Basolite z1200

Manufactured by Merck Group

Sourced in Spain, United States

Basolite Z1200 is a metal-organic framework material produced by Merck Group. It is designed for use in laboratory applications that require high surface area, porosity, and adsorption capacity.

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ZIF-8 (Basolite Z1200) (2 citations)

4 protocols using basolite z1200

Synthesis and Characterization of Metal-Organic Frameworks

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Cu₃(BTC)₂ was purchased from Sigma Aldrich with the commercial trade name Basolite C300. Similarly, other related MOFs like Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylate) and ZIF-8 with the trade names Basolite A100 and Basolite Z1200, respectively were also purchased from Sigma Aldrich, Barcelona, Spain. MIL-101(Cr) was synthesized by adopting earlier procedure, and its structural integrity was confirmed by powder X-ray diffraction (XRD), which was in good agreement with an earlier report [41 (link)]. Furthermore, CuCl, Cu(NO₃)₂.3H₂O, Cs₂CO₃, K₂CO₃, Na₂CO₃, B₂pin₂, 2-cyclohexenone and acetonitrile were procured from Sigma Aldrich, Barcelona, Spain.

Dhakshinamoorthy A., Alvaro M., Asiri A.M, & Garcia H. (2021). α,β-Enone Borylation by Bis(Pinacolato)Diboron Catalyzed by Cu3(BTC)2 Using Cesium Carbonate as a Base. Nanomaterials, 11(6), 1396.

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Synthesis of Bimetallic ZIF Frameworks

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All chemicals were used as received
from reliable commercial sources.
Basolite Z1200 (ZIF-8 material) and 2-methylimidazole (HmIm) were
purchased from Sigma-Aldrich Co. Cobalt(II) nitrate hexahydrate [Co(NO₃)₂·6H₂O] and methanol 96% were
purchased from Fisher Scientific, and ethanol (technical grade) was
purchased from Scharlab S.L.
For the synthesis of bimetallic
ZIF (Zn_0.6Co_0.4) frameworks, 2-methylimidazole
(HmIm), zinc nitrate hexahydrate
[Zn(NO₃)₂·6H₂O] and cobalt(II)
nitrate hexahydrate [Co(NO₃)₂·6H₂O] were procured from Sigma-Aldrich. Analytical grade methanol was
procured from J T Baker India.

Amayuelas E., Sharma S.K., Utpalla P., Mor J., Bartolomé L., Carter M., Trump B., Yakovenko A.A., Zajdel P, & Grosu Y. (2023). Bimetallic Zeolitic Imidazole Frameworks for Improved Stability and Performance of Intrusion–Extrusion Energy Applications. The Journal of Physical Chemistry. C, Nanomaterials and Interfaces, 127(37), 18310-18315.

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Synthesis and characterization of tamoxifen analogs

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Basolite^® C300 (CuBTC), Basolite^® Z1200 (ZIF-8), polyacrylonitrile (PAN, average Mw = 150,000), N,N-Dimethyl formamide (DMF), and (Z)-1-(p-Dimethylaminoethoxyphenyl)-1,2-diphenyl-1-butene (Tamoxifen citrate, TAM) were purchased from Sigma-Adrich (Saint Louis, MI, USA). (Z)-2-(p-(1,2-Diphenyl-1-butenyl)phenoxy)-N-methyl ethylamine (N-desmethyl tamoxifen, NDTAM), (E/Z)-4-[1-[4-[2-(Methylamino)ethoxy]phenyl]-2-phenyl-1-buten-1-yl]-phenol hydrochloride hydrate (1:1 E/Z mixture) Endoxifen, ENDO), (Z)-4-(1-[4-(Dimethylaminoethoxy)phenyl]-2-phenyl-1-butenyl)phenol (4-Hydroxytamoxifen, 4OHT), and 4-[1-[4-[2-(Methylamino)ethoxy]phenyl]-2-phenyl-1-butenyl-d5]phenol (E/Z Endoxifen-d5) were purchased from United States Biological (Salem, MA, USA). 2-[4-[(1Z)-1,2-diphenyl-1-buten-1-yl-3,3,4,4,4-d5]phenoxy]-N,N-dimethyl-ethanolamine (Tamoxifen-d5) and 4-[1-[4-[2-(dimethylamino)ethoxy]phenyl]-2-phenyl-1-buten-1-yl-3,3,4,4,4-d5]-phenol (4-Hydroxytamoxifen-d5) were obtained from Cayman Chemical Company (Ann Arbor, MI, USA). As this research does not involve clinical trials, the biological samples were altruistically donated following our Institutional Research and Ethics Board recommendations.

Flores-Hernandez D.R., Leija Gutiérrez H.M., Hernandez-Hernandez J.A., Sánchez-Fernández J.A, & Bonilla-Rios J. (2023). Enhancing Solid-Phase Extraction of Tamoxifen and Its Metabolites from Human Plasma Using MOF-Integrated Polyacrylonitrile Composites: A Study on CuBTC and ZIF-8 Efficacy. Nanomaterials, 14(1), 73.

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Synthesis and Characterization of ZIF-8 and Co-doped ZIF-8

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All chemicals and reagents were
of analytical grade and used as delivered without further purification.
These chemicals include Basolite Z1200 [2-methylimidazole zinc salt
(ZIF-8), Sigma-Aldrich], cobalt (II) chloride hexahydrate [CoCl₂·6H₂O, 97–102% assay (by complexometry),
Loba Chemie], zinc nitrate hexahydrate [Zn(NO₃)₂·6H₂O, ≥96.0% assay, Merck], polyvinylpyrrolidone
(PVP) [(C₆H₉NO)_n, Sigma-Aldrich], and 2-methylimidazole [Hmim, 99% assay, Sigma-Aldrich].
Acetone [(CH₃)₂CO, ≥ 99%], methanol [CH₃OH, 99.7%], and distilled water were obtained from Merck.
Highly pure certified He, N₂, CO₂, and H₂ gases used for the adsorption measurements were purchased
from Inox air product Ltd., India.

Panchariya D.K., Rai R.K., Anil Kumar E, & Singh S.K. (2018). Core–Shell Zeolitic Imidazolate Frameworks for Enhanced Hydrogen Storage. ACS Omega, 3(1), 167-175.

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