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Bis 4 tertbutylphenyl iodonium hexafluorophosphate

Manufactured by Merck Group
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Bis(4-tertbutylphenyl)iodonium hexafluorophosphate is a photoinitiator used in the curing of various polymer and coating systems. It is a crystalline solid that generates reactive species upon exposure to light, initiating polymerization reactions.

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Lab products found in correlation

Diphenyliodonium chloride, by Merck Group (1 mentions) Phosphate buffered saline tablets, by Thermo Fisher Scientific (1 mentions) Bis 4 methylphenyl iodonium hexafluorophosphate, by Merck Group (1 mentions) Ph1000, by Merck Group (1 mentions) Bisphenol a diglycidyl ether dgeba, by Merck Group (1 mentions) Acetone, by Merck Group (1 mentions) Dimethylformamide dmf, by Merck Group (1 mentions) 2 2 dimethoxy 2 phenylacetophenone, by Merck Group (1 mentions)

2 protocols using bis 4 tertbutylphenyl iodonium hexafluorophosphate

1

Electrochemical Characterization of Iodonium Salts

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Diphenyliodonium chloride, bis(4-tertbutylphenyl)iodonium hexafluorophosphate, (4-nitrophenyl)(2,4,6-trimethylphenyl)iodonium triflate, bis(4-methylphenyl)iodonium hexafluorophosphate, tetrabutylammonium hexafluorophosphate (tBu4NPF6) were obtained from Sigma-Aldrich. Phosphate-buffered saline (PBS) tablets (Fisher Bioreagents) were dissolved in deionized water to obtain a solution containing 0.01 M phosphate buffer, 0.0027 M KCl and 0.127 M NaCl. Acetonitrile (ACN, 99.9%), ferrocene, KNO3 were purchased from Sigma-Aldrich. tBu4NPF6 was vacuum dried before use. Aqueous dispersion of PEDOT:PSS was purchased from either Ossila (PH1000) or Sigma Aldrich (1.1%), as indicated. Other reagents were used as received.
Smołka S., Patel T., Pluczyk-Małek S., Turczyn R, & Krukiewicz K. (2024). Iodonium-based pro-adhesive layers for robust adhesion of PEDOT:PSS to surfaces. Science and Technology of Advanced Materials, 25(1), 2338786.
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2

Photocurable Polycaprolactone Synthesis

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Bisphenol A diglycidyl ether (DGEBA, Mw = 340.41 g/mol), 2,2-dimethoxy-2-phenyl-acetophenone, bis(4-tert-butylphenyl)iodonium hexafluorophosphate, acetone and dimethylformamide (DMF) with analytical grade were purchased from Sigma-Aldrich (San Luis, MO, USA). Linear polycaprolactone (PCL, Mw = 45,000 g/mol) was purchased from Perstrop (Malmö, Sweden). All materials were used as received.
Iregui A., Irusta L., Martin L, & González A. (2019). Analysis of the Process Parameters for Obtaining a Stable Electrospun Process in Different Composition Epoxy/Poly ε-Caprolactone Blends with Shape Memory Properties. Polymers, 11(3), 475.
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