeO3; Sigma–Aldrich, St. Louis, MO, USA), L-ascorbic acid (C6H8O6, Sigma, USA), D-(+)–glucose (C6H12O6, Sigma, USA), sodium hydroxide beads (NaOH, Daejung, Seoul, Korea), and 1N- hydrochloric acid (HCL, Daejung, Korea) were used. All chemicals were reagent-grade and used without further purification.
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2

Crude Glycerol Liquefaction and Polyurethane Foam Synthesis

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Unrefined crude glycerol (CG, GS Caltex, Seoul, Korea) consisting of 80 wt% glycerol, 12 wt% water, and other impurities was used as the liquefying solvent without further purification [18 (link)]. The co-solvent, 1,4-butanediol (BD, Daejung Co., Gyeonggi-do, Korea), was used with the crude glycerol. The acid and base catalysts utilized 95% sulfuric acid (Sam-chun Co., Seoul, Korea) and sodium hydroxide beads (Daejung Co., Gyeonggi-do, Korea), respectively. For the determination of the acid and hydroxyl numbers, ethanol (Daejung Co., Gyeonggi-do, Korea), phthalic anhydride (Tokyo Chemical Industry Co., Tokyo, Japan), pyridine (Sam-chun Co., Seoul, Korea), imidazole (Daejung Co., Gyeonggi-do, Korea), and standard sodium hydroxide (0.1 N and 0.5 N, Daejung Co., Gyeonggi-do, Korea) were used. To synthesize polyurethane foam, poly [(phenyl isocyanate)-co-formaldehyde] (PMDI, Sigma-Aldrich Co., Seoul, Korea) and a preresin mix (PIUSYS, Gyeonggi-do, Korea) were used [19 (link)]. All chemicals were of analytical reagent grade without further purification.
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3

Stainless Steel Mesh Photocatalytic Reactor

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The stainless steel mesh was purchased from Anping County Bolin Metal Wire Mesh Co., Ltd (China). Methylene blue hydrate, titanium oxide (TiO2), span 80, and fluorescein isothiocyanate-dextran (FITC) were purchased from Sigma-Aldrich. Hexadecane (95 %) was purchased from Thermo Scientific. Sodium hydroxide beads, ethyl alcohol (Extra Pure) and acetone (Extra Pure) were purchased from Daejung Chemicals & Metals (South Korea). Hydrochloric acid was purchased from Samchun Chemical (South Korea). All of these were used without further purification. Deionized water (DI water, 18.2 mΩ·cm) was utilized here and obtained from a water purification system (Human Corporation, South Korea).
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4

Synthesis of Copper Nanoparticles

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Copper(II) nitrate trihydrate (Cu(NO3)2·3H2O, 99–104%) and hydrazine hydrate (N2H4·xH2O, 50–60%) were purchased from Sigma-Aldrich (Steinheim, Germany), and sodium hydroxide beads (NaOH, 97%) and L(+)-ascorbic acid (C6H8O6, 99%) were purchased from Daejung (Siheung, Republic of Korea). Deionized (DI) water with a resistivity of 18.2 MΩ·cm was prepared using a water purification system (aquapuri 5 series, Young-In, Anyang, Republic of Korea).
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