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3 protocols using glycidyl methacrylate

1

Synthesis of Polymeric Materials

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Methyl Methacrylate (MMA) and Glycidyl methacrylate (GMA) were purchased from ACROS (USA), and Potassium persulfate and sodium bisulfite were obtained from Sigma Chem. Co. (St. Louis, MO, USA), Ethanol absolute perused from Adwic, Egypt, and finally, MB from Aldrich, Germany was perused. Potassium dichromate (K2Cr2O7), minimum assay 99%, was supplied by Sigma Aldrich, Germany. Potassium permanganate (KMnO4), a minimum assay of 99%, was supplied by Sigma Aldrich, Darmstadt, Germany.
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2

Synthesis and Characterization of GMHA

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GMHA was synthesized as previously described [34 (link)]. Briefly, HA (1g, MW:1.5 MDa, LifeCore Biomedical, Chaska, MN) was dissolved at 1% (w/v) concentration in deionized water and then TEA (7.33 mL), glycidyl methacrylate (7.33 ml, Acros), and tetrabutyl ammonium bromide (7.33 g, Acros) were added with 3 hours mixing between addition of each reagent. The reaction was allowed to proceed for 12 hours at room temperature followed by 1 hour at 60 °C. The GMHA product was precipitated in acetone, re-dissolved in deionized water, dialyzed, and recovered by lyophilization.
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3

Hybrid AdED System for Boron Removal

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The hybrid
AdED system was tailored from plexiglass. The anion exchange membrane
(AEM, AMI- 7001, Membrane International Inc., USA) and the cation
exchange membrane (CEM, CMI-7000, Membrane International Inc., USA)
were supplied to construct a hybrid (electrodialysis and adsorption)
system for boron removal from geothermal water streams. Real geothermal
brine was supplied from Alkan Geothermal Power Plant, Turkey. For
the synthesis of cellulose-based boron selective adsorbents, we purchased
microcrystalline cellulose powder from Sigma-Aldrich. Glycidyl methacrylate
(GMA, 97%), N-methyl-d-glucamine (NMDG,
99%), and benzoyl peroxide (75%) were purchased from Acros Organics.
Additionally, acetone (99.8%) and boric acid (99.5%), which were used
to prepare the stock boron solution (1000 ppm), were supplied from
Merck.
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