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Methylammonium bromide

Manufactured by Xi'an Yuri Solar Co.
Sourced in China

Methylammonium bromide is a chemical compound commonly used in laboratory settings. It serves as a precursor material for the synthesis of other compounds. The core function of methylammonium bromide is to provide a source of methylammonium ions for various chemical reactions and processes.

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11 protocols using methylammonium bromide

1

Perovskite Solar Cell Material Fabrication

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Cesium iodide (CsI), lead iodide (PbI2), lead bromide (PbBr2), formamidiniumiodide (FAI), N2,N2,N2′,N2′,N7,N7,N7′,N7′-octakis(4-methoxyphenyl)-9,9′-spirobi[9H-fluorene]-2,2′,7,7′-tetramine (Spiro-OMeTAD) and methylammonium bromide (MABr) were supplied by Xi'an Polymer Light Technology Corp. Trifluoromethanesulfonic anhydride (Tf2O) was purchased from Energy Chemical. Fluorine-doped tin oxide (FTO)-coated glass substrates, TiO2 paste, acetylacetone, titanium diisoproxide bis(acetylacetonate) 75% in isopropyl alcohol, isopropanol (IPA), N,N′-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), acetone, absolute ethanol, and chlorobenzene (CB) were supplied by Aladdin. 4-Tert-butylpyridine (tBP), bis(trifluoromethylsulfonyl) imide lithium salt (LiTFSI), acetonitrile (ACN), tris(2-(1H-pyrazol-1-yl)-4-tert-butylpyridine)-cobalt(iii) tris(bis(trifluoromethyl-sulfonyl) imide) (FK 209), were purchased from Sigma-Aldrich.
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2

Perovskite Solar Cell Fabrication Protocol

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FTO was purchased from OPVtech (China). Tin (IV) oxide (SnO2) nanoparticles (15% in H2O, colloidal dispersion) were purchased from Alfa Aesar. Lead (II) iodide (PbI2) (99.99%, trace metals basis), for use in the perovskite precursor, was obtained from Tokyo Chemical Industry Co., Ltd. Methylammonium chloride (CH3NH3Cl) (MACl) (99.5%, subjected to four rounds of purification), formamidinium chloride (HC(NH2)2Cl) (FACl) (99.5%, subjected to four rounds of purification), methylammonium bromide (CH3NH3Br) (MABr) (99.5%, subjected to four rounds of purification), and formamidinium iodide (HC(NH2)2I) (FAI) (99.5%, subjected to four rounds of purification) were purchased from Xi'an Polymer Light Technology Corp. 2,2′,7,7′‐tetrakis‐(N,N‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene (Spiro‐OMeTAD) (99.86%) was purchased from Advanced Election Technology. N,N‐dimethylformamide (DMF) (99.8%), dimethyl sulfoxide (DMSO) (99.9%), chlorobenzene (CB) (99.8%), 4‐tert‐butylpyridine (96%), and lithium bis (trifluoromethylsulfonyl) imide (99%) were purchased from J & K (China) Co., Ltd. Isopropyl alcohol (IPA) (99.9%) was obtained from Energy Chemical. Cobalt (III) FK209 TFSI salt (99.9%) was obtained from Greatcell Solar Materials Pty. Ltd. None of the reagents was purified further prior to their use.
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3

Synthesis of Perovskite Materials

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Lead (II) iodide (99.999%) was purchased from Sigma Aldrich. Methylammonium chloride, methylammonium bromide (>99.5%), methylammonium iodide (>99.5%), and Spiro-OMeTAD were purchased from Xi’an Polymer Light Technology in China.
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4

Fabrication of Perovskite Solar Cells

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PEDOT:PSS (4083) was purchased from Heraeus Electronic Materials Division. Methylammonium bromide (MABr, > 99.99%), lead bromide (PbBr2, > 99.99%), and TPBi (> 99%) were purchased from Xi'an Polymer Light Technology Corp. DMF, DMSO, and chlorobenzene (HPLC, > 99.9%) were purchased from Aladdin. Blue GaN wafers were purchased from Foshan National Semiconductor Co. Ltd., All chemicals were used as received without further purification.
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5

Perovskite Solar Cell Materials Preparation

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Methylammonium bromide (MABr, ≥99.5%), methylammonium chloride (MACl, ≥99.5%) were purchased from Xi'an Polymer Light Technology Corp. Poly(vinylidenefluoridetrifluoroethylene) (P(VDF‐TrFE), 70:30 mol%) was purchased from Piezotech. Lead acetate trihydrate (PbAc2, 99.998), polystyrene (PS, MW ≈ 280 000), polymethylmethacrylate (PMMA, MW ≈ 350 000), chlorobenzene (CB, 99.8%), n‐butyl Acetate (nBA, 99.5%), and N,N‐dimethylformamide (DMF, anhydrous, 99.8%) were purchased from Sigma‐Aldrich. Dimethyl sulfoxide anhydrous (DMSO, anhydrous, 99.8%) was purchased from Alfa Aesar. Cytop solution was prepared by adding Cytop solvent into Cytop with a volume ratio of 1:3. SnO2 solution was obtained by mixing SnO2 colloidal and deionized water in a volume ratio of 1:6. All materials were used as received without any additional purification.
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6

