1 10 phenanthroline

Styrene, sodium persulfate, sodium dodecyl sulfate (SDS), ethyl acrylate (EA), ethanol were purchased from Sinopharm Chemical Reagent (China, Shanghai). Butanediol diacrylate (BDDA) and allyl methacrylate (AMA) were obtained from TCI (Shanghai). Potassium hydroxide (KOH), sodium hydroxide (NaOH), aluminum oxide, and propylene carbonate were obtained from Aladdin (China, Shanghai). Dowfax2A1 was purchased from Dow Chemicals. Before emulsion polymerization, chemicals were purified to remove stabilizers. Typically, EA was extracted with 1 M sodium hydroxide solution and treated with water to a neutral state after which the remained water was removed by sodium sulfate. Styrene was treated with alumina oxide column (basic, 200-300 mesh). Water used in this project was all deionized.
Palladium (II) octaethylporphine (PdOEP, 85%) were obtained from Sigma-Aldrich. Perylene and BODIPY were purchased from J&K Scientific Co., Ltd. (1,10-Phenanthroline)tris[4,4,4-trifluoro-1-(2-thienyl)−1,3-butanedionato]europium(III) [Eu(TTA)3phen] was purchased from Tokyo Chemical Industry Co., Ltd. CU was prepared by the methods described in the literature²⁷ .

Fresh seedless chestnut rose (R. sterilis) fruits were collected in October 2021 on the farmland of Zhenning, Anshun, located in Guizhou Province, China (26°2′49.42″ N, 105°41′59.45″ E, 1247.6 m above sea level). Standard monosaccharides, 3-Phenylphenol, trifluoroacetic acid (TFA), 1,10-Phenanthroline, 1,1-diphenyl-2-picrylhydrazyl (DPPH), 2,2′-azinobis (3-ethylbenzothiazoline-6-sulphonic acid) (ABTS), and 3-(2-Pyridyl)-5,6-diphenyl-1,2,4-triazine-p,p′-disulfonic acid monosodium salt hydrate were purchased from TOKYO Chemical Industry Co., Ltd. (Tokyo, Japan). Sodium hydroxide was purchased from Thermo Fisher Co., Waltham, MA, USA. The pullulan polysaccharide calibration kit was purchased from Agilent Co., Santa Clara, CA, USA. α-Glucosidase, p-nitrophenyl-α-d-glucopyranoside (PNPG), and serum albumin (BSA) were obtained from Yuanye Bio-technology (Shanghai, China). All additional solvents and chemical reagents were acquired locally and were of either HPLC or analytical quality.