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Bis trifluoromethane sulfonamide lithium salt

Manufactured by Merck Group
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Bis(trifluoromethane)sulfonamide lithium salt is a chemical compound used as a reagent in various laboratory applications. It serves as a source of lithium cations and as a strong acid in organic synthesis and analytical chemistry.

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Lab products found in correlation

4 tert butylpyridine, by Merck Group (3 mentions) Chlorobenzene, by Merck Group (3 mentions) Ethanol, by Merck Group (2 mentions) Acetonitrile, by Merck Group (2 mentions) N n dimethylformamide (dmf), by Merck Group (1 mentions) 2 propanol, by Merck Group (1 mentions) Lead 2 iodide pbi2, by Thermo Fisher Scientific (1 mentions) Titanium isopropoxide, by Merck Group (1 mentions) Diethyl ether, by Merck Group (1 mentions) Hydroiodic acid, by Merck Group (1 mentions) Hydrobromic acid, by Merck Group (1 mentions) Acetic acid, by Merck Group (1 mentions) Triton x 114, by Merck Group (1 mentions) 1 butyl 3 methylimidazolium chloride, by Merck Group (1 mentions) Lithium hexafluorophosphate, by Merck Group (1 mentions) Dimethyl sulfoxide (dmso), by Merck Group (1 mentions) Dimethylformamide, by Merck Group (1 mentions) Ch3nh3br, by Xi'an Yuri Solar Co. (1 mentions) Isopropanol, by Sinopharm (1 mentions) Sncl2 2h2o, by Thermo Fisher Scientific (1 mentions)

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Sulfonamide (2 citations)

5 protocols using bis trifluoromethane sulfonamide lithium salt

1

Perovskite Solar Cell Fabrication

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Fluorine doped tin oxide (SnO2:F) glass substrate (>7 Ω/sq sheet resistance) was purchase from Solaronix. The Nb target (99.9 %) was provided by Brazilian Metallurgy and Mining Company (CBMM). Lead (II) iodide (PbI2-99.998%) was purchased from Alfa Aesar. Spiro-MeOTAD (99%), bis(trifluoromethane)sulfonamide lithium salt (≥99.0%), 4-tert-butylpyridine (96%), ethanol, acetonitrile (anhydrous, 99.8%) and chlorobenzene (99.8%) from Sigma Aldrich. 2-propanol (max 0.005% H2O) and N-N dimethylformamide (DMF- max 0.003% H2O) from Merck. TiO2 paste (DSL 30NR-D), FK 209 Co(III) TFSL salt and methylammonium iodide (CH3NH3I) from Dyesol. All chemicals were used as received, without purification.
Fernandes S.L., Albano L.G., Affonço L.J., da Silva J.H., Longo E, & Graeff C.F. (2019). Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells. Frontiers in Chemistry, 7, 50.
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2

Organic Photovoltaic Device Fabrication

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Titanium isopropoxide, methyl amine, diethyl ether and acetic acid were supplied from Merck Co., while the polyvinylpyrrolidone (PVP, M.wt 16000), 2,2-,7,7--tetrakis-(N,N-di-p-methoxyphenyl-amine)-9,9-, formamidine acetate, chlorobenzene, hydroiodic acid, hydrobromic acid, bis (trifluoromethane) sulfonamide lithium salt, 4-tert-butylpyridine and ethanol were purchased from Sigma Aldrich(99%). All the aforementioned chemicals were used without future purification. Fluorine tin oxide conductive glass sheets was supplied by Pilkington Co.
Hsu C.Y., AL-Salman H.N., Hussein H.H., Juraev N., Mahmoud Z.H., Al-Shuwaili S.J., Hassan Ahmed H., Ali Ami A., Ahmed N.M., Azat S, & kianfar E. (2024). Experimental and theoretical study of improved mesoporous titanium dioxide perovskite solar cell: The impact of modification with graphene oxide. Heliyon, 10(4), e26633.
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3

Bisphenol A Analysis via Ionic Liquids

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The bisphenol A standard was purchased from Sigma-Aldrich Chemie (Schnelldorf, Germany). Pure water was prepared using a water purification system formed by a delimer (CILIT MINICRONO (Cilit, SA, Barcelona, Spain) and a water purification system SETA OSMO BL-6 (Sociedad Española de Tratamiento de Agua, Madrid, Spain). Ultrapure water was employed for the preparation of 0.1 M solutions of these ILs.
Bis(trifluoromethane)sulfonamide lithium salt and 1-butyl-3-methylimidazolium chloride (Sigma-Aldrich Chemie, Schnelldorf, Germany) were used in orden to form the IL. Analytical grade acetonitrile was obtained from Applichem Panreac (Darmstadt, Germany), and water for HPLC from Macron Fine Chemicals (Gliwice, Poland). The non-ionic surfactant Triton X-114 was purchased from Sigma-Aldrich (Raleigh, NC, USA). Micro pipettes of 100–1000 µL were brought from Thermo Scientific (Wantaa, Finland).
Vicente-Martínez Y., Caravaca M, & Soto-Meca A. (2020). Determination of Very Low Concentration of Bisphenol A in Toys and Baby Pacifiers Using Dispersive Liquid–Liquid Microextraction by In Situ Ionic Liquid Formation and High-Performance Liquid Chromatography. Pharmaceuticals, 13(10), 301.
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4

Synthesis of Lithium-Ion Battery Electrolyte

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Ludox SM30 colloidal silica (d=10±2 nm), poly(propylene glycol)-toluene-2,4-diisocyante, PC, bis(trifluoromethane) sulfonamide lithium salt, ethylene carbonate/ diethylene carbonate (1v:1v) with lithium hexafluorophosphate were all purchased from Sigma Aldrich. Hydoxy terminated poly (ethylene oxide)-silane was obtained from Gelest. All the chemicals were used as received in appropriate conditions.
Choudhury S., Mangal R., Agrawal A, & Archer L.A. (2015). A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles. Nature Communications, 6, 10101.
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5

Perovskite Solar Cell Fabrication Protocol

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All the chemicals were used as received from commercial companies, including PbI2 and PbBr2 (>99%, TCI, Japan), CH3NH3Br (MABr, 99.8%, Xi’an Polymer Light Technology Corp., China), NH2CH=NH2I (FAI, 99.8%, Xi’an Polymer Light Technology Corp., China), CsI (99.999%, Alfa Aesar, UK), SnCl2·2H2O (98–103%, Alfa Aesar, UK), Spiro-OMeTAD (99.7%, Lumtec Co., Taiwan), isopropanol (99.8%, Sinopharm Chemical Reagent Co., Ltd, China). 4-tert-butylpyridine (TBP, 96%), Bis (trifluoromethane) sulfonamide lithium salt (99.95%), and solvents acetonitrile (99.9%), dimethylformamide (DMF, 99.8%), dimethylsulfoxide (DMSO, 99.9%), α, α, α-Trifluorotoluene (≥99%) and chlorobenzene (CB, 99.8%) were all purchased from Sigma Aldrich (USA). FTO-coated glass substrates (7 Ω sq−1) and PEN/ITO flexible substrates (15 Ω sq−1; 125-μm thick) were purchased from Yingkou OPVtech New Energy Co. Ltd. (China).
Dong Q., Zhu C., Chen M., Jiang C., Guo J., Feng Y., Dai Z., Yadavalli S.K., Hu M., Cao X., Li Y., Huang Y., Liu Z., Shi Y., Wang L., Padture N.P, & Zhou Y. (2021). Interpenetrating interfaces for efficient perovskite solar cells with high operational stability and mechanical robustness. Nature Communications, 12, 973.
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