Perovskite Solar Cell Material Synthesis

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DMF (anhydrous, 99.8%), DMSO (anhydrous, ≥99.9%), isopropanol (IPA, anhydrous, 99.5%), chlorobenzene (CB, anhydrous, 99.8%), Toluene (TL, anhydrous, 99.8%), ethyl acetate (EA, anhydrous, 99.8%), and MoOx were purchased from Sigma‐Aldrich. SnO2 colloidal solution (15 wt% in water) was purchased from Alfa Aesar. Lead (II) iodine (PbI2, ≥99.9%), Formamidinium iodide (FAI, ≥99.5%), methylammonium bromide (MABr, ≥99.5%), Spiro‐OMeTAD (≥99.5%), 4‐tert‐butyl pyridine (tBP), ≥96%), lithium bis(trifluoromethanesulfonyl) imide (Li‐TFSI, ≥99%), and tris(2‐(1h‐pyrazol‐1‐yl)‐4‐tert‐butylpyridine)‐cobalt(III)tris(bis(trifluoromethylsulfonyl)imide) (FK 209 Co(III) TFSI, ≥99%) were purchased from Xi'an Polymer Light Technology in China. Methylammonium chloride (MACl, ≥99.5%), cesium iodide (CsI, ≥99.99%) was purchased from Advanced Election Technology CO, Ltd. in China. The ITO target (In2O3/SnO2 = 90:10 wt%) was purchased from Huizhou Tianyi Rare Materials Co., Ltd in China.
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7

Ionic Liquid-Assisted Cellulose Modification

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Microcrystalline cellulose (DP = 220) was dried in a vacuum oven at 60 °C for 48 h prior to use. The ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl) was synthesized in our laboratory. The water content in AmimCl determined by Karl Fischer method was less than 0.3 wt%. Tetrabutylphosphonium hydroxide ([P4,4,4,4]OH, 40 wt%), acrylonitrile (AN, 99%), 1-butylimidazole (98%), N-(2-cyanoethyl)-imidazole (98%), 2-chloropropionyl chloride (97%), and cellulose acetate (CA, DS = 2.5) were supplied by Beijing Innochem Science and Technology Co., Ltd. Tin oxide (SnO2, 15 wt%) and isopropanol (IPA, 99.7%) were purchased from Alfa Aesar. Lead iodide (PbI2, 99.9%), cesium iodide (CsI, 99.99%), formamidine iodide (FAI, 99.5%), methylammonium chloride (MACl, 99.5%), methylammonium bromide (MABr, 99.5%), Spiro-OMeTAD (99.8%), lithium bis(trifluoromethanesulfonyl)imide (Li-TFSI, 99.95%), 4-tert-butyl pyridine (TBP, 96%), acetonitrile (ACN, 99.5%), and 4-methoxyphenethylammonium (4-CH3O-PEAI, 99.5%) were purchased from Xi’an Polymer Light Technology in China. Chlorobenzene (CB, 99.8%), dimethylsulfoxide (DMSO, 99.7%), and dimethylformamide (DMF, 99.8%) were brought from Sigma-Aldrich. All chemicals were used without further purification.
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8

Perovskite Solar Cell Precursor Materials

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Formamidinium iodide (FAI, 99.5%), methylammonium iodide (MAI, 99.5%), and methylammonium bromide (MABr, 99.5%) were obtained from Xi'an Polymer Light Technology Corp, China. Lead iodide (PbI2, 99.99%), lead bromide (PbBr2, 99%), and cesium iodide (CsI, 99%) were purchased from TCI. Bis(trifluoromethane) sulfonimide lithium salt (Li-TFSI, 99.95%), anhydrous dimethyl sulfoxide (DMSO, 99.9%), anhydrous N,N-dimethylformamide (DMF, 99.8%), 4-tert-butylpyridine (98%), anhydrous chlorobenzene (CB, 99.8%), anhydrous acetonitrile (99.8%), anhydrous 1-butanol (99.8%), and SnCl2·2H2O (99.995%) were received from Sigma-Aldrich. K2SnO3·3H2O (99.5%), urea (99.995%), YCl3·6H2O (99.99%), LaCl3·6H2O (99.99%), ScCl3·6H2O (99.9%), and ethylene glycol (EG, 99%) were obtained from Aladdin. All the chemicals were used as received without further purification. Deionized water (resistivity > 18 MΩ) was obtained through a Millipore water purification system. Prepatterned fluorine-doped tin oxide-coated (FTO) substrates with a sheet resistance of 14 Ω sq−1 were purchased from Pilkington.
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9

Perovskite Solar Cell Fabrication

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Lead iodide (PbI2), bis(trifluoromethylsulfonyl)-imide lithium salt (Li-TFSI), chlorobenzene, 4-tert-butylpyridine, N,N-dimethylformamide (DMF), dimethylsulfoxide (DMSO), and isopropyl alcohol (IPA) were purchased from Sigma-Aldrich. Formamidinium iodide (FAI), methylammonium bromide (MABr), and methylammonium chloride (MACl), 2,2′,7,7′-tetrakis-(N,N-di-4-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD) were purchased from Xi'an Polymer Light Technology Corp. 2-Methoxyethanol was purchased from Aladdin. Tin (IV) oxide colloid precursor was purchased from Alfa Aesar.
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10

Perovskite Solar Cell Material Preparation

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Lead iodide (PbI2, 99.99%) was purchased from TCI. Lead bromide (PbBr2), methylammonium iodide (MAI), and methylammonium bromide (MABr) were purchased from Xi'an Polymer Light Technology Corp. N,N‐Dimethyl formamide (DMF, 99.8%), and DMSO (99.7%) were purchased from Acros. The fluorine doped tin oxide (FTO) glass substrates were purchased from Yingkou OPV Tech New Energy Co., Ltd. All the materials were used as received without further purification.
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